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Synthesis and Structural Characterization of the Ruthenium Complex Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and FcCH(OH)C≡CH

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Abstract

A new complex [(p-Cymene)Ru(S2C2B10H9)(CH2CCH(OH)Fc)]2 · 0.5H2O (Fc = ferrocenyl) based on the 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand and FcCH(OH)C≡CH has been synthesized successfully and characterized by IR, NMR, MS, elemental analysis and single-crystal X-ray diffraction, in which the alkyne is inserted into one of the Ru–S bonds that may further lead to metal-induced B‒H activation, hydrogen atom transfer from the carborane via the metal center to the inserted alkyne, and the generation of a Ru–B bond. The complex crystallizes in triclinic system, space group \(P\bar {1}\) with a = 12.7329(5), b = 13.8422(5), c = 20.0796(7) Å, α = 87.249(3)°, β = 89.311(3)°, γ = 62.961(4)°, C50H73B20O2.5S4Fe2Ru2, Mr = 1372.37, V = 3148.39(19) Å3, ρc = 1.448 g/cm3, Z = 1, F(000) = 1394, µ(MoKα) = 1.094 mm–1, R = 0.0473 and ωR = 0.0990 for 9294 observed reflections (I > 2σ(I)).

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ACKNOWLEDGMENTS

This work was supported by the National Natural Science Foundation of China (no. 21261020), the Science and Technology Research Projects of the Education Department of Jiangxi Province (no. GJJ170921), and the Research Fund of Shangrao Normal University (no. G201803).

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Authors and Affiliations

  1. School of Chemistry and Environmental Sciences, Shangrao Normal University, 334001, Jiangxi, P.R. China

    J. R. Hu, K. G. Jin & C. P. Zhu

  2. School of Music and Dance, Shangrao Normal University, 334001, Jiangxi, P.R. China

    J. H. Wang

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  1. J. R. Hu
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  2. J. H. Wang
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  3. K. G. Jin
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  4. C. P. Zhu
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Correspondence to J. R. Hu.

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Hu, J.R., Wang, J.H., Jin, K.G. et al. Synthesis and Structural Characterization of the Ruthenium Complex Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and FcCH(OH)C≡CH. Russ J Coord Chem 46, 437–442 (2020). https://doi.org/10.1134/S1070328420060019

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