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Thin films of the composition 8% Y2O3–92% ZrO2 (8YSZ) as gas-sensing materials for oxygen detection

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The synthesis of hydrolytically active heteroligand precursors of the composition [M(O2C5H7) x (iOC5H11) y ] (M = Zr4+ and Y3+) using zirconium and yttrium acetylacetonates was investigated. It was shown that the reactivity of the obtained precursors in hydrolysis and polycondensation depends on the composition of the coordination sphere. It was studied how thin films of their solutions are applied by dip coating to the surface of Al2O3 substrates with platinum interdigital electrodes and a microheater. A study was made of the effect of the crystallization conditions and thickness of the oxide coatings of the composition 8 mol % Y2O3–ZrO2 on their microstructure and sensor characteristics in oxygen detection.

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References

  1. M. D. Angelica and Y. Fong, NIH Public Access 141, 520 (2008).

    Google Scholar 

  2. A. Carreau, B. Hafny-Rahbi, A. Matejuk, et al., J. Cell. Mol. Med. 15, 1239 (2011).

    Article  CAS  Google Scholar 

  3. R. E. Clutton, G. Schoeffmann, M. Chesnil, et al., Vet. Rec. 169, 440 (2011).

    Article  CAS  Google Scholar 

  4. P. Odier, J. F. Baumard, D. Panis, et al., J. Solid State Chem. 12, 324 (1975).

    Article  CAS  Google Scholar 

  5. S. Ikeda, O. Sakurai, K. Uematsu, et al., J. Mater. Sci. 20, 4593 (1985).

    Article  CAS  Google Scholar 

  6. M. Ihara, T. Kusano, and C. Yokoyama, J. Electrochem. Soc. 148, A209 (2001).

    Article  CAS  Google Scholar 

  7. J. Schefold, A. Brisse, and M. Zahid, ECS Trans. 25, 1021 (2009).

    Article  CAS  Google Scholar 

  8. A. Kishimoto, H. Hasunuma, T. Teranishi, et al., J. Alloys Compd. 648, 740 (2015).

    Article  CAS  Google Scholar 

  9. S. Omar, W. B. Najib, W. Chen, et al., J. Am. Ceram. Soc. 95, 1965 (2012).

    Article  CAS  Google Scholar 

  10. P. K. Sekhar, E. L. Brosha, R. Mukundan, et al., Solid State Ionics 181, 947 (2010).

    Article  CAS  Google Scholar 

  11. R. Radhakrishnan, A. V. Virkar, S. C. Singhal, et al., Sens. Actuat. B Chem. 105, 312 (2005).

    Article  CAS  Google Scholar 

  12. A. Cirera, C. Lopez-Gándara, and F. M. Ramos, J. Sensor. ID 258489 (2009).

    Google Scholar 

  13. E. Caproni, D. Gouvea, and R. Muccillo, Ceram. Int. 37, 273 (2011).

    Article  CAS  Google Scholar 

  14. M. Schulz, H. Fritze, and C. Stenzel, Sens. Actuat. B Chem. 187, 503 (2011).

    Article  Google Scholar 

  15. S. Yu, Q. Wu, M. Tabib-Azar, et al., Sens. Actuat. B Chem. 85, 212 (2002).

    Article  CAS  Google Scholar 

  16. M. Schelter, J. Zosel, W. Oelßner, et al., Sens. Actuat. B Chem. 187, 209 (2013).

    Article  CAS  Google Scholar 

  17. A. Lari, A. Khodadadi, and Y. Mortazavi, Sens. Actuat. B Chem. 139, 361 (2009).

    Article  CAS  Google Scholar 

  18. C. C. Chao, J. S. Park, X. Tian, et al., ACS Nano. 7, 2186 (2013).

    Article  CAS  Google Scholar 

  19. C. Xia, X. Lu, Y. Yan, et al., Appl. Surf. Sci. 257, 7952 (2011).

    Article  CAS  Google Scholar 

  20. J. F. Fernández-Sánchez, R. Cannas, S. Spichiger, et al., Anal. Chim. Acta 566, 271 (2006).

    Article  Google Scholar 

  21. J. M. Rheaume and A. P. Pisano, Ionics (Kiel) 17, 99 (2011).

    Article  CAS  Google Scholar 

