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Rate Constant of the Reaction between Ozone and Chloride Ion in an Aqueous Solution According to a Mechanism of Oxygen Atom Transfer

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

The effect of concentrations of Cl– and H+ ions, temperature, and ionic strength on the rate constant of the reaction between O3 and Cl–(aq) is studied experimentally. The reaction proceeds according to a mechanism of oxygen transfer and results in the formation of molecular chlorine in acidic medium. A formula is proposed for calculating the dependence of the rate constant on these factors.

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REFERENCES

  1. A. V. Levanov, I. V. Kuskov, A. V. Zosimov, E. E. Antipenko, and V. V. Lunin, Kinet. Catal. 44, 740 (2003).

    Article  CAS  Google Scholar 

  2. A. V. Levanov, E. E. Antipenko, and V. V. Lunin, Russ. J. Phys. Chem. A 86, 519 (2012).

    Article  CAS  Google Scholar 

  3. A. V. Levanov, E. E. Antipenko, and V. V. Lunin, Russ. J. Phys. Chem. A 86, 2086 (2012).

    Article  CAS  Google Scholar 

  4. A. V. Levanov, I. V. Kuskov, E. E. Antipenko, and V. V. Lunin, Russ. J. Phys. Chem. A 86, 757 (2012).

    Article  CAS  Google Scholar 

  5. A. V. Levanov, I. V. Kuskov, E. E. Antipenko, and V. V. Lunin, Russ. J. Phys. Chem. A 82, 2045 (2008).

    Article  CAS  Google Scholar 

  6. N. Kang, W. A. Jackson, P. K. Dasgupta, and T. A. Anderson, Sci. Total Environ. 405, 301 (2008).

    Article  CAS  PubMed  Google Scholar 

  7. K. J. Laidler, Pure Appl. Chem. 68, 149 (1996).

    Article  CAS  Google Scholar 

  8. A. V. Levanov, O. Ya. Isaikina, R. V. Gasanova, and V. V. Lunin, Ind. Eng. Chem. Res. 57, 14355 (2018).

  9. D. Maric, J. P. Burrows, R. Meller, and G. K. Moortgat, Photochem. Photobiol., A 70, 205 (1993).

  10. S. P. Sander, J. Abbatt, J. R. Barker, et al., JPL Publ. No. 10-6 (Jet Propuls. Labor., Pasadena, 2011).

    Google Scholar 

  11. A. V. Levanov, I. V. Kuskov, A. V. Zosimov, E. E. Antipenko, and V. V. Lunin, J. Anal. Chem. 58, 439 (2003).

    Article  CAS  Google Scholar 

  12. R. P. Bell, in Katalyse in Lösungen, Vol. 2 of Handbuch der Katalyse, Ed. by G.-M. Schwab (Springer, Wien, 1940), p. 191

  13. G. M. Panchenkov and V. P. Lebedev, Chemical Kinetics and Catalysis, 3rd ed. (Khimiya, Moscow, 1985) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. V. Levanov, O. Ya. Isaikina & V. V. Lunin

Authors
  1. A. V. Levanov
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  2. O. Ya. Isaikina
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  3. V. V. Lunin
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Correspondence to A. V. Levanov.

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Translated by V. Avdeeva

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Levanov, A.V., Isaikina, O.Y. & Lunin, V.V. Rate Constant of the Reaction between Ozone and Chloride Ion in an Aqueous Solution According to a Mechanism of Oxygen Atom Transfer. Russ. J. Phys. Chem. 93, 1045–1048 (2019). https://doi.org/10.1134/S0036024419060189

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  • DOI: https://doi.org/10.1134/S0036024419060189

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