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Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy

  • Physical Methods of Investigation
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Abstract

The complex formation of lithium thiocyanate with benzo-15-crown-5 (B15C5) was studied. The possibility of formation of both anhydrous and crystal water-containing complexes was demonstrated. The complexes LiB15C5NCS and LiB15C5H2ONCS were synthesized and characterized by X-ray diffraction and IR spectroscopy.

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References

  1. A. Yu. Tsivadze, A. A. Varnek, and V. E. Khutorskii, Metal Complexes with Crown Ligands (Nauka, Moscow, 1991) [in Russian].

    Google Scholar 

  2. O. V. Marokin, V. I. Zhilov, S. V. Demin, et al., Abstracts of Papers, X Conference on Extraction, Ufa, 1994 (Moscow, 1994), p. 147 [in Russian].

    Google Scholar 

  3. A. Yu. Tsivadze, V. I. Zhilov, and S. V. Demin, Koord. Khim. 22, 243 (1996).

    Google Scholar 

  4. SMART and SADABS Software Reference Manuals, Bruker AXS, Inc., Madison, Wisconsin, USA, 1998.

  5. SAINT, Version 6.02A, Bruker AXS, Inc., Madison, Wisconsin, USA, 2001.

  6. SHELXTL-Plus, Version 5.10, Bruker AXS, Inc., Madison, Wisconsin, USA, 1997.

  7. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009). doi 10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  8. L. I. Demina, L. G. Kuz’mina, S. V. Demin, et al., Russ. J. Inorg. Chem. 62, 1536 (2017).

    Article  CAS  Google Scholar 

  9. I. K. Kireeva, N. B. Generalova, V. A. Trofimov, and A. Yu. Tsivadze, Zh. Neorg. Khim. 36, 1464 (1991).

    CAS  Google Scholar 

  10. V. A. Trofimov, I. K. Kireeva, N. B. Generalova, and A. Yu. Tsivadze, Koord. Khim. 16, 1458 (1990).

    CAS  Google Scholar 

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Correspondence to V. I. Zhilov.

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Original Russian Text © L.G. Kuz’mina, L.I. Demina, S.V. Demin, N.A. Shokurova, V.I. Zhilov, A.Yu. Tsivadze, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 3, pp. 334–337.

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Kuz’mina, L.G., Demina, L.I., Demin, S.V. et al. Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy. Russ. J. Inorg. Chem. 63, 357–360 (2018). https://doi.org/10.1134/S0036023618030129

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  • DOI: https://doi.org/10.1134/S0036023618030129

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