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Russian Journal of Inorganic Chemistry

, Volume 62, Issue 6, pp 808–813 | Cite as

Reaction of the [B10H9O2C4H8] anion with C-nucleophiles

  • E. Yu. Matveev
  • S. S. Akimov
  • A. S. Kubasov
  • A. I. Nichugovskii
  • A. S. Nartov
  • V. M. Retivov
  • K. Yu. Zhizhin
  • N. T. Kuznetsov
Physical Methods of Investigation
  • 32 Downloads

Abstract

The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8]) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. Yu. Matveev
    • 1
    • 2
  • S. S. Akimov
    • 3
  • A. S. Kubasov
    • 1
  • A. I. Nichugovskii
    • 2
  • A. S. Nartov
    • 4
  • V. M. Retivov
    • 4
  • K. Yu. Zhizhin
    • 1
    • 2
  • N. T. Kuznetsov
    • 1
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Moscow Technological University (MITHT)MoscowRussia
  3. 3.Chimmed Ltd.MoscowRussia
  4. 4.Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”MoscowRussia

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