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Hydrothermal synthesis and crystal structure of a new 2D metal-organic framework: [Gd(Oba)(Ox)0.5(H2O)2] n (H2Oba = 4,4′-oxybis(benzoic acid); H2Ox = oxalic acid)

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Abstract

A new coordination polymer [Gd(Oba)(Ox)0.5(H2O)2] n (I) (H2Oba = 4,4′-oxybis(benzoic acid), H2Ox = oxalic acid) has been synthesized by hydrothermal reactions and characterized by elemental analysis and single-crystal X-ray diffraction. In I, two Gd3+ ions are bridged by Oba ligands to form 1D ribbon chains, which are further connected by Ox ligands, generating a 2D layer structure.

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References

  1. Yao, X.Q., Cao, D.P., Hu, J.S., et al., Cryst. Growth Des., 2011, vol. 11, no. 1, p. 231.

    Article  CAS  Google Scholar 

  2. Uribe-Romo, F.J., Hunt, J.R., Furukawa, H., et al., J. Am. Chem. Soc., 2010, vol. 131, no. 13, p. 4570.

    Article  Google Scholar 

  3. Banerjee, D., Kim, S.J., Wu, H.H., et al., Inorg. Chem., 2011, vol. 50, no. 1, p. 208.

    Article  CAS  Google Scholar 

  4. An, J. and Rosi, N.L., J. Am. Chem. Soc., 2010, vol. 132, no. 16, p. 5579.

    Article  Google Scholar 

  5. Wang, D.X., He, H.Y., Chen, X.X., et al., CrystEng-Comm., 2010, vol. 12, p. 1041.

    CAS  Google Scholar 

  6. Sharma, M.K., Senkovska, I., Kaskel, S., et al., Inorg. Chem., 2011, vol. 50, no. 2, p. 539.

    Article  CAS  Google Scholar 

  7. Zhang, Y.J., Liu, T., Kanegawa, S., and Sato, O., J. Am. Chem. Soc., 2010, vol. 132, no. 3, p. 912.

    Article  CAS  Google Scholar 

  8. Zhang, C.Y., Che, Y.K., Zhang, Z.X., et al., Chem. Commun., 2011, vol. 47, p. 2336.

    Article  CAS  Google Scholar 

  9. Li, H.L. and Sun, X.P., Chem. Commun., 2011, vol. 47, p. 2625.

    Article  CAS  Google Scholar 

  10. Jia, L.H., Li, R.Y., Duan, Z.M., et al., Inorg. Chem., 2011, vol. 50, no. 1, p. 144.

    Article  CAS  Google Scholar 

  11. Yu, Q., Zeng, Y.F., Zhao, J.P., et al., Inorg. Chem., 2010, vol. 49, no. 9, p. 4301.

    Article  CAS  Google Scholar 

  12. Zeng, M.H., Wang, Q.X., Tan, Y.X., et al., J. Am. Chem. Soc., 2010, vol. 132, no. 8, p. 2561.

    Article  CAS  Google Scholar 

  13. Zheng, X.L., Liu, Y., Pan, M., et al., Angew. Chem. Int. Ed., 2007, vol. 46, p. 7399.

    Article  CAS  Google Scholar 

  14. Chandrasekhar, V., Pandian, B.M., Vittal, J.J., and Clérac, R., Inorg. Chem., 2009, vol. 48, no. 3, p. 1148.

    Article  CAS  Google Scholar 

  15. Lama, P., Aijaz, A., Neogi, S., et al., Cryst. Growth Des., 2010, vol. 10, no. 8, p. 3410.

    Article  CAS  Google Scholar 

  16. He, H.Y., Yuan, D.Q., Ma, H.Q., et al., Inorg. Chem., 2010, vol. 49, no. 17, p. 7605.

    Article  CAS  Google Scholar 

  17. Jiang, H.L., Tsumori, N., and Xu, Q., Inorg. Chem., 2010, vol. 49, no. 21, p. 10001.

    Article  CAS  Google Scholar 

  18. Wang, C.G., Xing, Y.H., Li, Z.P., et al., Cryst. Growth Des., 2009, vol. 9, no. 3, p. 1525.

    Article  CAS  Google Scholar 

  19. Devic, T., Serre, C., Audebrand, N., et al., J. Am. Chem. Soc., 2005, vol. 127, no. 37, p. 12788.

    Article  CAS  Google Scholar 

  20. Han, Z.B., Cheng, X.N., and Chen, X.M., Cryst. Growth Des., 2005, vol. 5, no. 2, p. 695.

    Article  CAS  Google Scholar 

  21. Kondo, M., Irie, Y., and Shimizu, Y., Inorg. Chem., 2004, vol. 43, no. 20, p. 6139.

    Article  CAS  Google Scholar 

  22. Sun, C.Y., Gao, S., and Jin, L.P., Eur. J. Inorg. Chem., 2006, p. 2411.

  23. Sheldrick, G.M., Acta Crystallogr., A, 1990, vol. 46, no. 6, p. 467.

    Article  Google Scholar 

  24. Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  25. Sheldrick, G.M., SHELXTL-97, Program for Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    S. Sun, M. Y. Zhang, G. X. Zhang & Z. B. Han

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  1. S. Sun
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  2. M. Y. Zhang
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  3. G. X. Zhang
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  4. Z. B. Han
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Correspondence to Z. B. Han.

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Sun, S., Zhang, M.Y., Zhang, G.X. et al. Hydrothermal synthesis and crystal structure of a new 2D metal-organic framework: [Gd(Oba)(Ox)0.5(H2O)2] n (H2Oba = 4,4′-oxybis(benzoic acid); H2Ox = oxalic acid). Russ J Coord Chem 38, 305–308 (2012). https://doi.org/10.1134/S107032841202008X

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  • DOI: https://doi.org/10.1134/S107032841202008X

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