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Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate

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Abstract

Norbornadiene allylation by allyl formate in the presence of palladium catalytic systems has a number of features associated with different directions of β-hydride transfer in key intermediates, which can be carried out with the participation of allyl, norbornenyl, or formyl fragments. The value of the kinetic isotope effect and the nature of the limiting step in the reaction of hydroallylation of norbornadiene are determined using deuterated reagents.

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Authors and Affiliations

  1. MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies), 119571, Moscow, Russia

    S. A. Durakov, R. S. Shamsiev & V. R. Flid

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. E. Gekhman

Authors
  1. S. A. Durakov
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  2. R. S. Shamsiev
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  3. V. R. Flid
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  4. A. E. Gekhman
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Corresponding author

Correspondence to V. R. Flid.

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Dedicated to Academician of the Russian Academy of Sciences Ilya Iosifovich Moiseev in connection with his jubilee

Translated by Andrey Zeigarnik

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Durakov, S.A., Shamsiev, R.S., Flid, V.R. et al. Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate. Kinet Catal 60, 245–249 (2019). https://doi.org/10.1134/S0023158419030042

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  • DOI: https://doi.org/10.1134/S0023158419030042

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