Abstract
The Krafft temperature (ТKr) of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides (Alk = n-C n H2n + 1, n = 14, 16, 18) (D-n) and complexes of them with transition metals [Cu(II), Ni(II), Co(II), La(III)] in water is determined via conductometry and compared their corresponding acyclic analogs (alkyltrimethylammonium bromides). The dependence of the complexes’ ТKr on the structure of the inorganic salts and the hydrophobicity of ligands is established. It is shown that the complexation of D-n with metal nitrates and the shortening of the ligand hydrocarbon radical reduce ТKr.
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References
H. Hirata, A. Ohira, and N. Iimura, Langmuir 12, 6044 (1996).
V. G. Carolina and B. L. Bales, J. Phys. Chem. B 107, 5398 (2003).
M. S. Bakshi and R. Sood, Colloids Surf. A: Physicochem. Eng. Asp. 233, 203 (2004).
J. Z. Manojlovic, Thermal Sci. 16, S631 (2012).
S. K. Mehta, R. Kaur, and G. R. Chaudhary, Colloids Surf. A: Physicochem. Eng. Asp. 403, 103 (2012).
R. Kaur and S. K. Mehta, Coord. Chem. Rev. 262, 37 (2013).
S. Bhattacharya and N. Kumari, Coord. Chem. Rev. 253, 2133 (2009).
E. P. Zhil’tsova, M. R. Ibatullina, S. S. Lukashenko, T. N. Pashirova, A. D. Voloshina, V. V. Zobov, S. A. Ziganshina, M. P. Kutyreva, and L. Ya. Zakharova, Russ. Chem. Bull. 65, 1365 (2016).
E. P. Zhiltsova, S. S. Lukashenko, M. R. Ibatullina, et al., in Proceedings of the 8th International Symposium on Design and Synthesis of Supramolecular Architectures, Kazan, Russia, 2016, p. 110.
S. S. Lukashenko, E. P. Zhiltsova, T. N. Pashirova, et al., in Proceedings of the 20th Mendeleev Congress on General and Applied Chemistry, Vol. 2a: Abstracts (Russ. Akad. Nauk, Ekaterinburg, 2016), p. 379.
T. N. Pashirova, E. P. Zhil’tsova, R. R. Kashapov, S. S. Lukashenko, A. I. Litvinov, M. K. Kadirov, L. Ya. Zakharova, and A. I. Konovalov, Russ. Chem. Bull., Int. Ed. 59, 1745 (2010).
M. M. Islam, M. R. Rahman, and M. N. Islam, Int. J. Sci. Eng. Res. 6, 1508 (2015).
E. P. Zhiltsova, S. S. Lukashenko, T. N. Pashirova, et al., J. Mol. Liq. A 210, 136 (2015).
K. R. Lange, Surfactants: Synthesis, Properties, Analysis, Application (Professiya, St. Petersburg, 2004) [in Russian].
E. F. Bukanova, Colloid Chemistry of Surfactants (Mosk. Inst. Tonk. Khim. Tekhnol. im. M. V. Lomonosova, Moscow, 2006) [in Russian].
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Original Russian Text © M.R. Ibatullina, E.P. Zhil’tsova, S.S. Lukashenko, M.M. Anuar, M.P. Kutyreva, L.Ya. Zakharova, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 4, pp. 659–664.
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Ibatullina, M.R., Zhil’tsova, E.P., Lukashenko, S.S. et al. Krafft Temperature of 1-Alkyl-4-Aza-1-Azoniabicyclo[2.2.2]octane Bromide Complexes with Transition Metal Salts. Russ. J. Phys. Chem. 92, 799–803 (2018). https://doi.org/10.1134/S0036024418040064
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DOI: https://doi.org/10.1134/S0036024418040064