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Replacement of Ligands in a Molecule of Polyhedral Phenylmetallosiloxane Containing Nickel and Sodium Ions

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Abstract

The possibility of the partial or complete substitution of the outer-sphere solvate shell of n-butanol molecules by the nitrogen-containing compounds in the phenylnickelsodiumsiloxane complex. The high-symmetry spatially fixed rigidly cationic layer retains its structure. The obtained complexes Na2(μ-H2O)2(n-BuOH)2{[C6H5SiO2]6Ni4Na4(μ3-OH)2[C6H5SiO2]6} · 8(n-BuOH) · 2NH3 (II) and {[C6H5SiO2]6Ni4Na6(μ3-OH)2[C6H5SiO2]6} · 4(μ-C3H7NO) · 6(C3H7NO) · 2.8(H2O) · 0.6(C3H7NO) (III) are studied by X-ray diffraction analysis (CIF files CCDC nos. 1810736 (II) and 1810737 (III)).

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ACKNOWLEDGMENTS

The structures of the synthesized compounds were studied using the equipment of the Center for Molecule Composition Studies of the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences).

This work was supported by the Russian Science Foundation, project no. 14-23-00231.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. S. Vysochinskaya, P. V. Zhemchugov, A. A. Anisimov, F. M. Dolgushin, O. I. Shchegolikhina & A. M. Muzafarov

  2. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russia

    Yu. S. Vysochinskaya & A. M. Muzafarov

Authors
  1. Yu. S. Vysochinskaya
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  2. P. V. Zhemchugov
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  3. A. A. Anisimov
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  4. F. M. Dolgushin
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  5. O. I. Shchegolikhina
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  6. A. M. Muzafarov
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Corresponding authors

Correspondence to A. A. Anisimov or O. I. Shchegolikhina.

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Translated by E. Yablonskaya

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Vysochinskaya, Y.S., Zhemchugov, P.V., Anisimov, A.A. et al. Replacement of Ligands in a Molecule of Polyhedral Phenylmetallosiloxane Containing Nickel and Sodium Ions. Russ J Coord Chem 44, 653–659 (2018). https://doi.org/10.1134/S1070328418110088

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  • DOI: https://doi.org/10.1134/S1070328418110088

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