Russian Journal of Inorganic Chemistry

, Volume 62, Issue 6, pp 766–776 | Cite as

Bismuth complexes [p-Tol4P] 2 + [Bi2I8(THF)2]2–, [p-Tol4Sb] 2 + [Bi2I8(THF)2]2–, [p-Tol4P] 2 + [Bi2I8(DMSO)2]2–, [Bu4P] n + [(Bi2I7) n ] n, [p-Tol4P] n + [(Bi2I7) n ] n, and [p-Tol4Sb] n + [(Bi2I7) n ] n: Synthesis and structure

  • V. V. Sharutin
  • O. K. Sharutina
  • R. M. Khisamov
  • V. S. Senchurin
Coordination Compounds

Abstract

The complexes [p-Tol4P] 2 + [Bi2I8(THF)2]2–, [p-Tol4Sb] 2 + [Bi2I8(THF)2]2–, [p-Tol4P] 2 + [Bi2I8(DMSO)2]2–, [Bu4P] n + [(Bi2I7) n ] n, [p-Tol4P] n +[(Bi2I7) n ] n, and [p-Tol4Sb] n + [(Bi2I7) n ] n were synthesized by the reaction between bismuth iodides and tetrabutyl- and tetraphenylphosphonium, tetra-para-tolylphosphonium and -stibonium iodides in tetrahydrofuran, dimethyl sulfoxide, acetone, and ethyl cellosolve. The crystal structures of the synthesized complexes containing bi- and polynuclear anions with an octahedral coordination of bismuth atoms were characterized by X-ray diffraction.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • V. V. Sharutin
    • 1
  • O. K. Sharutina
    • 1
  • R. M. Khisamov
    • 1
  • V. S. Senchurin
    • 1
  1. 1.National South Ural State Research UniversityChelyabinskRussia

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