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Petroleum Chemistry

, Volume 57, Issue 12, pp 1043–1051 | Cite as

Olefin Synthesis from Dimethyl Ether in the Presence of a Hydrothermally Treated Mg–HZSM-5/Al2O3 Catalyst: Effect of Reaction Conditions on the Product Composition and Ratio

  • M. V. Magomedova
  • E. G. Peresypkina
  • I. A. Davydov
  • S. N. Khadzhiev
Article

Abstract

Systematic studies of olefin synthesis from dimethyl ether (DME) in the presence of a hydrothermally treated HZSM-5 zeolite catalyst modified with magnesium have been conducted. Dependences of DME conversion, product yield and selectivity, and lower olefin ratio on space time in the temperature range of 320–360°C have been analyzed. The type of the resulting products has been determined, and assumptions about the reaction chemistry have been made to reveal the role of methylation and hydrogen-transfer reactions in the products formation.

Keywords

olefin synthesis dimethyl ether HZSM-5 zeolite chemistry kinetics 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • M. V. Magomedova
    • 1
  • E. G. Peresypkina
    • 1
  • I. A. Davydov
    • 1
  • S. N. Khadzhiev
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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