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Calculating Equilibrium Constants in the SnCl2–H2O–NaOH System According to Potentiometric Titration Data

  • Colloidal Chemistry and Electrochemistry
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Abstract

The potentiometric titration of tin chloride SnCl2 is performed in the concentration range of 0.00009–1.1 mol/L with a solution of sodium hydroxide NaOH. According to potentiometric titration data based on modeling equilibria in the SnCl2–H2O–NaOH system, basic equations are generated for the main processes, and instability constants are calculated for the resulting hydroxo complexes and equilibrium constants of low-soluble tin(II) compounds. The data will be of interest for specialists in the field of theory of solutions.

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Authors and Affiliations

  1. Ural Federal University, Yekaterinburg, 620075, Russia

    L. N. Maskaeva, E. A. Fedorova & V. F. Markov

  2. Ural Institute of State Fire Service of EMERCOM of Russia, Yekaterinburg, 620062, Russia

    L. N. Maskaeva & V. F. Markov

  3. Kazan National Research Technological University, Kazan, 420015, Russia

    R. A. Yusupov

Authors
  1. L. N. Maskaeva
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  2. E. A. Fedorova
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  3. R. A. Yusupov
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  4. V. F. Markov
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Corresponding author

Correspondence to E. A. Fedorova.

Additional information

Original Russian Text © L.N. Maskaeva, E.A. Fedorova, R.A. Yusupov, V.F. Markov, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 5, pp. 831–837.

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Maskaeva, L.N., Fedorova, E.A., Yusupov, R.A. et al. Calculating Equilibrium Constants in the SnCl2–H2O–NaOH System According to Potentiometric Titration Data. Russ. J. Phys. Chem. 92, 1025–1031 (2018). https://doi.org/10.1134/S0036024418050230

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  • DOI: https://doi.org/10.1134/S0036024418050230

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