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63Cu and 115In NMR study of CuInS2 semiconductor

  • Atomic Structure and Nonelectronic Properties of Semiconductors
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Abstract

Two CuInS2 semiconductor samples synthesized from chemical elements with the equiatomic cation ratio (N Cu/N In = 1) and either an excess or stoichiometric sulfur content have been investigated by 63Cu and 115In nuclear magnetic resonance. The spectra were recorded on a Bruker Avance-400 spectrometer at a temperature of 290 K and frequencies of 106.14 MHz (63Cu) and 87.67 MHz (115In). Numerical simulation made it possible to determine the quadrupole coupling constants: 0.34 MHz (63Cu) and 1.1 MHz (115In). For the samples synthesized with excess sulfur (above stoichiometry), distortions are revealed in both the 63Cu and 115In spectra.

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Authors and Affiliations

  1. Kazan State Power University, Kazan, 420066, Russia

    I. Kh. Khabibullin, V. L. Matukhin, V. L. Ermakov & E. V. Schmidt

  2. Kazan Physical-Technical Institute, Kazan Research Center, Russian Academy of Sciences, Kazan, 420066, Russia

    O. I. Gnezdilov

  3. Institute of Solid-State and Semiconductor Physics, National Academy of Sciences of Belarus, Minsk, 220072, Belarus

    B. V. Korzun

Authors
  1. I. Kh. Khabibullin
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  2. V. L. Matukhin
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  3. V. L. Ermakov
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  4. O. I. Gnezdilov
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  5. B. V. Korzun
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  6. E. V. Schmidt
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Correspondence to I. Kh. Khabibullin.

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Original Russian Text © I.Kh. Khabibullin, V.L. Matukhin, V.L. Ermakov, O.I. Gnezdilov, B.V. Korzun, E.V. Schmidt, 2009, published in Fizika i Tekhnika Poluprovodnikov, 2009, Vol. 43, No. 1, pp. 3–6.

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Khabibullin, I.K., Matukhin, V.L., Ermakov, V.L. et al. 63Cu and 115In NMR study of CuInS2 semiconductor. Semiconductors 43, 1–3 (2009). https://doi.org/10.1134/S1063782609010011

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  • DOI: https://doi.org/10.1134/S1063782609010011

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