Skip to main content
SpringerLink
Log in

Oxidative polymerization of aniline on the surface of silica in the presence of poly(sulfonic acids) as a method of preparing efficient biosorbents

  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

Polyaniline coatings on the surface of the macroporous silica have been prepared by oxidative polymerization via protonation of aniline by poly(sulfonic acids): poly(p,p′-(2,2′-disulfonic acid)diphenyle-neisophthalamide and poly(p,p′-(2,2′-disulfonic acid)diphenyleneterephthalamide. Two variants of modification have been studied: namely, the polymerization of aniline carried out in the presence of the preliminarily silaminated glass covered by poly(sulfonic acid) and the modification of silaminated glass by preformed complexes of poly(p,p′-(2,2′-disulfonic acid)diphenylenephthalamide-polyaniline. In both cases, the even polyaniline-containing polymer coating with a thickness of ∼3 nm is formed on the support surface. Sorbents containing the poly(p,p′-(2,2′-disulfonic acid)diphenylenephthalamide-polyaniline complex are efficient for isolation of DNA from mixtures of biopolymers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. A. Kabanov, K. V. Aliev, O. V. Kargina, et al., J. Polym. Sci., Part C 16, 1079 (1967).

    CAS  Google Scholar 

  2. V. A. Kabanov and I. M. Papisov, Vysokomol. Soedin., Ser. A 21, 243 (1979).

    CAS  Google Scholar 

  3. V. A. Kabanov, O. V. Kargina, and M. V. Ul’yanova, Vysokomol. Soedin., Ser. A 22, 1038 (1980).

    CAS  Google Scholar 

  4. O. A. Kharenko, A. V. Kharenko, V. A. Kasaikin, et al., Vysokomol. Soedin., Ser. A 21, 2726 (1979).

    CAS  Google Scholar 

  5. V. A. Kabanov and A. B. Zezin, Pure Appl. Chem. 56, 343 (1984).

    Article  CAS  Google Scholar 

  6. V. A. Kabanov, Macromol. Chem., Macromol. Symp. 48–49, 425 (1991).

    Google Scholar 

  7. I. M. Papisov, Polymer Science, Ser. B 39, 122 (1997) [Vysokomol. Soedin., Ser. B 39, 562 (1997)].

    Google Scholar 

  8. L. Sharma Amit, Vibha Saxena, S. Annapoorni, and B. D. Malhotra, J. Appl. Polym. Sci. 81, 1460 (2001).

    Article  Google Scholar 

  9. D. V. Kapustin, E. Yu. Yagudaeva, L. L. Zavada, et al., Bioorg. Khim. 29, 310 (2003).

    CAS  Google Scholar 

  10. E. Yu. Yagudaeva, M. R. Muidinov, D. V. Kapustin, and V. P. Zubov, Izv. Akad. Nauk, Ser. Khim. 56, 1166 (2007).

    CAS  Google Scholar 

  11. A. G. C. Márquez, I. M. T. Rodríguez, and A. M. Rojas, Electrochim. Acta 52, 5294 (2007).

    Article  Google Scholar 

  12. Z. Wey and M. Wan, J. Appl. Polym. Sci. 87, 1297 (2003).

    Article  Google Scholar 

  13. V. F. Ivanov, O. L. Gribkova, K. V. Cheberyako, et al., Elektrokhimiya, No. 3, 339 (2004).

  14. M. A. Guseva, A. A. Isakova, O. L. Gribkova, et al., Polymer Science, Ser. A 49, 4 (2007) [Vysokomol. Soedin., Ser. A 49, 9 (2007)].

    Article  Google Scholar 

  15. Yu. E. Kirsh, Yu. A. Fedotov, N. N. Iudina, and E. E. Katalevskii, Vysokomol. Soedin., Ser. B 32, 403 (1990).

    CAS  Google Scholar 

  16. G. V. Lisichkin, Modified Silicas in Sorption, Catalysis, and Chromatography (Khimiya, Moscow, 1986) [in Russian].

    Google Scholar 

  17. E. A. Ponzio, R. Echevarria, G. M. Morales, and S. Barbero, Polym. Int. 50, 1180 (2001).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, ul. Miklukho-Maklaya 16/10, Moscow, 117997, Russia

    E. Yu. Yagudaeva, Ya. A. Bukina, A. I. Prostyakova, V. P. Zubov & D. V. Kapustin

  2. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    V. A. Tverskoy

Authors
  1. E. Yu. Yagudaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ya. A. Bukina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Prostyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. P. Zubov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. A. Tverskoy
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. V. Kapustin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. P. Zubov.

Additional information

Original Russian Text © E.Yu. Yagudaeva, Ya.A. Bukina, A.I. Prostyakova, V.P. Zubov, V.A. Tverskoy, D.V. Kapustin, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2009, Vol. 51, No. 6, pp. 1000–1007

This work was supported by EU grant no. 037212 (LSHB-CT-2007-037212) DIAGNOSIS.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yagudaeva, E.Y., Bukina, Y.A., Prostyakova, A.I. et al. Oxidative polymerization of aniline on the surface of silica in the presence of poly(sulfonic acids) as a method of preparing efficient biosorbents. Polym. Sci. Ser. A 51, 675–682 (2009). https://doi.org/10.1134/S0965545X09060121

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X09060121

Keywords

Search

Navigation