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Two Cd(II) Coordination Compounds Based on the Flexible N-Bridging Ligands: Syntheses, Crystal Structures and Luminescent Properties

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Abstract

Two coordination compounds, Cd2(Рtt)2Cl4(H2O)2 (Ι) and [Cd(Dpb)2Cl2]n · nH2O (II) (Рtt = 3-(pyrid-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl), Dpb = 1,4-bis(pyridin-3-ylmethoxy)benzene), were synthesized from hydro-solvothermal technique. Their structures have been characterized by infrared spectra, elemental analyses, single crystal X-ray diffraction analyses (CIF files CCDC nos. 1903141 (Ι), 1903138 (II)) and thermogravimetric analyses. Compound Ι is a dinuclear structure and II is a 1D chain. Moreover, the luminescent properties of Ι and II have been investigated with fluorescent spectra in the solid state, the two compounds display a strong fluorescent emission at room temperature and have potential applications as fluorescent-emitting materials.

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REFERENCES

  1. Wang, X.J., Liu, Y.H., Xu, C.Y., et al., Cryst. Growth Des., 2012, vol. 12, p. 2435.

    Article  CAS  Google Scholar 

  2. Shen, J.J., Li, M.X., Wang, Z.X., et al., Cryst. Growth Des., 2014, vol. 14, p. 2818.

    Article  CAS  Google Scholar 

  3. Denisov, G.L., Primakov, P.V., Korlyukov, A.A., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 836. https://doi.org/10.1134/S1070328419120030

    Article  CAS  Google Scholar 

  4. Ren, H., Song, T.Y., Xu, J.N., et al., Cryst. Growth Des., 2009, vol. 9, p. 105.

    Article  CAS  Google Scholar 

  5. Christian, G.F., Devic, T., Maurin, G., et al., Chem. Soc. Rev., 2011, vol. 0, p. 550.

    Google Scholar 

  6. Wu, Q., Li, J.D., Liu, F.X., et al., Russ. J. Coord. Chem., 2020, vol. 46, p. 137. https://doi.org/10.1134/S1070328420020086

    Article  CAS  Google Scholar 

  7. Genna, D.T., Wong, A.G., Matzger, A.J., et al., J. Am. Chem. Soc., 2013, vol. 135, p. 10586.

    Article  CAS  Google Scholar 

  8. Lifintseva, T.V., Burlov, A.S., Vlasenko, V.G., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 867. https://doi.org/10.1134/S1070328419120054

    Article  CAS  Google Scholar 

  9. Taydakov, I.V., Avetisov, R.I., Datskevich, N.P., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 883. https://doi.org/10.1134/S1070328419120078

    Article  CAS  Google Scholar 

  10. Serra, P., Veen, M.A., Gobechiya, A., et al., J. Am. Chem. Soc., 2012, vol. 134, p. 8314.

    Article  Google Scholar 

  11. Rojas, S., Carmona, F.J., Maldonado, C.R., et al., Inorg. Chem., 2016, vol. 55, p. 2650.

    Article  CAS  Google Scholar 

  12. Liu, J.W., Chen, L.F., Cui, H., et al., Chem. Soc. Rev., 2014, vol. 43, p. 6011.

    Article  CAS  Google Scholar 

  13. Knorr, M., Guyon, F., Khatyr, A., et al., Inorg. Chem., 2012, vol. 51, p. 9917.

    Article  CAS  Google Scholar 

  14. Li, B., Xu, Z.Q., Xu, Y.B., et al., Inorg. Chem. Commun., 2019, vol. 102, p. 57.

    Article  CAS  Google Scholar 

  15. Wang, X.L., Li, N., Tian, A.X., et al., Inorg. Chem., 2014, vol. 53, p. 7118.

    Article  CAS  Google Scholar 

  16. Wang, X.T., Wang, X.H., Wang, Z.M., et al., Inorg. Chem., 2009, vol. 48, p. 1301.

    Article  CAS  Google Scholar 

  17. Li, P.X. and Lu, J.F. Chinese J. Struct. Chem., 2017, vol. 35, p. 303.

    CAS  Google Scholar 

  18. Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  19. Sheldrick, G.M., SHELXS-97, Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  20. Askerov, R.K., Magerramov, A.M., Osmanov, V.K., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 112. https://doi.org/10.1134/S1070328419020039

    Article  CAS  Google Scholar 

  21. Wang, S.M., Sun, X.L., Zheng, X.Y., et al., Russ. J. Coord. Chem., 2018, vol. 44, p. 82. https://doi.org/10.1134/S1070328417120119

    Article  CAS  Google Scholar 

  22. Gogoleva, N.V., Shmelev, M.A., Evstifeev, I.S., et al., Russ. Chem. Bull., 2016, vol. 65, p. 181.

    Article  CAS  Google Scholar 

  23. Nikolaevskii, S.A., Evstifeev, I.S., Kiskin, M.A., et al., Polyhedron, 2018, vol. 152, p. 61.

    Article  CAS  Google Scholar 

  24. Kiraev, S.R., Nikolaevskii, S.A., Kiskin, M.A., et al., Inorg. Chim. Acta, 2018, vol. 477, p. 15.

    Article  CAS  Google Scholar 

  25. Nikolaevskii, S.A., Koshchienko, Y.V., Chernyshev, A.V., et al., Russ. J. Coord. Chem., 2014, vol. 40, p. 468. https://doi.org/10.1134/S1070328414070070

    Article  CAS  Google Scholar 

  26. Yang, E.C., Zhao, H.K., Ding, B., et al., Cryst. Growth Des., 2007, vol. 7, p. 2009.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The authors thank financial assistance from the Key Scientific Research Project of Education Department of Shaanxi Province (17JS027) and this work is also supported by team of syngas catalytic conversion of Shaanxi university of Technology.

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Authors and Affiliations

  1. Shaanxi Key Laboratory of Catalysis, College of Chemical & Environment Science, Shaanxi University of Technology, 723001, Han Zhong, P.R. China

    J. Song, R. Wu, J. F. Lu & Q. Zhang

  2. Mechanical Engineering Training Center, Shaanxi University of Technology, 723001, Han Zhong, P.R. China

    B. F. Duan

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  1. J. Song
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  2. B. F. Duan
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  3. R. Wu
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  4. J. F. Lu
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  5. Q. Zhang
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Correspondence to J. Song.

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Song, J., Duan, B.F., Wu, R. et al. Two Cd(II) Coordination Compounds Based on the Flexible N-Bridging Ligands: Syntheses, Crystal Structures and Luminescent Properties. Russ J Coord Chem 47, 75–80 (2021). https://doi.org/10.1134/S1070328421010073

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  • DOI: https://doi.org/10.1134/S1070328421010073

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