Skip to main content
Log in

Structural Features of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes with Oxygen Atoms of Tridentate Chelating (O,N,S) Ligands

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The structural features of 31 mononuclear octahedral d2-Re(V) monooxo complexes with tridentate chelating (O,N,S) ligands, [ReO\(\left( {{\text{L}}_{{{\text{tri}}}}^{m}} \right)\)\(\left( {{\text{L}}_{{{\text{bi}}}}^{n}} \right)\)] and [ReO\(\left( {{\text{L}}_{{{\text{tri}}}}^{m}} \right)\)(Lmono)2] (Lmono = Cl, Br, OMe, OPPh3, PPh3) are considered. The Re–O\({{\left( {{\text{L}}_{{{\text{tri}}}}^{m}} \right)}_{{trans}}}{\kern 1pt} ,\) Re–O\({{\left( {{\text{L}}_{{{\text{bi}}}}^{n}} \right)}_{{trans}}}{\kern 1pt} ,\) and Re–O(OMe) bonds in 14 complexes were found to be commensurable in length with (or shorter than) analogous cis-bonds. This indicates the presence of pseudo-dioxo ReO2 groups in these structures with increased orders of both Re–O bonds located in trans-positions relative to each other. In the structures of 12 compounds, the Re–O(Ltri)trans, Re–O(Lbi)trans, and Re–O(OPPh3) bonds are markedly longer than analogous cis-bonds in accordance with the structural consequences of the trans-effect of a multiply bonded oxo ligand.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Porai-Koshits, M.A. and Gilinskaya, E.A. Kristallokhimiya, Moscow, VINITI, 1966, p. 126.

  2. Porai-Koshits, M.A. and Atovmyan, L.O., Koord. Khim., 1975, vol. 1, p. 1271.

    CAS  Google Scholar 

  3. Griffith, F. and Wicing, C., J. Chem. Soc. A, 1968, no. 2, p. 379.

  4. Porai-Koshits, M.A., Izv. Yugosl. Kristallogr. Tsentra, 1974, vol. 9, p. 19.

    Google Scholar 

  5. Porai-Koshits, M.A. and Atovmyan, L.O., Kristallokhimiya koordinatsionnykh soedinenii molibdena (Crystal Chemistry of Coordination Compounds of Molybdenum), Moscow: Nauka, 1974.

  6. Shustorovich, E.M., Porai-Koshits, M.A., and Buslaev, Yu.A., Coord. Chem. Rev., 1975, vol. 17, no. 1, p. 1.

    Article  CAS  Google Scholar 

  7. Porai-Koshits, M.A. and Sergienko, V.S., Usp. Khim., 1990, vol. 59, no. 1, p. 86.

    Article  CAS  Google Scholar 

  8. Allen, F.H., Acta Crystallogr., Sect. B: Struct. Sci., 2002, vol. 58, no. 2, p. 380.

    Article  CAS  Google Scholar 

  9. Sergienko, V.S., Russ. J. Inorg. Chem., 2018, vol. 63, no. 14, p. 1764. https://doi.org/10.1134/S0036023618140048

    Article  CAS  Google Scholar 

  10. Sergienko, V.S. and Strashnova, S.B., Russ. J. Inorg. Chem., 2019, vol. 64, no. 7, p. 882. https://doi.org/10.1134/S0036023619070143

  11. Sergienko, V.S., Russ. J. Coord. Chem., 2019, vol. 45, no. 6, p. 439. https://doi.org/10.1134/S1070328419060071

  12. Sergienko, V.S. and Churakov A.V., Russ. J. Coord. Chem., 2019, vol. 45, no. 5, p. 276. https://doi.org/10.1134/S1070328419030072

