Study of the Effect of Inhibitor on the Corrosion Behavior of Steel Using Chebyshev Noise Spectroscopy and Electrochemical Impedance Spectroscopy

Abstract

The electrochemical noise of a system of two identical steel electrodes in the NaCl solution without and with an addition of benzotriazole (BTA) corrosion inhibitor is measured and analyzed. It is shown that this method is a convenient tool for testing the protective properties of inhibitor. The method of impedance spectroscopy applied to this electrochemical system gives the information on the mechanism of inhibitor action.

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REFERENCES

  1. 1

    Mansfeld, F., The electrochemical noise technique—application in corrosion research, Proc. 18th International Conference on Noise and Fluctuations—ICNF 2005, Gonzalez, T, Mateos, J., and Pardo, D., Eds., American Institute of Physics, 2005, p. 625.

  2. 2

    Electrochemical Noise Measurement for Corrosion Applications, Kearns, R., Scully, J.R., Robege, P.R., Rei-chert, D.L., and Dawson, J.L., Eds., West Conshohocken, PA: ASTM, 1994.

    Google Scholar 

  3. 3

    Huet, F., Electrochemical noise technique, in Analytical Methods in Corrosion Science and Engineering, Marcus, P. and Mansfeld, F., Eds., Boca Raton: CRC Press, 2006, p. 508.

    Google Scholar 

  4. 4

    Cottis, R.A., Interpretation of EN data, Corrosion, 2001, vol. 57, p. 265.

    CAS  Article  Google Scholar 

  5. 5

    Cottis, R. and Turgoose, S., Electrochemical Impedance and Noise. Corrosion Testing Made Easy, Syrett, B.C., Series Ed., Houston, TX: NACE International, 1999.

  6. 6

    Tan, Y.J., Baile, S., and Kinsella, B., The monitoring of the formation and destruction of corrosion inhibitor films using ENA, Corros. Sci., 1996, vol. 38, p. 1681.

    CAS  Article  Google Scholar 

  7. 7

    Tan, Y.J., Kinsella, B., and Bailey, S., Monitoring batch treatment inhibitor performance using ENA, Br. Corros. J., 1997, vol. 32, p. 212.

    CAS  Article  Google Scholar 

  8. 8

    Nagiub, A.M., Electrochemical noise analysis for different green corrosion inhibitors for copper exposed to chloride media, Port. Electrochim. Acta, 2017, vol. 35, p. 201.

    Article  Google Scholar 

  9. 9

    Tan, Y., Heterogeneous Electrode Processes and Localized Corrosion, Hoboken, NJ: Wiley, 2013.

    Google Scholar 

  10. 10

    Hermoso-Diaz, I.A., Gonzalez-Rodrigues, J.G., and Uruchuru-Chavarin, J., Use of EIS and electrochemical noise fractal analysis to study Salvia hispanica as green corrosion inhibitor for carbon steel, Int. J. Electrochem. Sci., 2016, vol. 11, p. 4253.

    CAS  Article  Google Scholar 

  11. 11

    Slavcheva, E. and Schmitt, G., Screening of new corrosion inhibitors via electrochemical noise analysis, Mater. Corros., 2002, vol. 53, p. 647.

    CAS  Article  Google Scholar 

  12. 12

    Ehsani, A., Mahjani, M.G., Hosseini, M., Safari, R., Moshrefi, R., and Shiri, H.M., Evaluation of Thymus vulgaris plant extract an eco-friendly corrosion inhibitor for stainless steel 304 in acidic solution by mean of electrochemical impedance spectroscopy, electrochemical noise analysis and density functional theory, J. Colloid Interface Sci., 2017, vol. 490, p. 444.

    CAS  Article  Google Scholar 

  13. 13

    Mehdipour, M., Ramezanzadeh, B., and Arman, S., Electrochemical noise investigation of Aloe plant extract as green inhibitor on the corrosion of stainless steel in 1 M H2SO4, J. Ind. Eng. Chem., 2015, vol. 21, p. 318.

    CAS  Article  Google Scholar 

  14. 14

    Lucio-Garcia, M.A., Gonzalez-Rodrigues, J.G., Martinez-Villafane, A., Dominguez-Patino, G., Neri-Flores, M.A., and Chacon-Nava, J.G., A study of hydroxyethyl imidazoline as H2S corrosion inhibitor using electrochemical noise and electrochemical impedance spectroscopy, J. Appl. Electrochem., 2010, vol. 40, p. 393.

    CAS  Article  Google Scholar 

  15. 15

    Aballe, A., Bethencourt, M., Botana, F.J., Marcos, M., and Osuna, R.M., Electrochemical noise applied to the study of the inhibition effect of CeCl3 on the corrosion behavior of Al–Mg alloy AA5083 in seawater, Electrochim. Acta, 2002, vol. 47, p. 1415.

    CAS  Article  Google Scholar 

  16. 16

    Garcia-Ochoa, E. and Genesca, J., Understanding the inhibiting properties of 3 amino-1,2,4-triazole from fractal analysis, Surf. Coat. Technol., 2004, vol. 184, p. 322.

    CAS  Article  Google Scholar 

  17. 17

    Grafov, B.M., Kluev, A.L., Kabanova, T.B., and Davydov, A.D., Chebyshev spectra resistance to trend of random noise, Fluctuation Noise Lett., 2018, vol. 17, 1850028.

    Article  Google Scholar 

  18. 18

    Grafov, B.M., Dobrovolskii, Yu.A., Klyuev, A.L., Ukshe, A.E., Davydov, A.D., and Astaf’ev, E.A., Median Chebyshev spectroscopy of electrochemical noise, J. Solid State Electrochem., 2017, vol. 21, p. 915.

    CAS  Article  Google Scholar 

  19. 19

    https://www.analog.com/en/design-center/evaluation-hardware-and-software/evaluation-boards-kits/eval-ad7176-2.html (29.11.2019).

  20. 20

    Orazem, M.E. and Tribollet, B., Electrochemical Impedance Spectroscopy,Wiley, 2008, p. 159.

    Google Scholar 

  21. 21

    Kim, Y.S. and Kim, J.G., Electrochemical and quantum chemical studies of 1, 2, 3-benzotriazole as inhibitor for copper and steel in simulated tap water, Mater. Trans., 2017, vol. 58, p. 76.

    CAS  Article  Google Scholar 

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Funding

The work was performed with support of Ministry of Science and Higher Education of Russian Federation.

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Correspondence to A. L. Klyuev or V. N. Andreev.

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The authors declare that they have no conflicts of interest.

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Translated by T. Kabanova

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Klyuev, A.L., Andreev, V.N., Davydov, A.D. et al. Study of the Effect of Inhibitor on the Corrosion Behavior of Steel Using Chebyshev Noise Spectroscopy and Electrochemical Impedance Spectroscopy. Russ J Electrochem 56, 1011–1017 (2020). https://doi.org/10.1134/S1023193520120095

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Keywords:

  • electrochemical noise
  • Chebyshev noise spectroscopy
  • electrochemical impedance
  • corrosion of steel
  • inhibitor of corrosion