Skip to main content
SpringerLink
Log in

Solvation Thermodynamics of DL-Phenylalanine in Aqueous NaNO3 Solution at 298.15 K

  • Physical Chemistry of Solutions
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

By “formol titrimetry” method solubilities of DL-phenylalanine (PA) in aqueous NaNO3 solution were measured at 298.15 K. The standard Gibbs energy of PA in aqueous and aqueous NaNO3 solution and also transfer free energy of PA was evaluated. The thermodynamic parameters: molar volume, densities, dipole moment and solvent diameter of aqueous solution of NaNO3 have also been reported. Electrolyte effects on the solubility and relative stability of PA is guided by different types of interactions which are explained in this manuscript.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. P. Das, S. Chatterjee, and I. N. Basu Mallick, J. Chin. Chem. Soc. 51, 1 (2004).

    Article  CAS  Google Scholar 

  2. T. S. Banipal, G. Singh, and B. S. Lark, J. Solut. Chem. 30, 657 (2001).

    Article  CAS  Google Scholar 

  3. M. N. Islam and R. K. Wadi, Phys. Chem. Liq. 39, 77 (2001).

    Article  CAS  Google Scholar 

  4. K. Koseoglu, Esma, and H. C. Hang, Anal. Biochem. 277, 243 (2000).

    Article  CAS  Google Scholar 

  5. K. Mahali, S. Roy, and B. K. Dolui, J. Biophys. Chem. 2, 185 (2011).

    Article  CAS  Google Scholar 

  6. Y. Nozaki and C. Tanford, J. Boil. Chem. 238, 4074 (1963).

    CAS  Google Scholar 

  7. M. Abu-Hamdlyyah and A. Shehabuddin, J. Chem. Eng. Data 27, 74 (1982).

    Article  Google Scholar 

  8. S. Roy, K. Mahali, and B. K. Dolui, Biochem. Ind. J. 3, 63 (2009).

    Google Scholar 

  9. S. Roy, K. Mahali, and B. K. Dolui, Biochem. Ind. J. 4, 71 (2010).

    CAS  Google Scholar 

  10. S. Roy, K. Mahali, S. Akhter, and B. K. Dolui, Asian J. Chem. 25, 6661 (2013).

    Article  CAS  Google Scholar 

  11. S. Roy, K. Mahali, and B. K. Dolui, Asian J. Chem. 25, 8037 (2013).

    Article  CAS  Google Scholar 

  12. K. Mahali, S. Roy, and B. K. Dolui, J. Solut. Chem. 42, 1096 (2013).

    Article  CAS  Google Scholar 

  13. S. Roy, K. Mahali, and B. K. Dolui, J. Solut. Chem. 42, 1472 (2013).

    Article  CAS  Google Scholar 

  14. S. Roy, K. Mahali, S. Mondal, and B. K. Dolui, Russ. J. Gen. Chem. 85, 162 (2015).

    Article  CAS  Google Scholar 

  15. K. Mahali, S. Roy, and B. K. Dolui, J. Chem. Eng. Data 60, 1233 (2015).

    Article  CAS  Google Scholar 

  16. S. Roy, K. Mahali, S. Mondal, and B. K. Dolui, Russ. J. Phys. Chem. A 89, 654 (2015).

    Article  CAS  Google Scholar 

  17. A. V. Kustov and V. P. Korolev, Russ. J. Phys. Chem. A 81, 193 (2007).

    Article  CAS  Google Scholar 

  18. R. G Bates and S. F. Coetzee, Solute–Solvent Interactions (Marcel Dekker, New York, 1969), p. 45.

    Google Scholar 

  19. J. Datta and K. K Kundu, J. Phys. Chem. 86, 4055 (1982).

    Article  CAS  Google Scholar 

  20. K. E. S. Tang and V. A. Bloomfield, Biophys. J. 79, 2222 (2000).

    Article  CAS  Google Scholar 

  21. J. B. Dalton and C. L. A. Schmidt, J. Biol. Chem. 103, 549 (1933).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Shibpur Dinobundhoo Institution (College), Howrah, West Bengal, 711102, India

    Sanjay Roy

  2. Department of Chemistry, Visva-Bharati, Santiniketan, Birbhum, West Bengal, 731235, India

    Samiran Mondal & Bijoy Krishna Dolui

Authors
  1. Sanjay Roy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Samiran Mondal
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bijoy Krishna Dolui
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Bijoy Krishna Dolui.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Roy, S., Mondal, S. & Dolui, B.K. Solvation Thermodynamics of DL-Phenylalanine in Aqueous NaNO3 Solution at 298.15 K. Russ. J. Phys. Chem. 92, 734–738 (2018). https://doi.org/10.1134/S003602441804026X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602441804026X

Keywords

Search

Navigation