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Olefin Synthesis from Dimethyl Ether in the Presence of a Hydrothermally Treated Mg–HZSM-5/Al2O3 Catalyst: Effect of Reaction Conditions on the Product Composition and Ratio

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Abstract

Systematic studies of olefin synthesis from dimethyl ether (DME) in the presence of a hydrothermally treated HZSM-5 zeolite catalyst modified with magnesium have been conducted. Dependences of DME conversion, product yield and selectivity, and lower olefin ratio on space time in the temperature range of 320–360°C have been analyzed. The type of the resulting products has been determined, and assumptions about the reaction chemistry have been made to reveal the role of methylation and hydrogen-transfer reactions in the products formation.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    M. V. Magomedova, E. G. Peresypkina, I. A. Davydov & S. N. Khadzhiev

Authors
  1. M. V. Magomedova
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  2. E. G. Peresypkina
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  3. I. A. Davydov
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  4. S. N. Khadzhiev
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Corresponding author

Correspondence to E. G. Peresypkina.

Additional information

Original Russian Text © M.V. Magomedova, E.G. Peresypkina, I.A. Davydov, S.N. Khadzhiev, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 6, pp. 663–671.

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Magomedova, M.V., Peresypkina, E.G., Davydov, I.A. et al. Olefin Synthesis from Dimethyl Ether in the Presence of a Hydrothermally Treated Mg–HZSM-5/Al2O3 Catalyst: Effect of Reaction Conditions on the Product Composition and Ratio. Pet. Chem. 57, 1043–1051 (2017). https://doi.org/10.1134/S0965544117100115

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  • DOI: https://doi.org/10.1134/S0965544117100115

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