Two Cd(II) Coordination Compounds Based on the Flexible N-Bridging Ligands: Syntheses, Crystal Structures and Luminescent Properties

Russian Journal of Coordination Chemistry volume 47, pages75–80(2021)Cite this article

Abstract

Two coordination compounds, Cd2(Рtt)2Cl4(H2O)2 (Ι) and [Cd(Dpb)2Cl2]n · nH2O (II) (Рtt = 3-(pyrid-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl), Dpb = 1,4-bis(pyridin-3-ylmethoxy)benzene), were synthesized from hydro-solvothermal technique. Their structures have been characterized by infrared spectra, elemental analyses, single crystal X-ray diffraction analyses (CIF files CCDC nos. 1903141 (Ι), 1903138 (II)) and thermogravimetric analyses. Compound Ι is a dinuclear structure and II is a 1D chain. Moreover, the luminescent properties of Ι and II have been investigated with fluorescent spectra in the solid state, the two compounds display a strong fluorescent emission at room temperature and have potential applications as fluorescent-emitting materials.

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ACKNOWLEDGMENTS

The authors thank financial assistance from the Key Scientific Research Project of Education Department of Shaanxi Province (17JS027) and this work is also supported by team of syngas catalytic conversion of Shaanxi university of Technology.

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Affiliations

  1. Shaanxi Key Laboratory of Catalysis, College of Chemical & Environment Science, Shaanxi University of Technology, 723001, Han Zhong, P.R. China

    J. Song, R. Wu, J. F. Lu & Q. Zhang

  2. Mechanical Engineering Training Center, Shaanxi University of Technology, 723001, Han Zhong, P.R. China

    B. F. Duan

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  1. J. Song
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  2. B. F. Duan
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  3. R. Wu
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  4. J. F. Lu
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Correspondence to J. Song.

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Song, J., Duan, B.F., Wu, R. et al. Two Cd(II) Coordination Compounds Based on the Flexible N-Bridging Ligands: Syntheses, Crystal Structures and Luminescent Properties. Russ J Coord Chem 47, 75–80 (2021). https://doi.org/10.1134/S1070328421010073

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Keywords:

  • hydro-solvothermal technique
  • crystal structure
  • luminescent property