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Russian Journal of Coordination Chemistry

, Volume 44, Issue 6, pp 380–387 | Cite as

Gallium Complexes with Acenaphthene-1-Imino-2-one: Synthesis and Reactivity

  • D. A. Razborov
  • A. N. Lukoyanov
  • M. V. Moskalev
  • E. V. Baranov
  • I. L. Fedyushkin
Article
  • 17 Downloads

Abstract

The reduction of acenaphthene-1-(2,6-diisopropylphenyl)imino-2-one (Dpp-Mian) by gallium in the presence of iodine primarily results in a bis(ligand) paramagnetic derivative [(Dpp-Mian)2GaI] and then to a dimeric diamagnetic complex [(Dpp-Mian)GaI]2, the reaction of which with PhC≡CH gives a cycloaddition product [{Dpp-Mian(HC=CPh)}GaI]2. The new compounds are characterized by IR spectroscopy and 1H NMR spectroscopy. The structures of complexes (Dpp-Mian)2GaI and [{Dpp- Mian(HC=CPh)}GaI]2 are determined by X-ray structure analysis (CIF files CCDC nos. 1571860 and 1571861, respectively). The catalytic activity tests for compounds [(Dpp-Mian)GaI]2 and [{Dpp-Mian(HC=CPh)}GaI]2 are conducted in the reactions of 4-chloroaniline with phenylacetylene and carbodiimide and in the reaction of phenylacetylene with 1-naphthol.

Keywords

gallium N,O-ligands synthesis structure X-ray structure analysis hydroamination and hydroarylation of unsaturated substrates 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • D. A. Razborov
    • 1
  • A. N. Lukoyanov
    • 1
  • M. V. Moskalev
    • 1
  • E. V. Baranov
    • 1
  • I. L. Fedyushkin
    • 1
  1. 1.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussia

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