Skip to main content
SpringerLink
Log in

Thermodynamic Description of the Nonexchange Sorption of Substances by Ion Exchangers

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Based on the stoichiometry of absorption, a thermodynamic approach is proposed for describing the nonexchange sorption of substances with ion exchangers from individual solutions and mixtures. This approach is applied to describe the absorption of amino acids using the sorption of tryptophan and hystidine with anion exchangers AV-17-2P in Cl form as an example. Integral and differential characteristics of nonexchange sorption in these systems are described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. F. Helfferich, Ionenaustauscher. Band 1: Grundlagen, Struktur–Herstellung, Theorie (Chemie, Weinheim, 1959).

    Google Scholar 

  2. E. S. Trunaeva, O. N. Khokhlova, and V. Yu. Khokhlov, J. Struct. Chem. 58, 17 (2017).

    Article  CAS  Google Scholar 

  3. O. N. Khokhlova, V. Yu. Khokhlov, E. S. Trunaeva, and L. S. Nechaeva, Russ. J. Phys. Chem. A 90, 1434 (2016).

    Article  CAS  Google Scholar 

  4. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Rob, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vteven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, et al., Gaussian 03, Revision C.02 (Gaussian Inc., Pittsburgh PA, Wallingford, CT, 2003).

  5. V. F. Selemenev, V. N. Chikanov, and P. Frelikh, Zh. Fiz. Khim. 64, 3330 (1990).

    CAS  Google Scholar 

  6. Yu. A. Kokotov and V. A. Pasechnik, Equilibrium and Kinetics of Ion Exchange (Nauka, Leningrad, 1977) [in Russian].

    Google Scholar 

  7. V. A. Ivanov and E. A. Karpyuk, Sorbtsion. Khromatogr. Protsessy 15, 19 (2015).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Voronezh State University, 394036, Voronezh, Russia

    E. S. Trunaeva, O. N. Khokhlova & V. Yu. Khokhlov

Authors
  1. E. S. Trunaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. N. Khokhlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. Yu. Khokhlov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. N. Khokhlova.

Additional information

Translated by S. Lebedev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Trunaeva, E.S., Khokhlova, O.N. & Khokhlov, V.Y. Thermodynamic Description of the Nonexchange Sorption of Substances by Ion Exchangers. Russ. J. Phys. Chem. 92, 2440–2444 (2018). https://doi.org/10.1134/S0036024418120440

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024418120440

Keywords:

Search

Navigation