Russian Journal of Physical Chemistry A

, Volume 92, Issue 5, pp 927–932 | Cite as

Thermodynamics of R-(+)-2-(4-Hydroxyphenoxy)propanoic Acid Dissolution in Methanol, Ethanol, and Methanol-Ethanol Mixture

  • Wei Liu
  • Jinju Ma
  • Xinding Yao
  • Ruina Fang
  • Liang Cheng
Physical Chemistry of Solutions

Abstract

The solubilities of R-(+)-2-(4-hydroxyphenoxy)propanoic acid (D-HPPA) in methanol, ethanol and various methanol-ethanol mixtures are determined in the temperature range from 273.15 to 323.15 K at atmospheric pressure using a laser detecting system. The solubilities of D-HPPA increase with increasing mole fraction of ethanol in the methanol–ethanol mixtures. Experimental data were correlated with Buchowski-Ksiazczak λh equation and modified Apelblat equation; the first one gives better approximation for the experimental results. The enthalpy, entropy and Gibbs free energy of D-HPPA dissolution in methanol, ethanol and methanol-ethanol mixtures were also calculated from the solubility data.

Keywords

R-(+)-2-(4-hydroxyphenoxy)propanoic acid solid-liquid equilibrium solubility dissolution enthalpy dissolution entropy dissolution Gibbs free energy 

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References

  1. 1.
    N. Sunsandee, M. Hronec, M. Štolcová, and N. Leepipatpiboon, J. Mol. Liq. 180, 252 (2013).CrossRefGoogle Scholar
  2. 2.
    N. Sunsandee, S. Suren, N. Leepipatpiboon, and M. Hronec, J. Mol. Liq. 338, 217 (2013).Google Scholar
  3. 3.
    Y. H. Hu, X. M. Jiang, W. G. Yang, and Z. G. Chen, J. Mol. Liq. 169, 74 (2012).CrossRefGoogle Scholar
  4. 4.
    H. S. M. Ali and P. York, J. Mol. Liq. 73, 62 (2012).CrossRefGoogle Scholar
  5. 5.
    F. Shakeel, N. Haq, and M. M. Salem-Bekhit, J. Mol. Liq. 207, 274 (2015).CrossRefGoogle Scholar
  6. 6.
    Kim Dae Whang, US Patent No. 6486098 (1998).Google Scholar
  7. 7.
    M. A. Khan, R. A. Afridi, S. Hashim, et al., Crop Protect. 90, 34 (2016).CrossRefGoogle Scholar
  8. 8.
    W. Dong, S. Jiang, K Shi, et al., Bioresourse Technol. 186, 114 (2015).CrossRefGoogle Scholar
  9. 9.
    P. Tehranchian, J. K. Norsworthy, N. E. Korres, et al., Pestic. Biochem. Physiol. 133, 79 (2016).CrossRefGoogle Scholar
  10. 10.
    C. L. Zhang, F. A. Wang, and Y. Wang, J. Chem. Eng. Data 52, 1563 (2007).CrossRefGoogle Scholar
  11. 11.
    W. Liu, L. Xu, et al., Fluid Phase Equilib. 322–323, 26 (2012).CrossRefGoogle Scholar
  12. 12.
    W. Liu, L. Xu, et al., Thermochim. Acta 544, 89 (2012).CrossRefGoogle Scholar
  13. 13.
    H. Sun, B. Liu, K. Ren, et al., Fluid Phase Equilib. 417, 62 (2016).CrossRefGoogle Scholar
  14. 14.
    J. M. Prausnitz, R. N. Lichtenthaler, and E. G. Azevedo, Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed. (Prentice Hall, Upper Saddle River, NJ, 1999).Google Scholar
  15. 15.
    A. F. M. Barton, CRC Handbook of Solubility Parameters and Other Cohesion Parameters, 2nd ed. (CRC, Boca Raton, FL, 1991).Google Scholar
  16. 16.
    A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 29, 1527 (1997).CrossRefGoogle Scholar
  17. 17.
    A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 3l, 85 (1999).CrossRefGoogle Scholar
  18. 18.
    E. Manzurola and A. Apelblat, J. Chem. Thermodyn. 34, l127 (2002).CrossRefGoogle Scholar
  19. 19.
    H. Buchowski, A. Ksiazczak, and K. Pietrzyk, J. Phys. Chem. 84, 975 (1980).CrossRefGoogle Scholar
  20. 20.
    A. Ksiazczak and J. Kosinski, Fluid Phase Equilib. 44, 211 (1988).CrossRefGoogle Scholar
  21. 21.
    A. Ksiazczak, K. Moorthi, and I. Nagata, Fluid Phase Equilib. 95, 15 (1994).CrossRefGoogle Scholar
  22. 22.
    Y. Bao, J. Wang, Y. Wang, et al., J. Chem. Eng. Chin. Univ. 17, 457 (2003).Google Scholar
  23. 23.
    Y. X. Mo, L. P. Dang, and H. Y. Wei, Fluid Phase Equilib. 300, 105 (2011).CrossRefGoogle Scholar
  24. 24.
    P. Wang, J. K. Wang, J. B. Gong, and M. J. Zhang, Fluid Phase Equilib. 306, 171 (2011).CrossRefGoogle Scholar
  25. 25.
    A. Apelblat and E. Manzurola, J. Chem, J. Chem. Thermodyn. 31, 85 (1999).CrossRefGoogle Scholar
  26. 26.
    E. Manzurola and A. Apelblat, J. Chem. Thermodyn. 34, l127 (2002).CrossRefGoogle Scholar
  27. 27.
    M. J. Liu, H. L. Fu, D. P. Yin, et al., J. Chem. Eng. Data 59, 2070 (2014).CrossRefGoogle Scholar
  28. 28.
    D. R. Delgado, A. R. Holguin, O. A. Almanza, F. Martinez, and Y. Marcus, Fluid Phase Equilib. 305, 80 (2011).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Wei Liu
    • 1
    • 3
  • Jinju Ma
    • 1
    • 3
  • Xinding Yao
    • 1
    • 3
  • Ruina Fang
    • 1
    • 3
  • Liang Cheng
    • 2
  1. 1.Environment and Chemistry Engineering DepartmentYellow River Conservancy Technical InstituteKaifengPR China
  2. 2.School of Chemical Engineering and EnergyZhengzhou UniversityZhengzhouPR China
  3. 3.Kaifeng Key Laboratory of Green Coating MaterialsKaifengPR China

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