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Calculating the Entropy of Solid and Liquid Metals, Based on Acoustic Data

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The entropies of iron, cobalt, rhodium, and platinum are studied for the first time, based on acoustic data and using the Debye theory and rigid-sphere model, from 298 K up to the boiling point. A formula for the melting entropy of metals is validated. Good agreement between the research results and the literature data is obtained.

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Correspondence to V. V. Tekuchev.

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Original Russian Text © V.V. Tekuchev, D.P. Kalinkin, I.V. Ivanova, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 5, pp. 679–683.

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Tekuchev, V.V., Kalinkin, D.P. & Ivanova, I.V. Calculating the Entropy of Solid and Liquid Metals, Based on Acoustic Data. Russ. J. Phys. Chem. 92, 819–822 (2018). https://doi.org/10.1134/S003602441805031X

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  • DOI: https://doi.org/10.1134/S003602441805031X

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