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Structures, Photoluminescence, and Photocatalytic Properties of Two New Coordination Polymers based on 4-nitroimidazolate

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Abstract

The reaction of AgNO3/Ni(NO3)2 · 6H2O with 4-nitroimidazolate (HNim) gave two new coordination poymers of [Ag(Nim)]n (I) and [Ni(Nim)(H2O)4]n (II). X-ray single-crystal analyses (СIF files CCDC nos. 1508955 (I) and 1821871 (II)) reveal that I and II show 2D grid layer and mononuclear network, respectively. The photoluminescence investigation indicates that I could be a prospective candidate for developing luminescence sensors for the highly sensing of Fe3+ analyte. Furthermore, the photocatalysis properties of II for degradation of the methyl violet and Rhodamine B have been examined.

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ACKNOWLEDGMENTS

The authors acknowledge financial assistance from Sichuan University of Science and Engineering (nos. 2015RC26, 2015RC29 and 2017RCL02), the Education Committee of Sichuan Province (no. 17ZA0264), the Project of Zigong Science and Technology (no. 2016HG06) and the Opening Project of Key Laboratory of Green Catalysis of Sichuan Institutes of High Education (no. LYJ1705).

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Authors and Affiliations

  1. School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong,, P.R. China

    D. Zhou, L. Lu, Y. Luo, F. Chen, J. R. He & M. W. Dong

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  1. D. Zhou
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  2. L. Lu
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  3. Y. Luo
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  4. F. Chen
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  5. J. R. He
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Correspondence to L. Lu.

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Zhou, D., Lu, L., Luo, Y. et al. Structures, Photoluminescence, and Photocatalytic Properties of Two New Coordination Polymers based on 4-nitroimidazolate. Russ J Coord Chem 44, 812–817 (2018). https://doi.org/10.1134/S1070328418120126

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  • DOI: https://doi.org/10.1134/S1070328418120126

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