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Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis

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Abstract

Controlled hydrolysis of the terbium cyclopentadienyl complexes results in the formation of the heteroligand tetranuclear terbium complex [{Tb(η5-C5H5)}3{Tb(THF)3}(μ3-Cl)(μ2-Cl)6(μ4-O)] (I), the recrystallization of which from tetrahydrofuran (THF) gives solvatomorph I · 0.5THF (Ia). According to the X-ray structure analysis data (CIF files CCDC 1569329 (I) and 1569330 (Ia)), the complexes are tetrahedral with the μ4-bridging O2– anion at the center of the tetrahedron. The cyclopentadienyl ligand in complex I is shown to act as an “antenna” providing luminescence of the complex.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119992, Russia

    D. M. Roitershtein, M. D. Dobrokhodov, A. A. Vinogradov, M. E. Minyaev & I. E. Nifant’ev

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    D. M. Roitershtein

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    K. A. Lyssenko & I. V. Taidakov

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. V. Churakov

  5. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russia

    N. P. Datskevich & I. V. Taidakov

  6. Moscow State University, Moscow, 119899, Russia

    I. E. Nifant’ev

Authors
  1. D. M. Roitershtein
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  2. M. D. Dobrokhodov
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  3. A. A. Vinogradov
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  4. M. E. Minyaev
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  5. K. A. Lyssenko
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  6. A. V. Churakov
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  7. N. P. Datskevich
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  8. I. V. Taidakov
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  9. I. E. Nifant’ev
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Correspondence to D. M. Roitershtein.

Additional information

Original Russian Text © D.M. Roitershtein, M.D. Dobrokhodov, A.A. Vinogradov, M.E. Minyaev, K.A. Lyssenko, A.V. Churakov, N.P. Datskevich, I.V. Taidakov, I.E. Nifant’ev, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 3, pp. 206–210.

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Roitershtein, D.M., Dobrokhodov, M.D., Vinogradov, A.A. et al. Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis. Russ J Coord Chem 44, 410–414 (2018). https://doi.org/10.1134/S1070328418060052

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  • DOI: https://doi.org/10.1134/S1070328418060052

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