Skip to main content
SpringerLink
Log in

New Hybrid Material: (C3H6N3)4Bi2Cl10. Synthesis, Structural Study and Spectroscopic Behavior

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The structure of (C3H6N3)4Bi2Cl10 was determined by single crystal X-ray diffraction at room temperature. It crystallizes in the orthorhombic space group Pcmn, with a = 9.430 (1) Å, b = 17.426 (3) Å, c = 19.883(5) Å, V = 3267.3 (11) Å3 and Z = 4. The structure consists of discrete binuclear [Bi2Cl10]4– anions and 3-aminopyrazolium cations. The crystal packing is governed by weak N–H···Cl hydrogen bonds, π–π and electrostatic Cl···Cl interactions. Infrared spectrum is used to gain more information on the title compound. An assignment of the observed vibration modes is reported. The crystal morphology is studied using the BFDH laws. The calculated HOMO and LUMO energies show that charge transfer occur within organic and inorganic molecules. The optical absorption of the zero-dimensional hybrid was also investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Lü, E. H. Shen, Y. G. Li, et al., Cryst. Growth & Des. 5, 65 (2005).

    Article  Google Scholar 

  2. D.B. Mitzi and P. Brock, Inorg. Chem. 40, 2096 (2001).

    Article  CAS  Google Scholar 

  3. H. Ferjani, H. Boughzala, and A. Driss, Acta Crystallogr. Sect. E 68, m615 (2012).

    Article  Google Scholar 

  4. M. A. Tershansy, A. M. Goforth, M. D. Smith, et al., Acta Crystallogr. Sect. E 62, m3269 (2006).

    Article  Google Scholar 

  5. A. Piecha, R. Jakubas, G. Bator, and J. Baran, Vib. Spectrosc. 51, 226 (2009).

    Article  CAS  Google Scholar 

  6. T. Ben Rhayem, H. Boughzala, A. Driss, Acta Crystallogr. Sect. E 69, m330 (2013).

    Article  Google Scholar 

  7. D. B. Mitzi, C. D. Dimitrakopoulos, J. Rosner, et al., Adv. Mater. 14, 1772 (2002).

    Article  CAS  Google Scholar 

  8. D. B. Mitzi, K. Chondroudis, and C. R. Kagan, IBM. J. Res. Dev. 45 (1), 29 (2001).

    Article  CAS  Google Scholar 

  9. W. Bi, N. Louvain, N. Mercier, et al., Adv. Mater. 20, 1013 (2008).

    Article  CAS  Google Scholar 

  10. A. M. Goforth, L. Peterson, Jr., M. D. Smith., and H.-C. Z. Loye., J. Solid State Chem. 178, 3529 (2005).

    Article  CAS  Google Scholar 

  11. G. C. Papavassiliou, G. A. Mousdis, C. P. Raptopoulou, and A. Terzis, Z. Naturforsch., B: Chem. Sci. 54, 1405 (1999).

    CAS  Google Scholar 

  12. C. Feldmann, J. Solid State Chem. 172, 53 (2003).

    Article  CAS  Google Scholar 

  13. H. Krautscheild and F. Vielsack, J. Chem. Soc., Dalton Trans. 16, 2731 (1999).

    Article  Google Scholar 

  14. G. A. Fisher and N. C. Norman, Adv. Inorg. Chem. 41, 233 (1994).

    Article  CAS  Google Scholar 

  15. A. J. M. Duisenberg, J. Appl. Crystallogr. 25, 92 (1992).

    Article  CAS  Google Scholar 

  16. A. C. T. North, D. C. Phillips, and F. S. Mathews, Acta Crystallogr., Sect. A: Found. Crystallogr. 24, 351 (1968).

    Article  Google Scholar 

  17. G. M. Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr. 64, 112 (2008).

    Article  CAS  Google Scholar 

  18. K. Brandenburg, DIAMOND, Crystal Impact (GbR, Bonn, Germany, 2008).

    Google Scholar 

  19. Mercury CSD 3.0.1 (Build RC6) (Cambridge Crystallographic Data Centre (CCDC), 2013).

  20. A. Coelho, Topas V 4.2 (Bruker AXS, 2007–2009).

    Google Scholar 

  21. J. P. H. Charmant, N. C. Norman, J. Starbuck, Acta Crystallogr. Sect. E 58, m144 (2002).

    Article  Google Scholar 

  22. G. A. Bowmaker, P. C. Junk, A. M. Lee, et al., Aust. J. Chem. 51, 293 (1998).

    Article  CAS  Google Scholar 

  23. A. Bravais, Etudes Cristallographiques (Gauthier-Villars, Paris, France, 1913).

    Google Scholar 

  24. G. Fridel, Bull. Soc. Fr. 30, 326 (1907).

    Google Scholar 

  25. J. D. H. Donnay and D. Harker, Am. Mineral. 22, 446 (1937).

    CAS  Google Scholar 

  26. V. M. Leovac, Z. D. Tomić, A. Kovács, et al., J. Organomet. Chem. 693, 77 (2008).

    Article  CAS  Google Scholar 

  27. J. A. Jimenez, R. M. Claramunt, O. Mó, et al., Phys. Chem. Chem. Phys. 1, 5113 (1999).

    Article  Google Scholar 

  28. E. Kavitha, N. Sundaranganesan, and S. Sebastian, Ind. J. Pure Appl. Phys. 48, 20 (2010).

    CAS  Google Scholar 

  29. O. Prasad, L. Sinha, and N. Kumar, J. At. Mol. Sci. 1, 201 (2010).

    Google Scholar 

  30. I. Fleming, Frontier Orbitals and Organic Chemical Reactions (Wiley, New York, 1976).

    Google Scholar 

  31. Cache: Work System Pro Version 7.5.0.85 (Fujitsu Limited. 2000–2006 Oxford Molecular).

  32. D. F. V. Lewis, C. Ioannides, and D. V. Parke, Xenobiotica. 24, 401 (1994).

    Article  CAS  Google Scholar 

  33. K. Oldenburg, A. Vogler, I. Mikό, and O. Horváth, Inorg. Chim. Acta 248, 107 (1996).

    Article  CAS  Google Scholar 

  34. A. Vogler, A. Paukner, and H. Kunkely, Coord. Chem. Rev. 97, 285 (1990).

    Article  CAS  Google Scholar 

  35. A. Vogler and H. Nikol, Pure Appl. Chem. 64, 1311 (1992).

    Article  CAS  Google Scholar 

  36. H. Nikol and A. Vogler, J. Amer. Chem. Soc. 113, 8986 (1991).

    Article  Google Scholar 

  37. W. R. Mason, Inorg. Chem. 38, 2742 (1999).

    Article  CAS  Google Scholar 

  38. M. V. S. Prasad, K. Chaitanya, N. U. Sri, and V. Veeraiah, Spectrochim. Acta, Pt A: Mol. Biomol. Spectrosc. 99, 379 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, College of Science, IMSIU (Al Imam Mohammad Ibn Saud Islamic University), Riyadh, 11623, Kingdom of Saudi Arabia

    Hela Ferjani

  2. Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, Manar II Tunis, Tunis, 2092, Tunisia

    Hela Ferjani & Habib Boughzala

Authors
  1. Hela Ferjani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Habib Boughzala
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hela Ferjani.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ferjani, H., Boughzala, H. New Hybrid Material: (C3H6N3)4Bi2Cl10. Synthesis, Structural Study and Spectroscopic Behavior. Russ. J. Inorg. Chem. 63, 349–356 (2018). https://doi.org/10.1134/S0036023618030099

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023618030099

Search

Navigation