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Effect of Hydroxyl Groups in a Cation Structure on the Properties of Ionic Liquids

  • PHYSICAL CHEMISTRY OF HYBRID NANOMATERIALS AND MULTICOMPONENT SYSTEMS
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Abstract

Two series of imidazolium ionic liquids with the bis(trifluoromethylsulfonyl)imide anion were synthesized, which differ by the presence of a hydroxyl group at the ω-position of the alkyl substituent in the cation structure (nC = 2–8). The properties of the liquids were studied by DSC, TGA, and IR and NMR spectroscopy. Their thermal stability was studied, and the melting points, viscosity, and volatility in vacuum were measured. The effect of OH groups in the structure of the ionic liquid on its properties was evaluated.

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ACKNOWLEDGMENTS

This study was supported by the Russian Science Foundation (grant no. 14-19-00503).

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. G. Krasovskiy, E. A. Chernikova, L. M. Glukhov & G. I. Kapustin

  2. Moscow Aviation Institute (National Research University), 125993, Moscow, Russia

    A. A. Koroteev

Authors
  1. V. G. Krasovskiy
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  2. E. A. Chernikova
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  3. L. M. Glukhov
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  4. G. I. Kapustin
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  5. A. A. Koroteev
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Corresponding author

Correspondence to V. G. Krasovskiy.

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Translated by L. Smolina

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Krasovskiy, V.G., Chernikova, E.A., Glukhov, L.M. et al. Effect of Hydroxyl Groups in a Cation Structure on the Properties of Ionic Liquids. Russ. J. Phys. Chem. 92, 2379–2385 (2018). https://doi.org/10.1134/S0036024418120245

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  • DOI: https://doi.org/10.1134/S0036024418120245

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