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μ2-Oxobis[(aroxo)tris(para-tolyl)antimony]: Synthesis and Structure

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Abstract

µ2-Oxobis[(2,4,6-tribromophenoxo)tris(para-tolyl)antimony] (I), µ2-oxobis[(2,3,4,5,6-pentachlorophenoxo) tris(para-tolyl)antimony] (II), and µ2-oxobis(2,4-dinitrophenoxo)tris(para-tolyl)antimony] (III) have been synthesized with high yields by the reaction of tris(para-tolyl)antimony with 2,4,6-tribromo-, 2,3,4,5,6-pentachloro-, and 2,4-dinitrophenol, respectively, in ether in the presence of tert-butylhydroperoxide. The Sb atoms in complexes I, II, and III have a distorted trigonal bipyramidal coordination with the aroxyl ligands and the bridging oxygen atom in axial positions. The central Sb–O–Sb moiety in molecules of complexes I–III has an angular structure.

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Authors and Affiliations

  1. National South Ural State Research University, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

Authors
  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. A. N. Efremov
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, A.N. Efremov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 3, pp. 327–333.

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Sharutin, V.V., Sharutina, O.K. & Efremov, A.N. μ2-Oxobis[(aroxo)tris(para-tolyl)antimony]: Synthesis and Structure. Russ. J. Inorg. Chem. 63, 343–348 (2018). https://doi.org/10.1134/S0036023618030208

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  • DOI: https://doi.org/10.1134/S0036023618030208

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