Russian Journal of Inorganic Chemistry

, Volume 63, Issue 3, pp 338–342 | Cite as

Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4]

  • Ya. A. Medvedkov
  • M. S. Grigor’ev
  • L. B. Serezhkina
  • D. V. Pushkin
  • V. N. Serezhkin
Coordination Compounds
  • 4 Downloads

Abstract

Crystals of [(UO2)2(mal)(Cl)2(DMA)4] (mal2– is malonate ion and DMA is dimethylacetamide) have been synthesized and studied by X-ray crystallography. The key structure units are binuclear island complexes [(UO2)2(mal)(Cl)2(DMA)4], which belong to the A2Q02M 6 1 crystal-chemical group (A = UO 2 2+ , Q02 = mal2–, M1 = Cl and DMA) of uranyl complexes. The complexes form a framework through a system of intermolecular nonbonded interactions, which are characterized by means of the Voronoi–Direchlet molecular polyhedron method.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    V. N. Serezhkin, M. S. Grigor’ev, A. V. Vologzhanina, et al., Russ. Chem. Bull. 62, 1835 (2013).CrossRefGoogle Scholar
  2. 2.
    L. B. Serezhkina, E. V. Peresypkina, A. V. Virovets, et al., Crystallogr. Rep. 59, 48 (2014).CrossRefGoogle Scholar
  3. 3.
    L. B. Serezhkina, E. V. Peresypkina, Ya. A. Medvedkov, et al., Russ. J. Inorg. Chem. 58, 1465 (2013).CrossRefGoogle Scholar
  4. 4.
    L. B. Serezhkina, M. S. Grigor’ev, Ya. A. Medvedkov, and V. N. Serezhkin, Crystallogr. Rep. 60, 670 (2015).CrossRefGoogle Scholar
  5. 5.
    Ya. A. Medvedkov, L. B. Serezhkina, M. S. Grigor’ev, and V. N. Serezhkin, Crystallogr. Rep. 61, 383 (2016).CrossRefGoogle Scholar
  6. 6.
    Ya. A. Medvedkov, M. S. Grigor’ev, L. B. Serezhkina, et al., Radiochemistry 59, 113 (2017).CrossRefGoogle Scholar
  7. 7.
    SAINT-Plus, Version 7.23, Bruker AXS, Inc., Madison, Wisconsin, USA, 2007.Google Scholar
  8. 8.
    SADABS, Bruker AXS, Inc., Madison, Wisconsin, USA, 2008.Google Scholar
  9. 9.
    G. M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2008).CrossRefGoogle Scholar
  10. 10.
    G. M. Sheldrick, Acta Crystallogr. Sect. C 71, 3 (2015).CrossRefGoogle Scholar
  11. 11.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Interscience, New York, 1986).Google Scholar
  12. 12.
    D. Bougeard, J. Villepin, and A. Novak, Spectrochim. Acta A 44, 1281 (1988).CrossRefGoogle Scholar
  13. 13.
    G. Durgaprasad, D. N. Sathyanarayana, and C. C. Patel, Spectroshim. Acta A 28, 2311 (1972).CrossRefGoogle Scholar
  14. 14.
    V. N. Serezhkin, Yu. N. Mikhailov, and Yu. A. Buslaev, Russ. J. Inorg. Chem. 42, 1871 (1997).Google Scholar
  15. 15.
    V. N. Serezhkin, M. O. Karasev, and L. B. Serezhkina, Radiochemistry 55, 137 (2013).CrossRefGoogle Scholar
  16. 16.
    V. N. Serezhkin, Ya. A. Medvedkov, L. B. Serezhkina, and D. V. Pushkin, Russ. J. Phys. Chem. 89, 1018 (2015).CrossRefGoogle Scholar
  17. 17.
    V. N. Serezhkin and L. B. Serezhkina, Crystallogr. Rep. 57, 33 (2012).CrossRefGoogle Scholar
  18. 18.
    V. N. Serezhkin and A. V. Savchenkov, Cryst. Growth Des. 15, 2878 (2015).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Ya. A. Medvedkov
    • 1
  • M. S. Grigor’ev
    • 2
  • L. B. Serezhkina
    • 1
  • D. V. Pushkin
    • 1
  • V. N. Serezhkin
    • 1
  1. 1.Samara National Research University Named after Academician S.P. KorolevSamaraRussia
  2. 2.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations