Advertisement

Russian Journal of Inorganic Chemistry

, Volume 62, Issue 6, pp 760–765 | Cite as

Hexafluorosilicates of cobalt(II) complexes with dimethylsulfoxide and dimethylformamide

  • T. G. Cherkasova
  • I. Yu. Bagryanskaya
  • N. V. Pervukhina
  • N. V. Kurat’eva
  • V. V. Medvedev
  • E. S. Tatarinova
  • E. V. Cherkasova
Coordination Compounds

Abstract

New double complexes [Co(DMSO)6][SiF6] ⋅ 2H2O (I) and [Co(DMF)3(H2O)3][SiF6] ⋅ DMF (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals of complex I belong to the tetragonal symmetry system, space group R3̄, Z = 3, a = 11.8232(3) Å, c = 18.4699(5) Å, V = 2235.97(10) Å3, ρcalc = 1.573 g/cm3. Crystals of complex II are triclinic, space group P1̄, Z = 2, a = 8.6264(4) Å, b = 10.1419(4) Å, c = 13.9657(6) Å, α = 100.847(2)°, β = 98.549(2)°, γ = 93.479(2)°, V = 1181.71(9) Å3, ρcalc = 1.539 g/cm3.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Yu. N. Kukushkin, The Chemistry of Complex Compounds (Vysshaya Shkola, Moscow, 1985) [in Russian].Google Scholar
  2. 2.
    V. O. Gel’mbol’dt, Russ. J. Inorg. Chem. 59, 79 (2014).CrossRefGoogle Scholar
  3. 3.
    V. O. Gel’mbol’dt, Russ. J. Inorg. Chem. 57, 287 (2012).CrossRefGoogle Scholar
  4. 4.
    V. V. Ponomareva, K.V. Domasevich, V. V. Komarchuk, et al., Russ. J. Inorg. Chem. 51, 1355 (2006).CrossRefGoogle Scholar
  5. 5.
    Yu. A. Simonov, V. Kh. Kravtsov, N. V. Gerbeleu, et al., Russ. J. Inorg. Chem. 44, 1390 (1999).Google Scholar
  6. 6.
    P. N. Bourosh, E. B. Koropchanu, Yu. A. Simonov, et al., Koord. Khim. 28, 689 (2002).CrossRefGoogle Scholar
  7. 7.
    G. Kristian, Analytical Chemistry (BINOM. Laboratoriya znanii, Moscow, 2009), Vol. 2 [in Russian].Google Scholar
  8. 8.
    G. Charlot, Les methodes de la chimie analytique: Analyse quantitative minerale (Masson, Paris, 1961).Google Scholar
  9. 9.
    G. Sheldrick, SADABS. Version 01 (Bruker, Madison, Wisconsin, USA, 2004).Google Scholar
  10. 10.
    M. C. Burla, R. Caliandro, M. Camalli, et al., J. Appl. Crystallogr. 40, 609 (2007).CrossRefGoogle Scholar
  11. 11.
    G. M. Sheldrick, SHELX97. Program for the Solution and Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).Google Scholar
  12. 12.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Interscience, New York, 1986).Google Scholar
  13. 13.
    F. H. Allen, O. Kennard, and D. G. Watson, J. Chem. Soc., Perkin Trans., S1 (1987).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • T. G. Cherkasova
    • 1
  • I. Yu. Bagryanskaya
    • 2
    • 4
  • N. V. Pervukhina
    • 3
  • N. V. Kurat’eva
    • 3
    • 4
  • V. V. Medvedev
    • 1
  • E. S. Tatarinova
    • 1
  • E. V. Cherkasova
    • 1
  1. 1.Kuzbass State Technical UniversityKemerovoRussia
  2. 2.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  3. 3.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  4. 4.Novosibirsk National Research State UniversityNovosibirskRussia

Personalised recommendations