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Mechanism of the Reaction between Cobalamin(II) and Periodate

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Abstract

The reaction between a reduced form of cobalamin (cobalamin(II), Cbl(II)) and periodate in alkaline medium is studied. It is shown that there is no destruction of cobalamin at the ratio of [Cbl(II)] : [IO\(_{4}^{ - }\)] = 2 : 1. The reaction mechanism includes interactions between Cbl(II) and H4IO\(_{6}^{ - }\) and H3IO\(_{6}^{{2 - }}\) leading to the formation of aquacobalamin and radicals I(VI), which rapidly oxidize the second molecule of Cbl(II) to aquacobalamin.

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Authors and Affiliations

  1. Ivanovo State Academy of Chemical Technology, 153460, Ivanovo, Russia

    I. A. Dereven’kov, N. I. Shpagilev & S. V. Makarov

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  1. I. A. Dereven’kov
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  2. N. I. Shpagilev
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  3. S. V. Makarov
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Correspondence to I. A. Dereven’kov.

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Translated by L. Mosina

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Dereven’kov, I.A., Shpagilev, N.I. & Makarov, S.V. Mechanism of the Reaction between Cobalamin(II) and Periodate. Russ. J. Phys. Chem. 92, 2182–2186 (2018). https://doi.org/10.1134/S0036024418110080

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