Skip to main content
SpringerLink
Log in

Samarium, Europium, and Gadolinium Complexes with 4-(2,1,3-Benzothiadiazol-4-ylamino)pent-3-en-2-onate

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

New lanthanide complexes with 4-(2,1,3-benzothiadiazol-4-ylamino)pent-3-en-2-onate (L–) [Ln(L)3] are synthesized using two methods: by the reaction of Ln(N(SiMe3)2)3 with the protonated form of the ligand LH (Ln = Sm, Gd) and by the reaction of LnCl3 (Ln = Eu) with LH in the presence of KN(SiMe3)2 as a base. According to the X-ray diffraction data, the synthesized complexes [Ln(L)3] · 0.5Solv (Solv = THF, C7H8) are isotypical (CIF files CCDC nos. 1826520, 1826521, and 1826522 for Sm, Eu, and Gd, respectively). A specific feature of the structures is the disordering of the metal atom and one of the ligands over two positions when the fragments of the ligands are arranged via the head-to-tail type occupying the same volume of the space. This probably leads to failure in the crystal lattice. The photoluminescence spectra of [Sm(L)3] · 0.5THF are recorded. A relationship between the coordination mode of the ligand and the position of the long-wavelength band of the electron transitions in the complexes with the L– ligand is revealed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Neto, B.A.D., Lapis, A.A.M., da Silva Júnior, E.N., et al., Eur. J. Org. Chem., 2013, p. 228.

  2. Gu, C., Liu, D., Wang, J., et al., J. Mater. Chem. A, 2018, vol. 6, p. 2371.

    Article  CAS  Google Scholar 

  3. Crossley, D.L., Urbano, L., Neumann, R., et al., ACS Appl. Mater. Interfaces, 2017, vol. 9, p. 28243.

    Article  CAS  PubMed  Google Scholar 

  4. Chulanova, E.A., Pritchina, E.A., Malaspina, L.A., et al., Chem.-Eur. J., 2017, vol. 23, p. 852.

    Article  CAS  PubMed  Google Scholar 

  5. Lonchakov, A. and Rakitin, O., Gritsan, N., et al., Molecules, 2013, vol. 18, p. 9850.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  6. Xu, Z., Kong, L., Wang, Y., et al., Org. Electron., 2018, vol. 54, p. 94.

    Article  CAS  Google Scholar 

  7. Neto, B.A.D., Carvalho, P.H.P.R., and Correa, J.R., Acc. Chem. Res., 2015, vol. 48, p. 1560.

    Article  CAS  PubMed  Google Scholar 

  8. da Cruz, E.H.G., Carvalho, P.H.P.R., Correa, J.R., et al., New J. Chem., 2014, vol. 38, p. 2569.

    Article  CAS  Google Scholar 

  9. Mota, A.A.R., Corrêa, J.R., Carvalho, P.H.P.R., et al., Org. Chem., 2016, vol. 81, p. 2958.

    Article  CAS  Google Scholar 

  10. Aguiar, L.D.O., Regis, E., Tuzimoto, P., et al., Liq. Cryst., 2018, vol. 45, p. 49.

    Article  CAS  Google Scholar 

  11. Langis-Barsetti, S., Maris, T., and Wuest, J.D., Org. Chem., 2017, vol. 82, p. 5034.

    Article  CAS  Google Scholar 

  12. Cheng, Q., Han, X., Tong, Y., et al., Inorg. Chem., 2017, vol. 56, p. 1696.

    Article  CAS  PubMed  Google Scholar 

  13. Plebst, S., Bubrin, M., Schweinfurth, D., et al., Z. Naturforsch., A: Phys. Sci., 2017, vol. 72, p. 839.

    CAS  Google Scholar 

  14. Goswami, S., Winkel, R.W., and Schanze, K.S., Inorg. Chem., 2015, vol. 54, p. 10007.

    Article  CAS  PubMed  Google Scholar 

  15. Mancilha, F.S., Barloy, L., Rodembusch, F.S., et al., Dalton Trans., 2011, vol. 40, p. 10535.

    Article  CAS  PubMed  Google Scholar 

  16. Gallardo, H., Conte, G., Bortoluzzi, A.J., et al., Inorg. Chim. Acta, 2011, vol. 365, p. 152.

    Article  CAS  Google Scholar 

  17. Gallardo, H., Conte, G., Tuzimoto, P., et al., Inorg. Chem. Commun., 2008, vol. 11, p. 1292.

    Article  CAS  Google Scholar 

  18. Sukhikh, T.S., Bashirov, D.A., Ogienko, D.S., et al., RSC Adv., 2016, vol. 6, p. 43901.

    Article  CAS  Google Scholar 

  19. Sukhikh, T.S., Ogienko, D.S., Bashirov, D.A., et al., J. Coord. Chem., 2016, vol. 69, p. 3284.

    Article  CAS  Google Scholar 

  20. Sukhikh, T.S., Komarov, V.Y., Konchenko, S.N., et al., Polyhedron, 2018, vol. 139, p. 33.

    Article  CAS  Google Scholar 

  21. Sukhikh, T.S., Bashirov, D.A., Shuvaev, S., et al., Polyhedron, 2018, vol. 141, p. 77.

    Article  CAS  Google Scholar 

  22. Sukhikh, T.S., Bashirov, D.A., Kolybalov, D.S., et al., Polyhedron, 2017, vol. 124, p. 139.

    Article  CAS  Google Scholar 

  23. Sukhikh, T.S., Bashirov, D.A., Kuratieva, N.V., et al., Dalton Trans., 2015, vol. 44, p. 5727.

    Article  CAS  PubMed  Google Scholar 

  24. Herrmann, W.A., Synthetic Methods of Organometallic and Inorganic Chemistry: Lanthanides and Actinides, Thieme Publishing Group, 1997, vol. 6.

    Google Scholar 

  25. APEX2 (version 2.0). SAINT (version 8.18c), and SAD-ABS (version 2.11), Madison: Bruker Advanced X‑ray Solutions, 2000−2012.

  26. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  27. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  CAS  Google Scholar 

  28. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  29. Armelao, L., Quici, S., Barigelletti, F., et al., Coord. Chem. Rev., 2010, vol. 254, p. 487.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are grateful to A.P. Zubareva and O.S. Koshcheeva for performing elemental analysis and to A.A. Ryadun for recording luminescence spectra.

This work was carried out in terms of the state task and was supported by the Russian Foundation for Basic Research, project no. 16-03-00637.

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    T. S. Sukhikh, D. S. Ogienko, D. A. Bashirov, N. V. Kurat’eva, A. I. Smolentsev & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    T. S. Sukhikh, D. A. Bashirov, N. V. Kurat’eva & S. N. Konchenko

Authors
  1. T. S. Sukhikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. S. Ogienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. A. Bashirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. V. Kurat’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. I. Smolentsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. N. Konchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. S. Sukhikh.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sukhikh, T.S., Ogienko, D.S., Bashirov, D.A. et al. Samarium, Europium, and Gadolinium Complexes with 4-(2,1,3-Benzothiadiazol-4-ylamino)pent-3-en-2-onate. Russ J Coord Chem 45, 30–35 (2019). https://doi.org/10.1134/S1070328419010111

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328419010111

Keywords:

Search

Navigation