Advertisement

Russian Journal of Physical Chemistry A

, Volume 89, Issue 8, pp 1316–1324 | Cite as

Calculating the excess gibbs energy of real ternary solutions on the basis of the non-random two-liquid model

  • V. M. Raeva
Chemical Thermodynamics and Thermochemistry
  • 53 Downloads

Abstract

The concentration dependences of the excess Gibbs energy of ternary solutions with various deviations from ideality are calculated on the basis of the non-random two-liquid (NRTL) model.

Keywords

ternary solutions excess Gibbs energy isoline diagrams NRTL equation deviations from ideal behavior compensated solutions 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Thermodynamics of Vapor-Liquid Equilibrium, Ed. by A. G. Morachevskii (Khimiya, Leningrad, 1989) [in Russian].Google Scholar
  2. 2.
    S. Walas, Phase Equilibria in Chemical Technology (Butterworth-Heinemann, Boston, London, Oxford, UK, 1985; Mir, Moscow, 1989), Ch. 1.Google Scholar
  3. 3.
    V. A. Durov and E. P. Ageev, Thermodynamical Theory of Solutions (Editorial URSS, Moscow, 2003) [in Russian].Google Scholar
  4. 4.
    V. M. Raeva, A. K. Frolkova, and L. A. Serafimov, Theor. Found. Chem. Eng. 30, 21 (1996).Google Scholar
  5. 5.
    V. M. Raeva, A. K. Frolkova, and V. N. Ponomarev, Russ. J. Phys. Chem. A 74, 1068 (2000).Google Scholar
  6. 6.
    L. A. Serafimov and V. M. Raeva, Theor. Found. Chem. Eng. 37, 250 (2003).CrossRefGoogle Scholar
  7. 7.
    N. A. Smirnova, Molecular Theory of Solutions (Khimiya, Leningrad, 1987) [in Russian].Google Scholar
  8. 8.
    T. M. Kushner, G. V. Shutova, and L. A. Serafimov, in Proceedings of the 6th All-Union Conference on the Theory and Practice of Rectification (Severodonetsk, 1991), p. 48.Google Scholar
  9. 9.
    L. A. Serafimov, A. K. Frolkova, and V. M. Raeva, Theor. Found. Chem. Eng. 30, 557 (1996).Google Scholar
  10. 10.
    V. M. Raeva, L. A. Serafimov, and V. N. Stepanov, Russ. J. Phys. Chem. A 87, 1151 (2013).CrossRefGoogle Scholar
  11. 11.
    V. A. Kireev, Zh. Fiz. Khim. 14, 1469 (1940).Google Scholar
  12. 12.
    G. V. Shutova, T. M. Kushner, and L. A. Serafimov, in Problems of Thermodynamics of Heterogeneous Systems and Surface Phenomena Theory, Ed. by V. B. Fillipov (SPb. Univ., St. Petersburg, 1992), Vol. 4, p. 64 [in Russian].Google Scholar
  13. 13.
    L. A. Serafimov, V. M. Raeva, and A. K. Frolkova, Vestn. MITKhT 7(5), 57 (2012).Google Scholar
  14. 14.
    A. Yu. Sazonova, V. M. Raeva, and A. K. Frolkova, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 56(11), 50 (2013).Google Scholar
  15. 15.
    A. Yu. Sazonova, V. M. Raeva, T. V. Chelyuskina, and A. K. Frolkova, Theor. Found. Chem. Eng. 48, 148 (2014).CrossRefGoogle Scholar
  16. 16.
    A. Y. Sazonova and V. M. Raeva, in Proceedings of the 10th International Conference on Distillation and Absorption, Sept. 14–17, 2014, Friedrichshafen, Germany, p. 885.Google Scholar
  17. 17.
    Ch.-CH. Hsu and Ch.-H. Tu, J. Chin. Inst. Chem. Eng. 39, 265 (2008).CrossRefGoogle Scholar
  18. 18.
    R. W. Hanks and J. J. Christensen, Thermochim. Acta 23, 41 (1978).CrossRefGoogle Scholar
