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Modifying the Hydrophobic Properties of Metal–Organic Framework HKUST-1

  • PHYSICAL CHEMISTRY OF HYBRID NANOMATERIALS AND MULTICOMPONENT SYSTEMS
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Abstract

The possibility is considered of optimizing the hydrophobic properties of metal–organic framework HKUST-1 (Сu2(btc)3, btc = benzene-1,3,5-tricarboxylate) using chloroform as a component of the reaction medium during synthesis. Using this modified technique to prepare the material helps to enhance its textural and structural characteristics.

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REFERENCES

  1. H. Furukawa, K. E. Cordova, M. O’Keeffe, and O. M. Yaghi, Science (Washington, DC, U. S.) 341, 1230444 (2013).

    Article  CAS  Google Scholar 

  2. G. Férey, Chem. Soc. Rev. 37, 191 (2008).

    Article  PubMed  Google Scholar 

  3. S. Kitagawa, R. Kitaura, and S.-I. Noro, Angew. Chem., Int. Ed. Engl. 43, 2334 (2004).

    Article  CAS  Google Scholar 

  4. I. Ahmed and S. H. Jhung, Mater. Today 17, 136 (2014).

    Article  CAS  Google Scholar 

  5. J. L. C. Rowsell and O. M. Yaghi, Microporous Mesoporous Mater. 73, 3 (2004).

    Article  CAS  Google Scholar 

  6. J. Gascon, S. Aguado, and F. Kapteijn, Microporous Mesoporous Mater. 113, 132 (2008).

  7. K. Schlichte, T. Kratzke, and S. Kaskel, Microporous Mesoporous Mater. 73, 81 (2004).

    Article  CAS  Google Scholar 

  8. J.-R. Li, R. J. Kuppler, and H.-C. Zhou, Chem. Soc. Rev. 8, 1477 (2009).

    Article  CAS  Google Scholar 

  9. J. Lei, R. Qian, P. Ling, L. Cui, and H. Ju, Trends Anal. Chem. 58, 71 (2014).

    Article  CAS  Google Scholar 

  10. J. P. Garcia-Garcia, M. Müller, and A. Corma, Chem. Sci. 5, 2979 (2014).

    Article  CAS  Google Scholar 

  11. M.-X. Wu and Y.-W. Yang, Adv. Mater. 29, 1606134 (2017).

    Article  CAS  Google Scholar 

  12. Z. Hu, B. J. Deibert, and J. Li, Chem. Soc. Rev. 43, 5815 (2014).

    Article  CAS  PubMed  Google Scholar 

  13. C. A. Fernandez, S. K. Nune, H. V. Annapureddy, et al., Dalton Trans. 44, 13490 (2015).

    Article  CAS  PubMed  Google Scholar 

  14. S. Rodriguez-Hermida, M. Y. Tsang, C. Vignatti, et al., Angew. Chem., Int. Ed. Engl. 55, 16049 (2016).

    Article  CAS  Google Scholar 

  15. Y. Peng, V. Krungleviciute, I. Eryazici, et al., J. Am. Chem. Soc. 135, 11887 (2013).

    Article  CAS  PubMed  Google Scholar 

  16. P. Chowdhury, C. Bikkina, D. Meister, et al., Microporous Mesoporous Mater. 117, 406 (2009).

    Article  CAS  Google Scholar 

  17. L. M. Kustov, Russ. J. Phys. Chem. A 89, 2006 (2015).

    Article  CAS  Google Scholar 

  18. V. P. Ananikov, K. I. Galkin, M. P. Egorov, et al., Mendeleev Commun. 26, 365 (2016).

    Article  CAS  Google Scholar 

  19. V. I. Isaeva, M. I. Barkova, A. V. Kucherov, et al., Ross. Nanotekhnol. 9 (5–6), 52 (2014).

    Google Scholar 

  20. R. Yepez, S. García, P. Schachat, et al., New J. Chem. 5112 (2015).

  21. J. L. C. Rowsell and O. M. Yaghi, J. Am. Chem. Soc. 128, 1304 (2006).

    Article  CAS  PubMed  Google Scholar 

  22. A. L. Klyachko-Gurvich, Russ. Chem. Bull. 10, 1756 (1961).

    Article  Google Scholar 

  23. V. P. Ananikov, Russ. Chem. Bull., 2551 (2011).

  24. R. Silverstein, F. X. Webster, and D. J. Kiemle, Spectrometric Identification of Organic Compounds, 8th ed. (Wiley, Chichester, 2014)

    Google Scholar 

  25. Y. Li and R. T. Yang, AIChE J. 54, 269 (2008).

    Article  CAS  Google Scholar 

  26. C. Petit, J. Burress, and T. J. Bandosz, Carbon 49, 563 (2011).

    Article  CAS  Google Scholar 

  27. C. Carbonell, I. Imaz, and D. Maspoch, Chem. Soc. Rev. 40, 291 (2011).

    Article  PubMed  Google Scholar 

  28. G. S. Pawley, J. Appl. Crystallogr. 14, 357 (1981).

    Article  CAS  Google Scholar 

  29. V. B. Zlokazov and V. V. Chernyshev, J. Appl. Crystallogr. 25, 447 (1992).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to Dr. A. Kashin (Department of Structural Investigations, Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences) for performing the electron microscope investigations of our samples.

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Correspondence to V. I. Isaeva or V. V. Chernyshev.

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Translated by E. Khozina

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Isaeva, V.I., Chernyshev, V.V., Sokolova, N.A. et al. Modifying the Hydrophobic Properties of Metal–Organic Framework HKUST-1. Russ. J. Phys. Chem. 92, 2391–2395 (2018). https://doi.org/10.1134/S0036024418120178

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  • DOI: https://doi.org/10.1134/S0036024418120178

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