Russian Journal of Physical Chemistry A

, Volume 92, Issue 5, pp 1025–1031 | Cite as

Calculating Equilibrium Constants in the SnCl2–H2O–NaOH System According to Potentiometric Titration Data

  • L. N. Maskaeva
  • E. A. Fedorova
  • R. A. Yusupov
  • V. F. Markov
Colloidal Chemistry and Electrochemistry


The potentiometric titration of tin chloride SnCl2 is performed in the concentration range of 0.00009–1.1 mol/L with a solution of sodium hydroxide NaOH. According to potentiometric titration data based on modeling equilibria in the SnCl2–H2O–NaOH system, basic equations are generated for the main processes, and instability constants are calculated for the resulting hydroxo complexes and equilibrium constants of low-soluble tin(II) compounds. The data will be of interest for specialists in the field of theory of solutions.


tin(II) chalcogenides complexation hydrolysis ionic equilibria boundary conditions of formation potentiometric titration thin films 


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • L. N. Maskaeva
    • 1
    • 2
  • E. A. Fedorova
    • 1
  • R. A. Yusupov
    • 3
  • V. F. Markov
    • 1
    • 2
  1. 1.Ural Federal UniversityYekaterinburgRussia
  2. 2.Ural Institute of State Fire Service of EMERCOM of RussiaYekaterinburgRussia
  3. 3.Kazan National Research Technological UniversityKazanRussia

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