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Russian Journal of Physical Chemistry A

, Volume 92, Issue 4, pp 630–639 | Cite as

Thermodynamic Properties of Alloys of the Sn–Yb System

  • V. S. Sudavtsova
  • M. A. Shevchenko
  • M. I. Ivanov
  • A. S. Kozorezov
  • V. G. Kudin
Chemical Thermodynamics and Thermochemistry
  • 16 Downloads

Abstract

Thermochemical properties of liquid alloys of the Sn–Yb system are studied via calorimetry at 1110–1310 K over the ranges of concentrations 0 < xYb < 0.47 and 0.82 < xYb < 1. Considerable negative heat effects of the mixing of these alloys are identified. Activities of the components, the Gibbs energies and entropies of mixing, and the liquidus curve of the phase diagram of this system are calculated using the ideal associated solution (IAS) model and agree with data from the literature.

Keywords

calorimetry liquid alloys thermochemical properties ideal associated solution model Sn–Yb system 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. S. Sudavtsova
    • 1
  • M. A. Shevchenko
    • 1
  • M. I. Ivanov
    • 1
  • A. S. Kozorezov
    • 1
  • V. G. Kudin
    • 1
  1. 1.Frantsevich Institute for Problems of Materials ScienceKyivUkraine

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