Reaction of the [B10H9O2C4H8]– anion with C-nucleophiles
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The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8]–) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).
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