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Russian Journal of Inorganic Chemistry

, Volume 62, Issue 6, pp 736–745 | Cite as

Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine

  • R. E. Khoma
  • V. O. Gel’mbol’dt
  • A. A. Ennan
  • V. N. Baumer
  • A. N. Puzan
  • T. V. Koksharova
  • A. V. Mazepa
Coordination Compounds
  • 19 Downloads

Abstract

Reaction products have been isolated from SO2–L–H2O–О2 systems (L = ethylenediamine, N,N,N′,N′-tetramethylethylenediamine, piperazine, and morpholine) as onium salts [H3NCH2CH2NH3]SO4, [(CH3)2NHCH2CH2NH(CH3)2]SO4, [(CH3)2NHCH2CH2NH(CH3)2]S2O6 ⋅ H2O, [C4H8N2H4]SO3 ⋅ H2O, [C4H8N2H4]S2O6, [C4H8N2H4]SO4 ⋅ H2O, [O(C2H4)2NH2]2SO4 ⋅ H2O. The prepared compounds have been characterized by X-ray diffraction analysis, X-ray powder diffraction, IR and mass spectroscopy.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • R. E. Khoma
    • 1
    • 2
  • V. O. Gel’mbol’dt
    • 3
  • A. A. Ennan
    • 1
  • V. N. Baumer
    • 4
  • A. N. Puzan
    • 4
  • T. V. Koksharova
    • 2
  • A. V. Mazepa
    • 5
  1. 1.Physicochemical Institute for Environment and Human ProtectionNational Academy of Sciences of UkraineOdessaUkraine
  2. 2.Odessa National UniversityOdessaUkraine
  3. 3.Odessa National Medical UniversityOdessaUkraine
  4. 4.Institute of Single CrystalsNational Academy of Sciences of UkraineKharkovUkraine
  5. 5.Bogatskii Physicochemical InstituteNational Academy of Sciences of UkraineOdessaUkraine

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