Abstract
A new coordination polymer [Cu(H2Tci)2(Bipy)(H2O)] · 2H2O (I) (H3Tci = tris(2-carboxyethyl)isocyanurate, Bipy = 4,4′-bipyridine) has been synthesized and characterized by elemental analysis, IR, and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I (C34H42CuN8O21) crystallizes in the monoclinic crystal system, space group P21/c. In I, the metal centers are linked by Bipy ligands to generate an infinite linear chain and the H2Tci ligands adopt monodentate coordination mode to graft the linear chain. The adjacent chains are linked by hydrogen bonds to form a three-dimensional supramolecular framework.
Similar content being viewed by others
References
Yan, Y., Telepeni, I., Yang, S.H., et al., J. Am. Chem. Soc., 2010, vol. 132, no. 12, p. 4092.
Zhang, Y.J., Liu, T., Kanegawa, S., and Sato, O., J. Am. Chem. Soc., 2010, vol. 132, no. 3, p. 912.
Jia, J., Shao, M., Jia, T.T., et al., CrystEngComm., 2010, vol. 12, p. 1548.
Uribe-Romo, F.J., Hunt, J.R., Furukawa, H., et al., J. Am. Chem. Soc., 2010, vol. 131, no. 13, p. 4570.
Yue, Q., Yan, L., Zhang, J.Y., and Gao, E.Q., Inorg. Chem., 2010, vol. 49, no. 19, p. 8647.
Wang, T.W., Liu, D.S., Huang, C.C., et al., Cryst. Growth Des., 2010, vol. 10, no. 8, p. 3429.
Yu, Q., Zeng, Y.F., Zhao, J.P., et al., Inorg. Chem., 2010, vol. 49, no. 9, p. 4301.
Kang, L.C., Chen, X., Wang, H.S., et al., Inorg. Chem., 2010, vol. 49, no. 20, p. 9275.
White, K.A., Chengelis, D.A., Gogick, K.A., et al., J. Am. Chem. Soc., 2009, vol. 131, no. 50, p. 18069.
Lu, W.G., Jiang, L., Feng, X.L., and Lu, T.B., Inorg. Chem., 2009, vol. 48, no. 15, p. 6997.
Dang, D.B., Bai, Y., He, C., et al., Inorg. Chem., 2010, vol. 49, no. 4, p. 1280.
An, J. and Rosi, N.L., J. Am. Chem. Soc., 2010, vol. 132, no. 16, p. 5579.
Wang, D.X., He, H.Y., Chen, X.X., et al., CrystEng-Comm., 2010, vol. 12, p. 1041.
Dai, F.N., He, H.Y., Gao, D., et al., CrystEngComm., 2009, vol. 11, p. 2516.
Gomez, V., Corbella, M., Bardia, M.F., and Calvet, T., Dalton Trans., 2010, vol. 39, p. 11664.
Wang, R.M., Zhang, J., and Li, L.J., Inorg. Chem., 2009, vol. 48, no. 15, p. 7194.
Luo, J.H., Xu, H.W., Liu, Y., et al., J. Am. Chem. Soc., 2008, vol. 130, no. 30, p. 9626.
Koh, K., Wong-Foy, A.G., and Matzger, A.J., Angew. Chem. Int. Ed., 2008, vol. 47, p. 677.
Han, Z.B. and Zhang, G.X., CrystEngComm., 2010, vol. 12, p. 348.
Han, Z.B., Zhang, G.X., Zeng, M.H., et al., Inorg. Chem., 2010, vol. 49, no. 3, p. 769.
Han, Z.B., Zhang, G.X., Zeng, M.H., et al., CrystEng-Comm., 2009, vol. 11, p. 2629.
Ghosha, S.K. and Kitagawa, S., CrystEngComm., 2008, vol. 10, p. 1739.
Liang, L.L., Cai, Y.G., Weng, N.S., et al., Inorg. Chem. Commun., 2009, vol. 12, p. 86.
Sheldrick, G.M., Acta Crystallogr., A, 1990, vol. 46, no. 6, p. 467.
Sheldrick, G.M., SHELX-97, Program for Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.
Sheldrick, G.M., SHELXTL-97, Program for Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Zhang, M.Y., Zhang, G.X., Gao, J.Q. et al. A 1D linear chain coordination polymer constructed by Cu(II) with H3Tci and Bipy ligands (H3Tci = tris(2-carboxyethyl)isocyanurate, Bipy = 4,4′-bipyridine). Russ J Coord Chem 38, 279–283 (2012). https://doi.org/10.1134/S1070328412040124
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328412040124