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Synthesis, Crystal Structure, and Luminescence of Three-dimensional Cd(II) Coordination Polymer Generated from Benzopenone-2,4′-dicarboxylate and 1,4-Bis(1H-imidazol-1-yl)butane Mixed Ligands

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Abstract

A new coordination polymer, namely, [Cd(L)(BIB)0.5]n (H2L = benzophenone-2,4′-dicarboxylic acid, BIB = 1,4-bis(1H-imidazol-1-yl)butane), was synthesized under hydrothermal condition. Single-crystal X-ray analysis reveals that two adjacent Cd(II) ions are bridged by four L2− ligands to form a two-dimensional layers, which are further connected by BIB to build a beautiful three-dimensional (3D) network. The luminescent and thermal properties of the compound are investigated.

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Authors and Affiliations

  1. Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass, Zhejiang A and F University, Lin’an, Zhejiang, 311300, People’s Republic of China

    J. N. Xing, J. Z. Guo & B. Li

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  1. J. N. Xing
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  2. J. Z. Guo
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  3. B. Li
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Correspondence to B. Li.

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Xing, J.N., Guo, J.Z. & Li, B. Synthesis, Crystal Structure, and Luminescence of Three-dimensional Cd(II) Coordination Polymer Generated from Benzopenone-2,4′-dicarboxylate and 1,4-Bis(1H-imidazol-1-yl)butane Mixed Ligands. Crystallogr. Rep. 63, 581–584 (2018). https://doi.org/10.1134/S1063774518040296

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  • DOI: https://doi.org/10.1134/S1063774518040296

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