Abstract
Ozonation products of sour crude oil have been determined at the molecular level by means of ion cyclotron resonance Fourier-transform mass spectrometry in soft ionization modes. It has been shown that a proper choice of ozonation conditions makes it possible to selectively ozonize heteroatomic nitrogen, sulfur, and oxygen compounds, such as pyrrole derivatives, sulfides, disulfides, thiophene derivatives, resins, and asphaltenes. It has been found that the hydrocarbon portion of the oil is not ozonized under the given conditions.
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References
A. V. Stavitskaya, Candidate’s Dissertation in Engineering (Moscow, 2015) [in Russian].
J. Li, L. N. Yang, and J. Shen, Pet. Sci. Technol. 29, 247 (2011).
J. L. Garcia-Gutierrez, G. A. Fuentes, M. E. Hernandez-Teran, et al., Appl. Catal., A 305, 15 (2006).
J. L. Garcia-Gutierrez, G. A. Fuentes, M. E. Hernandez-Teran, et al., Appl. Catal., A 334, 366 (2008).
X. Jiang, H. Li, W. Zhu, et al., Fuel 88, 431 (2008).
C. Ma, B. Dai, P. Liu, et al., J. Ind. Eng. Chem. 20, 2769 (2014).
B. Kasprzyk-Hordern and M. Ziolek, Appl. Catal., B 46, 639 (2003).
N. M. Likhterova, V. V. Lunin, V. N. Torkhovskii, et al., Khim. Tekhnol. Topl. Masel, No. 4, 18 (2006).
Z. Cha, PhD Thesis (2009).
G. V. Tarakanov and A. A. Kazakov, Vestn. Astrakhansk. Gos. Tekh. Univ., No. 2, 65 (2011).
O. Turkay, H. Inan, and A. Dimoglo, Sep. Purif. Technol. 134, 110 (2014).
A. V. Akopyan, Candidate’s Dissertation in Chemistry (Moscow, 2015) [in Russian].
V. D. Kam’yanov, A. K. Lebedev, and P. P. Sivirilov, Ozonolysis of Petroleum Feedstock (MGN “Rasko”, Tomsk, 1997) [in Russian].
A. V. Stavitskaya, M. L. Konstantinova, S. D. Razumovskii, et al., Vestn. Kazansk. Tekhnol. Univ. 16 (22) (2013).
S. D. Razumovskii and G. E. Zaikov, Ozone and Its Reactions with Organic Compounds (Nauka, Moscow, 1974) [in Russian].
P. S. Bailey, Chem. Rev. 58, 925 (1958).
A. Gaspar, E. Zellermann, S. Lababidi, et al., Energy Fuels 26, 3481 (2012).
M. M. M. Guilherme and P. Dalmaschio, Fuel 115, 190 (2014).
A. G. Marshall, C. L. Hendrickson, and G. S. Jackson, Mass Spectrom. Rev. 17, 1 (1998).
C. A. Hughey, C. L. Hendrickson, R. P. Rodgers, et al., Anal. Chem. 73, 4676 (2001).
A. V. Stavitskaya, M. L. Konstantinova, and R. Z. Safieva, Pet. Chem. 56, 623 (2016).
A. V. Stavitskaya and R. Z. Safieva, Tr. RGU 279, 117 (2015).
S. Otsuki, T. Nonaka, N. Takashima, et al., Energy Fuels 14, 1232 (2000).
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Original Russian Text © A.V. Stavitskaya, M.L. Konstantinova, S.D. Razumovskii, R.Z. Safieva, V.A. Vinokurov, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 6, pp. 633–638.
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Stavitskaya, A.V., Konstantinova, M.L., Razumovskii, S.D. et al. Analysis of Sour Oil Ozonation Products by Ultra-High Resolution Mass-Spectrometry. Pet. Chem. 57, 1012–1017 (2017). https://doi.org/10.1134/S0965544117120131
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DOI: https://doi.org/10.1134/S0965544117120131