  13. Sergienko, V.S., Russ. J. Inorg. Chem., 2019, vol. 64, no. 4, p. 460. https://doi.org/10.1134/S0036023618040174

    Article  Google Scholar 

  14. Sergienko, V.S. and Churakov, A.V., Crystallogr. Rep., 2013, vol. 58, no. 1, p. 5.

    Google Scholar 

  15. Sergienko, V.S. and Churakov, A.V., Crystallogr. Rep., 2014, vol. 59, no. 3, p. 300.

    Article  CAS  Google Scholar 

  16. Chen, X., Femia, F.J., Babich, J.W., and Zubieta, J., Inorg. Chim. Acta, 2000, vol. 307, no. 2, p. 149.

    Article  CAS  Google Scholar 

  17. Meveles, F., Roucoux, A., Noiret, N., and Patin, H., Dalton Trans., 2001, no. 10, p. 3603.

  18. Abram, U., Alberto, R., Dilworth, J.R., et al., Polyhedron, 1999, vol. 18, no. 8, p. 2995.

    Article  CAS  Google Scholar 

  19. Schroer, J. and Abram, U., Polyhedron, 2009, vol. 28, no. 6, p. 2277.

    Article  CAS  Google Scholar 

  20. Traar, P., Schröckender, A., Judmaier, M.E., et al., Eur. J. Inorg. Chem., 2010, no. 20, p. 5718.

  21. Tessier, C., Rochon, F.D., and Beauchamp, A.L., Inorg. Chem., 2004, vol. 43, no. 23, p. 7463.

    Article  CAS  PubMed  Google Scholar 

  22. Tshentu, Z.R., Gerber, T.L.A., and Mayer, P., Bull. Chem. Soc. Ethiop., 2007, vol. 21, no. 1, p. 75.

    Article  CAS  Google Scholar 

  23. Gerber, T.L.A., Mayer, P., and Tshentu, Z.R., J. C-oord. Chem., 2005, vol. 58, no. 17, p. 1589.

    CAS  Google Scholar 

  24. Gerber, T.L.A., Tshentu, Z.R., and Mayer, P., J. C-oord. Chem., 2003, vol. 56, no. 15, p. 1357.

    CAS  Google Scholar 

  25. Gerber, T.L.A., Luzipo, D., and Mayer, P., J. Coord. Chem., 2003, vol. 56, no. 17, p. 1549.

    Article  CAS  Google Scholar 

  26. Tessier, C., Rochon, F.D., and Beauchamp, A.L., Inorg. Chem., 2002, vol. 41, no. 21, p. 6527.

    Article  CAS  PubMed  Google Scholar 

  27. Huy, N.H., Grewe, J., Schroer, J., et al., Inorg. Chem., 2008, vol. 47, no. 12, p. 5136.

    Article  CAS  Google Scholar 

  28. Nock, B., Maina, T., Tisato, F., et al., Inorg. Chem., 2000, vol. 39, no. 23, p. 5197.

    Article  CAS  PubMed  Google Scholar 

  29. Femia, F.J., Chen, X., Babich, J.W., and Zubieta, J., Inorg. Chim. Acta, 2001, vol. 316, no. 2, p. 145.

    Article  CAS  Google Scholar 

  30. Nguen, H.H. and Abrum, U., Polyhedron, 2009, vol. 28, no. 10, p. 3945.

    Article  CAS  Google Scholar 

  31. Nguen, H.H., Deflon, V.M., and Abrum, U., Eur. J. Inorg. Chem., 2009, p. 3179.

  32. Sawusch, S., Shilde, U., Starke, I., et al., Inorg. Chim. Acta, 1998, vol. 268, no. 2, p. 109.

    Article  CAS  Google Scholar 

  33. Gerber, T.I.A., Preetz, I.G.H., Jacobs, R., and van Brecht, B.J.A.M., J. Coord. Chem., 1994, vol. 31, no. 1, p. 31.

    Article  CAS  Google Scholar 

  34. Kirsch, S., Noll, B., Spies, H., et al., J. Chem. Soc., Dalton Trans., 1998, no. 4, p. 455.

  35. Franklin, K.J., Howardp-Look, H.E., and Lock, C.J.L., Inorg. Chem., 1982, vol. 21, no. 4, p. 1941.

    Article  CAS  Google Scholar 

  36. Kirrsch, S., Jankowski, R., Leibnitz, P., et al., J. Biol. Inorg. Chem., 1999, vol. 4, no. 1, p. 48.

    Article  Google Scholar 

  37. Konno, T., Shimazaki, Y., Kawai, M., and Hirotsu, M., Inorg. Chem., 2001, vol. 40, no. 17, p. 4250.

    Article  CAS  PubMed  Google Scholar 

  38. Mevelles, F., Rucoux, A., Noiret, H., and Patin, H., Inorg. Chim. Acta, 2002, vol. 332, no. 1, p. 30.

    Article  Google Scholar 

  39. Chiotellis, A., Tsoukalas, C., Pelecanou, M., et al., Inorg. Chem., 2006, vol. 45, no. 14, p. 5635.

    Article  CAS  PubMed  Google Scholar 

  40. Papagiannopoulou, I., Pirmettis, I., Pelecanou, M., et al., Inorg. Chim. Acta, 2007, vol. 360, no. 11, p. 3597.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. S. Sergienko.

Additional information

Translated by Z. Svitanko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sergienko, V.S., Churakov, A.V. Structural Features of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes with Oxygen Atoms of Tridentate Chelating (O,N,S) Ligands. Russ J Coord Chem 45, 651–666 (2019). https://doi.org/10.1134/S1070328419080074

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328419080074

Keywords:

Navigation