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Selective Hydrogenation of Acetylene and Physicochemical Properties of Pd–Fe/Al2O3 Bimetallic Catalysts

  • Chemical Kinetics and Catalysis
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Abstract

The selective hydrogenation of acetylene on Pd–Fe/Al2O3 catalysts prepared by decomposition of ferrocene on reduced Pd/Al2O3 was studied. The effect of the conditions of treatment of the Pd–ferrocene/ Al2O3 precursor on the catalyst activity and selectivity was investigated, and the optimum conditions were determined at which the Pd–Fe/Al2O3 catalyst has higher selectivity than Pd/Al2O3 without any loss of activity.

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References

  1. G. Ertl, H. Knozinger, F. Schuth, and J. Weitkamp, Handbook of Heterogeneous Catalysts (VCH, Weinheim, 1997), Vol.5.

  2. V. D. Stytsenko and D. P. Mel’nikov, Russ. J. Phys. Chem. A 90, 932 (2016).

    Article  CAS  Google Scholar 

  3. Q. Zhang, J. Li, X. Liu, and Q. Zhu, Appl. Catal., A 197, 221 (2000).

    Article  CAS  Google Scholar 

  4. D. C. Huang, K. H. Chang, W. F. Pong, et al., J. Catal. Lett. 53, 155 (1998).

    Article  CAS  Google Scholar 

  5. Yunya Zhang, Weijian Diao, C. T. Williams, and J. R. Monnier, Appl. Catal., A 469, 419 (2014).

    Article  CAS  Google Scholar 

  6. M. Kuhn, M. Lucas, and P. Claus, Ind. Eng. Chem. Res. 54, 1 (2016).

    Google Scholar 

  7. J. Osswald, R. Giedigkeit, R. E. Jentoft, et al., J. Catal. 258, 210 (2008).

    Article  CAS  Google Scholar 

  8. F. Studt, F. Abild-Pedersen, T. Bligaard, et al., Science 320 (5881), 1320 (2008).

    Article  CAS  Google Scholar 

  9. F. Studt, F. Abild-Pedersen, T. Bligaard, et al., Angew. Chem. Int. Ed. 47, 9299 (2008).

    Article  CAS  Google Scholar 

  10. J. H. Kang, E. W. Shin, W. J. Kim, J. D. Park, and S. H. Moon, J. Catal. 208, 310 (2002).

    Article  CAS  Google Scholar 

  11. I. S. Mashkovskii, O. P. Tkachenko, G. N. Baeva, and A. Yu. Stakheev, Kinet. Catal. 50, 768 (2009).

    Article  CAS  Google Scholar 

  12. Xian Pei Guang, Yan Liu Xiao, and Xiaofeng Yang, ACS Catal. 7, 1491 (2017).

    Article  Google Scholar 

  13. A. A. Solov’yanov, V. V. Kharatyan, and V. D. Stytsenko, Khim. Tekhnol., No. 6, 123 (2010).

    Google Scholar 

  14. E. W. Shin, C. H. Choi, K. S. Chang, Y. H. Na, and S. H. Moon, Catal.Today 44, 137 (1998).

    Article  CAS  Google Scholar 

  15. K. Lázár, M. Nimz, and G. Lietz, Hyperfine Interact. 41, 657 (1988).

    Article  Google Scholar 

  16. M. P. Felicissimo, O. N. Martyanov, T. Risse, and H.-J. Freund, Surf. Sci. 601, 2105 (2007).

    Article  CAS  Google Scholar 

  17. L. M. R. Gavidia, D. Sebastián, E. Pastor, A. S. Aricò, and V. Baglio, Materials 10, 580 (2017).

    Article  Google Scholar 

  18. B. Gumina, E. Paone, and F. Mauriello, Catalysts 7, 78 (2017).

    Article  Google Scholar 

  19. F. Boccuzzi, E. Guglielminotti, F. Pinna, and M. Signoretto, J. Chem. Soc., Faraday Trans. 91, 3237 (1995).

    Article  CAS  Google Scholar 

  20. Y. Hong, H. Zhang, J. Sun, et al., ACS Catal. 4, 3335 (2014).

    Article  CAS  Google Scholar 

  21. N. Lingaiah, P. S. Sai Prasad, P. P. Kanta Rao, et al., Appl. Catal., A 213, 189 (2001).

    Article  CAS  Google Scholar 

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Correspondence to V. D. Stytsenko.

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Original Russian Text © V.D. Stytsenko, D.P. Mel’nikov, O.P. Tkachenko, E.V. Savel’eva, A.P. Semenov, L.M. Kustov, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 5, pp. 716–722.

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Stytsenko, V.D., Mel’nikov, D.P., Tkachenko, O.P. et al. Selective Hydrogenation of Acetylene and Physicochemical Properties of Pd–Fe/Al2O3 Bimetallic Catalysts. Russ. J. Phys. Chem. 92, 862–869 (2018). https://doi.org/10.1134/S0036024418050308

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  • DOI: https://doi.org/10.1134/S0036024418050308

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