Two Cd(II) Coordination Compounds Based on the Flexible N-Bridging Ligands: Syntheses, Crystal Structures and Luminescent Properties

Abstract

Two coordination compounds, Cd2(Рtt)2Cl4(H2O)2 (Ι) and [Cd(Dpb)2Cl2]n · nH2O (II) (Рtt = 3-(pyrid-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl), Dpb = 1,4-bis(pyridin-3-ylmethoxy)benzene), were synthesized from hydro-solvothermal technique. Their structures have been characterized by infrared spectra, elemental analyses, single crystal X-ray diffraction analyses (CIF files CCDC nos. 1903141 (Ι), 1903138 (II)) and thermogravimetric analyses. Compound Ι is a dinuclear structure and II is a 1D chain. Moreover, the luminescent properties of Ι and II have been investigated with fluorescent spectra in the solid state, the two compounds display a strong fluorescent emission at room temperature and have potential applications as fluorescent-emitting materials.

This is a preview of subscription content, access via your institution.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

REFERENCES

  1. 1

    Wang, X.J., Liu, Y.H., Xu, C.Y., et al., Cryst. Growth Des., 2012, vol. 12, p. 2435.

    CAS  Article  Google Scholar 

  2. 2

    Shen, J.J., Li, M.X., Wang, Z.X., et al., Cryst. Growth Des., 2014, vol. 14, p. 2818.

    CAS  Article  Google Scholar 

  3. 3

    Denisov, G.L., Primakov, P.V., Korlyukov, A.A., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 836. https://doi.org/10.1134/S1070328419120030

    CAS  Article  Google Scholar 

  4. 4

    Ren, H., Song, T.Y., Xu, J.N., et al., Cryst. Growth Des., 2009, vol. 9, p. 105.

    CAS  Article  Google Scholar 

  5. 5

    Christian, G.F., Devic, T., Maurin, G., et al., Chem. Soc. Rev., 2011, vol. 0, p. 550.

    Google Scholar 

  6. 6

    Wu, Q., Li, J.D., Liu, F.X., et al., Russ. J. Coord. Chem., 2020, vol. 46, p. 137. https://doi.org/10.1134/S1070328420020086

    CAS  Article  Google Scholar 

  7. 7

    Genna, D.T., Wong, A.G., Matzger, A.J., et al., J. Am. Chem. Soc., 2013, vol. 135, p. 10586.

    CAS  Article  Google Scholar 

  8. 8

    Lifintseva, T.V., Burlov, A.S., Vlasenko, V.G., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 867. https://doi.org/10.1134/S1070328419120054

    CAS  Article  Google Scholar 

  9. 9

    Taydakov, I.V., Avetisov, R.I., Datskevich, N.P., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 883. https://doi.org/10.1134/S1070328419120078

    CAS  Article  Google Scholar 

  10. 10

    Serra, P., Veen, M.A., Gobechiya, A., et al., J. Am. Chem. Soc., 2012, vol. 134, p. 8314.

    Article  Google Scholar 

  11. 11

    Rojas, S., Carmona, F.J., Maldonado, C.R., et al., Inorg. Chem., 2016, vol. 55, p. 2650.

    CAS  Article  Google Scholar 

  12. 12

    Liu, J.W., Chen, L.F., Cui, H., et al., Chem. Soc. Rev., 2014, vol. 43, p. 6011.

    CAS  Article  Google Scholar 

  13. 13

    Knorr, M., Guyon, F., Khatyr, A., et al., Inorg. Chem., 2012, vol. 51, p. 9917.

    CAS  Article  Google Scholar 

  14. 14

    Li, B., Xu, Z.Q., Xu, Y.B., et al., Inorg. Chem. Commun., 2019, vol. 102, p. 57.

    CAS  Article  Google Scholar 

  15. 15

    Wang, X.L., Li, N., Tian, A.X., et al., Inorg. Chem., 2014, vol. 53, p. 7118.

    CAS  Article  Google Scholar 

  16. 16

    Wang, X.T., Wang, X.H., Wang, Z.M., et al., Inorg. Chem., 2009, vol. 48, p. 1301.

    CAS  Article  Google Scholar 

  17. 17

    Li, P.X. and Lu, J.F. Chinese J. Struct. Chem., 2017, vol. 35, p. 303.

    CAS  Google Scholar 

  18. 18

    Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  19. 19

    Sheldrick, G.M., SHELXS-97, Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  20. 20

    Askerov, R.K., Magerramov, A.M., Osmanov, V.K., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 112. https://doi.org/10.1134/S1070328419020039

    CAS  Article  Google Scholar 

  21. 21

    Wang, S.M., Sun, X.L., Zheng, X.Y., et al., Russ. J. Coord. Chem., 2018, vol. 44, p. 82. https://doi.org/10.1134/S1070328417120119

    CAS  Article  Google Scholar 

  22. 22

    Gogoleva, N.V., Shmelev, M.A., Evstifeev, I.S., et al., Russ. Chem. Bull., 2016, vol. 65, p. 181.

    CAS  Article  Google Scholar 

  23. 23

    Nikolaevskii, S.A., Evstifeev, I.S., Kiskin, M.A., et al., Polyhedron, 2018, vol. 152, p. 61.

    CAS  Article  Google Scholar 

  24. 24

    Kiraev, S.R., Nikolaevskii, S.A., Kiskin, M.A., et al., Inorg. Chim. Acta, 2018, vol. 477, p. 15.

    CAS  Article  Google Scholar 

  25. 25

    Nikolaevskii, S.A., Koshchienko, Y.V., Chernyshev, A.V., et al., Russ. J. Coord. Chem., 2014, vol. 40, p. 468. https://doi.org/10.1134/S1070328414070070

    CAS  Article  Google Scholar 

  26. 26

    Yang, E.C., Zhao, H.K., Ding, B., et al., Cryst. Growth Des., 2007, vol. 7, p. 2009.

    CAS  Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors thank financial assistance from the Key Scientific Research Project of Education Department of Shaanxi Province (17JS027) and this work is also supported by team of syngas catalytic conversion of Shaanxi university of Technology.

Author information

Affiliations

Authors

Corresponding author

Correspondence to J. Song.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Song, J., Duan, B.F., Wu, R. et al. Two Cd(II) Coordination Compounds Based on the Flexible N-Bridging Ligands: Syntheses, Crystal Structures and Luminescent Properties. Russ J Coord Chem 47, 75–80 (2021). https://doi.org/10.1134/S1070328421010073

Download citation

Keywords:

  • hydro-solvothermal technique
  • crystal structure
  • luminescent property