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Gallium Complexes with Acenaphthene-1-Imino-2-one: Synthesis and Reactivity

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Abstract

The reduction of acenaphthene-1-(2,6-diisopropylphenyl)imino-2-one (Dpp-Mian) by gallium in the presence of iodine primarily results in a bis(ligand) paramagnetic derivative [(Dpp-Mian)2GaI] and then to a dimeric diamagnetic complex [(Dpp-Mian)GaI]2, the reaction of which with PhC≡CH gives a cycloaddition product [{Dpp-Mian(HC=CPh)}GaI]2. The new compounds are characterized by IR spectroscopy and 1H NMR spectroscopy. The structures of complexes (Dpp-Mian)2GaI and [{Dpp- Mian(HC=CPh)}GaI]2 are determined by X-ray structure analysis (CIF files CCDC nos. 1571860 and 1571861, respectively). The catalytic activity tests for compounds [(Dpp-Mian)GaI]2 and [{Dpp-Mian(HC=CPh)}GaI]2 are conducted in the reactions of 4-chloroaniline with phenylacetylene and carbodiimide and in the reaction of phenylacetylene with 1-naphthol.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, 603600, Russia

    D. A. Razborov, A. N. Lukoyanov, M. V. Moskalev, E. V. Baranov & I. L. Fedyushkin

Authors
  1. D. A. Razborov
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  2. A. N. Lukoyanov
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  3. M. V. Moskalev
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  4. E. V. Baranov
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  5. I. L. Fedyushkin
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Corresponding author

Correspondence to I. L. Fedyushkin.

Additional information

Original Russian Text © D.A. Razborov, A.N. Lukoyanov, M.V. Moskalev, E.V. Baranov, I.L. Fedyushkin, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 3, pp. 176–183.

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Razborov, D.A., Lukoyanov, A.N., Moskalev, M.V. et al. Gallium Complexes with Acenaphthene-1-Imino-2-one: Synthesis and Reactivity. Russ J Coord Chem 44, 380–387 (2018). https://doi.org/10.1134/S1070328418060040

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  • DOI: https://doi.org/10.1134/S1070328418060040

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