  22. J. H. Joo and G. M. Choi, Solid State Ionics 177, 1053 (2006).

    Article  CAS  Google Scholar 

  23. H. B. Wang, C. R. Xia, G. Y. Meng, et al., Mater. Lett. 44, 23 (2000).

    Article  CAS  Google Scholar 

  24. N. T. Kuznetsov, V. G. Sevast’yanov, E. P. Simonenko, et al., RF Patent No. 2, 407705 (2010).

    Google Scholar 

  25. N. P. Simonenko, E. P. Simonenko, V. G. Sevastyanov, et al., Russ. J. Inorg. Chem. 60, 795 (2015). doi 10.1134/S0036023615070153

    Article  CAS  Google Scholar 

  26. N. P. Simonenko, E. P. Simonenko, V. G. Sevastyanov, et al., Russ. J. Inorg. Chem. 61, 667 (2016). doi 10.1134/S003602361606019X

    Article  CAS  Google Scholar 

  27. N. P. Simonenko, E. P. Simonenko, V. G. Sevastyanov, et al., Russ. J. Inorg. Chem. 61, 805 (2016). doi 10.1134/S0036023616070184

    Article  CAS  Google Scholar 

  28. T. L. Egorova, M. V. Kalinina, E. P. Simonenko, et al., Russ. J. Inorg. Chem. 61, 1061 (2016). doi 10.1134/S0036023616090047

    Article  CAS  Google Scholar 

  29. N. P. Simonenko, V. A. Nikolaev, E. P. Simonenko, et al., Russ. J. Inorg. Chem. 61, 1505 (2016). doi 10.1134/S0036023616120184

    Article  CAS  Google Scholar 

  30. V. G. Sevast’yanov, E. P. Simonenko, N. P. Simonenko, et al., Russ. J. Inorg. Chem. 57, 307 (2012). doi 10.1134/S0036023612030278

    Article  Google Scholar 

  31. E. P. Simonenko, N. P. Simonenko, V. G. Sevastyanov, et al., Russ. J. Inorg. Chem. 57, 1521 (2012). doi 10.1134/S0036023612120194

    Article  CAS  Google Scholar 

  32. N. P. Simonenko, V. A. Nikolaev, E. P. Simonenko, et al., Russ. J. Inorg. Chem. 61, 929 (2016). doi 10.1134/S0036023616080167

    Article  CAS  Google Scholar 

  33. E. P. Simonenko, N. P. Simonenko, V. G. Sevastyanov, et al., Yad. Fiz. Inzh. 5, 331 (2014).

    Google Scholar 

  34. E. P. Simonenko, N. P. Simonenko, V. G. Sevastyanov, et al., Kompoz. Nanostrukt., No. 4, 52 (2011).

    Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    N. P. Simonenko, E. P. Simonenko, A. S. Mokrushin, V. S. Popov, V. G. Sevastyanov & N. T. Kuznetsov

  2. Samara National Research University, Moskovskoe sh. 34, Samara, 443086, Russia

    E. P. Simonenko, V. G. Sevastyanov & N. T. Kuznetsov

  3. National Research Center “Kurchatov Institute”, pl. akademika Kurchatova 1, Moscow, 123098, Russia

    A. A. Vasiliev

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  1. N. P. Simonenko
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  2. E. P. Simonenko
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  4. V. S. Popov
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  6. V. G. Sevastyanov
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  7. N. T. Kuznetsov
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Correspondence to N. P. Simonenko.

Additional information

Original Russian Text © N.P. Simonenko, E.P. Simonenko, A.S. Mokrushin, V.S. Popov, A.A. Vasiliev, V.G. Sevastyanov, N.T. Kuznetsov, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 6, pp. 707–714.

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Simonenko, N.P., Simonenko, E.P., Mokrushin, A.S. et al. Thin films of the composition 8% Y2O3–92% ZrO2 (8YSZ) as gas-sensing materials for oxygen detection. Russ. J. Inorg. Chem. 62, 695–701 (2017). https://doi.org/10.1134/S0036023617060213

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  • DOI: https://doi.org/10.1134/S0036023617060213

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