  19. 19.
    M. R. Generro de Chialvo and A. C. de Chialvo, Ind. Eng. Chem. Res. 33, 1035 (1994).CrossRefGoogle Scholar
  20. 20.
    S. P. Šebanović, I. R. Grgurić, M. Lj. Kijevčanin, A. Ž. Tasić, and B. D. Djordjević, Korean J. Chem. Eng. 21, 858 (2004).CrossRefGoogle Scholar
  21. 21.
    K. A. G. Schmidt, Y. Maham, and A. E. Mather, J. Therm. Anal. Calorim. 89, 61 (2007).CrossRefGoogle Scholar
  22. 22.
    V. M. Raeva, Cand. Sci. (Tech. Sci.) Dissertation (Mosc. Inst. Fine Chem. Technol., Moscow, 1998).Google Scholar
  23. 23.
    L. A. Serafimov, A. K. Frolkova, and V. M. Raeva, Theor. Found. Chem. Eng. 36, 353 (2002).CrossRefGoogle Scholar
  24. 24.
    L. A. Serafimov, A. K. Frolkova, and V. M. Raeva, Theor. Found. Chem. Eng. 37, 157 (2003).CrossRefGoogle Scholar
  25. 25.
    V. M. Raeva, S. K. Klyuchikov, A. K. Frolkova, and L. A. Serafimov, Russ. J. Phys. Chem. A 83, 775 (2009).CrossRefGoogle Scholar
  26. 26.
    L. A. Serafimov, V. M. Raeva, and V. N. Stepanov, Theor. Found. Chem. Eng. 46, 221 (2012).CrossRefGoogle Scholar
  27. 27.
    V. M. Raeva, L. A. Serafimov, and V. N. Stepanov, Vestn. MITKhT 7(1), 51 (2012).Google Scholar
  28. 28.
    V. M. Raeva, L. A. Serafimov, and V. N. Stepanov, Russ. J. Phys. Chem. A 85, 529 (2011).CrossRefGoogle Scholar
  29. 29.
    J. R. Loehe, H. C. van Ness, and M. M. Abbott, J. Chem. Eng. Data 26, 178 (1981).CrossRefGoogle Scholar
  30. 30.
    V. V. Kocherbitov and A. M. Toikka, Russ. J. Appl. Chem. 70, 1691 (1997).Google Scholar
  31. 31.
    G. Conti, P. Gianni, L. Lepori, and E. Matteoli, Pure Appl. Chem. 67, 1849 (1998).Google Scholar
  32. 32.
    I. L. Acevedo, G. C. Pedrosa, E. L. Arancibia, and M. Katz, J. Solution Chem. 30, 1029 (2001).CrossRefGoogle Scholar
  33. 33.
    E. Matteoli, P. Gianni, and L. Lepori, J. Chem. Eng. Data 55, 5441 (2010).CrossRefGoogle Scholar
  34. 34.
    R. F. Platford, J. Solution Chem. 4, 37 (1975).CrossRefGoogle Scholar
  35. 35.
    J. W. Morris, P. J. Mulvey, M. M. Abbott, and H. C. van Ness, J. Chem. Eng. Data 20, 403 (1975).CrossRefGoogle Scholar
  36. 36.
    P. Gianni, L. Lepori, and E. Matteoli, Fluid Phase Equilib. 297, 52 (2010).CrossRefGoogle Scholar
  37. 37.
    P. Gianni, L. Lepori, E. Matteoli, and M. C. Righetti, Fluid Phase Equilib. 356, 157 (2013).CrossRefGoogle Scholar
  38. 38.
    R. C. Reid, J. Prausnitz, and T. Sherwood, The Properties of Gases and Liquids (McGraw-Hill, New York, 1966; Khimiya, Leningrad, 1982).Google Scholar
  39. 39.
    A. Mejia, H. Segura, M. Cartes, L. Cifuentes, and M. Flores, Fluid Phase Equilib. 273, 68 (2008).CrossRefGoogle Scholar
  40. 40.
    M. T. Sanz, B. Blanco, S. Beltran, et al., J. Chem. Eng. Data 46, 635 (2001).CrossRefGoogle Scholar
  41. 41.
    A. V. Nikitskii, T. M. Kushner, and L. A. Serafimov, Russ. J. Phys. Chem. A 72, 1943 (1998).Google Scholar
  42. 42.
    L. A. Serafimov and T. V. Chelyuskina, Russ. J. Phys. Chem. A 85, 767 (2011).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  1. 1.Moscow State University of Fine Chemical TechnologiesMoscowRussia

Personalised recommendations