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The Nature of Conformational Polymorphism in the Crystals of Ph3Sb(O2CCH2–CH=CH2)2

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Abstract

Crystallization of the Ph3Sb(O2CCH2−CH=CH2)2 complex upon fast solvent (benzene) evaporation gives monoclinic crystals (I), whereas in the case of slow evaporation, triclinic crystals are formed (II). Also, monoclinic crystals are spontaneously transformed into triclinic crystals within 6 months. It was shown that the presence of voids near one carboxylate ligand in the monoclinic phase of Ph3Sb-(O2CCH2−CH=CH2)2 decreases the energy of intermolecular interactions and, as a consequence, leads to a conformational transition with a noticeable decrease in the crystal lattice energy. Thus, the presence of voids in the monoclinic phase crystal allows the formation of a thermodynamically more favorable conformation of the molecule in the crystal. Several structural models were determined for the Ph3Sb(O2CCH2−CH=CH2)2 complex (CIF files no. 1887561 (IIAM), model of non-interacting atoms; 1887562 (I), multipole model; 1887563 (IIIAM), model of non-interacting atoms; 1887564 (II), multipole model).

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ACKNOWLEDGMENTS

This work was performed using the scientific equipment of the Center for Collective use “Analytical Center of the Institute of Organometallic Chemistry, Russian Academy of Sciences.”

Funding

This work was supported by the Russian Foundation for Basic Research (project no. 17-03-01257).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137, Nizhny Novgorod, Russia

    G. K. Fukin, E. V. Baranov, A. V. Cherkasov & R. V. Rumyantsev

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  1. G. K. Fukin
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  2. E. V. Baranov
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  3. A. V. Cherkasov
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  4. R. V. Rumyantsev
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Correspondence to G. K. Fukin.

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Translated by Z. Svitanko

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Fukin, G.K., Baranov, E.V., Cherkasov, A.V. et al. The Nature of Conformational Polymorphism in the Crystals of Ph3Sb(O2CCH2–CH=CH2)2. Russ J Coord Chem 45, 585–591 (2019). https://doi.org/10.1134/S1070328419080025

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