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Structural Features of Monomeric Octahedral Monooxo d2-Renium(V) Complexes with Oxygen Atoms of O,N Bidentate-Chelating Ligands (Ln): 2. [ReO(Ln)(Lmono)3] Complexes with Six- and Seven-Membered Chelate Rings ReNC3O and ReNC4O

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Abstract

Structural features of 26 mononuclear octahedral monooxo d2-Re(V) complexes with singly charged oxygen atoms of bidentate-chelating (O,N) ligands (Ln), namely, [ReO(Ln)(Lmono)3] (where Lmono stands for a monodentate ligand) containing six- and seven-membered chelate rings ReNC3O and ReNC4O, are considered. The atoms O(Ln), with one exception, are in the trans positions to ligands O(oxo). In [ReO(OPPh3)Cl2(L35)], the trans position to the oxo ligand is occupied by the neutral oxygen atom of ligand OPPh3. In [ReO(Hal)2(Ln)(Lmono)] [(Lmono = PPh3, AsPPh3, and OPPh3)] structures, two geometric isomers exist: halide ligands are either in the cis- or in the trans position to each other.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. S. Sergienko & A. V. Churakov

  2. All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences, Moscow, 125190, Russia

    V. S. Sergienko

Authors
  1. V. S. Sergienko
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  2. A. V. Churakov
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Correspondence to V. S. Sergienko.

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Original Russian Text © V.S. Sergienko, A.V. Churakov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 6, pp. 718–727.

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Sergienko, V.S., Churakov, A.V. Structural Features of Monomeric Octahedral Monooxo d2-Renium(V) Complexes with Oxygen Atoms of O,N Bidentate-Chelating Ligands (Ln): 2. [ReO(Ln)(Lmono)3] Complexes with Six- and Seven-Membered Chelate Rings ReNC3O and ReNC4O. Russ. J. Inorg. Chem. 63, 753–763 (2018). https://doi.org/10.1134/S0036023618060219

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  • DOI: https://doi.org/10.1134/S0036023618060219

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