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Protonation of the Dodecahydro-closo-Dodecaborate Anion in CH3CN/CF3COOH

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The behavior of the [B12H12]2– anion in CH3CN, CF3COOH, and the CH3CN/CF3COOH system is studied by IR spectroscopy. Based on the IR spectroscopy data correlated with the data obtained when studying the protonation processes of boron cluster anions [B6H6]2– and [B10H10]2–, the possibility to prepare the protonated form of the closo-dodecaborate anion, namely monoanion [B12H13]–, is concluded in CF3COOH and the CH3CN/CF3COOH system. In the IR spectra of salts of the protonated forms of anions [BnHn]2– (n = 6, 10, 12) in solutions and Nujol mulls, a high-frequency shift of the ν(BH) absorption bands is observed as compared with the spectra of salts of non-protonated anions Cat2[BnHn] (Δν = 70–100 cm–1).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    L. V. Goeva, V. V. Avdeeva, E. A. Malinina & N. T. Kuznetsov

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  1. L. V. Goeva
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  2. V. V. Avdeeva
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  3. E. A. Malinina
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  4. N. T. Kuznetsov
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Correspondence to V. V. Avdeeva.

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Original Russian Text © L.V. Goeva, V.V. Avdeeva, E.A. Malinina, N.T. Kuznetsov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 6, pp. 670–677.

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Goeva, L.V., Avdeeva, V.V., Malinina, E.A. et al. Protonation of the Dodecahydro-closo-Dodecaborate Anion in CH3CN/CF3COOH. Russ. J. Inorg. Chem. 63, 700–707 (2018). https://doi.org/10.1134/S0036023618060116

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  • DOI: https://doi.org/10.1134/S0036023618060116

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