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Analysis of Sour Oil Ozonation Products by Ultra-High Resolution Mass-Spectrometry

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Abstract

Ozonation products of sour crude oil have been determined at the molecular level by means of ion cyclotron resonance Fourier-transform mass spectrometry in soft ionization modes. It has been shown that a proper choice of ozonation conditions makes it possible to selectively ozonize heteroatomic nitrogen, sulfur, and oxygen compounds, such as pyrrole derivatives, sulfides, disulfides, thiophene derivatives, resins, and asphaltenes. It has been found that the hydrocarbon portion of the oil is not ozonized under the given conditions.

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References

  1. A. V. Stavitskaya, Candidate’s Dissertation in Engineering (Moscow, 2015) [in Russian].

    Google Scholar 

  2. J. Li, L. N. Yang, and J. Shen, Pet. Sci. Technol. 29, 247 (2011).

    Article  CAS  Google Scholar 

  3. J. L. Garcia-Gutierrez, G. A. Fuentes, M. E. Hernandez-Teran, et al., Appl. Catal., A 305, 15 (2006).

    Article  CAS  Google Scholar 

  4. J. L. Garcia-Gutierrez, G. A. Fuentes, M. E. Hernandez-Teran, et al., Appl. Catal., A 334, 366 (2008).

    Article  CAS  Google Scholar 

  5. X. Jiang, H. Li, W. Zhu, et al., Fuel 88, 431 (2008).

    Article  Google Scholar 

  6. C. Ma, B. Dai, P. Liu, et al., J. Ind. Eng. Chem. 20, 2769 (2014).

    Article  Google Scholar 

  7. B. Kasprzyk-Hordern and M. Ziolek, Appl. Catal., B 46, 639 (2003).

    Article  CAS  Google Scholar 

  8. N. M. Likhterova, V. V. Lunin, V. N. Torkhovskii, et al., Khim. Tekhnol. Topl. Masel, No. 4, 18 (2006).

    Google Scholar 

  9. Z. Cha, PhD Thesis (2009).

    Google Scholar 

  10. G. V. Tarakanov and A. A. Kazakov, Vestn. Astrakhansk. Gos. Tekh. Univ., No. 2, 65 (2011).

    Google Scholar 

  11. O. Turkay, H. Inan, and A. Dimoglo, Sep. Purif. Technol. 134, 110 (2014).

    Article  CAS  Google Scholar 

  12. A. V. Akopyan, Candidate’s Dissertation in Chemistry (Moscow, 2015) [in Russian].

    Google Scholar 

  13. V. D. Kam’yanov, A. K. Lebedev, and P. P. Sivirilov, Ozonolysis of Petroleum Feedstock (MGN “Rasko”, Tomsk, 1997) [in Russian].

    Google Scholar 

  14. A. V. Stavitskaya, M. L. Konstantinova, S. D. Razumovskii, et al., Vestn. Kazansk. Tekhnol. Univ. 16 (22) (2013).

    Google Scholar 

  15. S. D. Razumovskii and G. E. Zaikov, Ozone and Its Reactions with Organic Compounds (Nauka, Moscow, 1974) [in Russian].

    Google Scholar 

  16. P. S. Bailey, Chem. Rev. 58, 925 (1958).

    Article  CAS  Google Scholar 

  17. A. Gaspar, E. Zellermann, S. Lababidi, et al., Energy Fuels 26, 3481 (2012).

    Article  CAS  Google Scholar 

  18. M. M. M. Guilherme and P. Dalmaschio, Fuel 115, 190 (2014).

    Article  Google Scholar 

  19. A. G. Marshall, C. L. Hendrickson, and G. S. Jackson, Mass Spectrom. Rev. 17, 1 (1998).

    Article  CAS  Google Scholar 

  20. C. A. Hughey, C. L. Hendrickson, R. P. Rodgers, et al., Anal. Chem. 73, 4676 (2001).

    Article  CAS  Google Scholar 

  21. A. V. Stavitskaya, M. L. Konstantinova, and R. Z. Safieva, Pet. Chem. 56, 623 (2016).

    Article  CAS  Google Scholar 

  22. A. V. Stavitskaya and R. Z. Safieva, Tr. RGU 279, 117 (2015).

    Google Scholar 

  23. S. Otsuki, T. Nonaka, N. Takashima, et al., Energy Fuels 14, 1232 (2000).

    Article  CAS  Google Scholar 

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Correspondence to A. V. Stavitskaya.

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Original Russian Text © A.V. Stavitskaya, M.L. Konstantinova, S.D. Razumovskii, R.Z. Safieva, V.A. Vinokurov, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 6, pp. 633–638.

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Stavitskaya, A.V., Konstantinova, M.L., Razumovskii, S.D. et al. Analysis of Sour Oil Ozonation Products by Ultra-High Resolution Mass-Spectrometry. Pet. Chem. 57, 1012–1017 (2017). https://doi.org/10.1134/S0965544117120131

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  • DOI: https://doi.org/10.1134/S0965544117120131

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