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Russian Journal of Inorganic Chemistry

, Volume 63, Issue 3, pp 406–413 | Cite as

Extraction of Rare-Earth Elements from Hydrochloric Acid by Carbamoyl Methyl Phosphine Oxides in the Presence of Ionic Liquids

  • A. N. Turanov
  • V. K. Karandashev
  • A. N. Yarkevich
Physical Chemistry of Solutions
  • 22 Downloads

Abstract

The distribution of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y between aqueous HCl solutions and solutions of carbamoyl methyl phosphine oxides (CMPOs) has been studied in the presence of the 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide ionic liquid (IL). The efficiency and selectivity of REE(III) extraction by CMPO solutions increase considerably in the presence of the ionic liquid in the organic phase. The stoichiometry of the extractable complexes has been determined; the effects of the IL cation, organic solvent, CMPO structure, and aqueous HCl concentration on the efficiency of REE(III) recovery into the organic phase has been considered.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. N. Turanov
    • 1
  • V. K. Karandashev
    • 2
    • 3
  • A. N. Yarkevich
    • 4
  1. 1.Institute of Solid State PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Institute of Problems in Microelectronics and High-Purity Compounds TechnologyRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  3. 3.MISiS National Research Technological UniversityMoscowRussia
  4. 4.Institute of Physiologically Active CompoundsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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