Skip to main content
SpringerLink
Log in

Effect of Potassium Promotion on the Formation of a Fe/Cact Catalyst in the Course of Reduction in CO and CO/H2

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The process of formation of a Fe/C catalyst was considered as a sequence of topochemical reactions. It was demonstrated that potassium promotion accelerated the formation of magnetite at the stage of catalyst calcination in a flow of argon. The particle size of iron oxides decreased with the concentration of potassium. Potassium promotion also led to an increase in the concentration of Hägg carbide in the course of catalyst reduction by synthesis gas.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Chen, A., Kaminsky, M., Geoffroy, G.L., and Vannice, M.A., J. Phys. Chem., 1986, vol. 90, p. 4810.

    Article  CAS  Google Scholar 

  2. Jung, H.J., Walker, P.L.,Jr., and Vannice, M.A., J. Catal., 1982, vol. 75, p.416.

    Article  CAS  Google Scholar 

  3. Venter, J.J., Kaminsky, M., Geoffroy, G.L., and Vannice, M.A., J. Catal., 1987, vol. 103, p.450.

    Article  CAS  Google Scholar 

  4. Jung, H.J., Vannice, M.A., Mulay, L.N., Stanfield, R.M., and Delgass, W.N., J. Catal., 1982, vol. 76, no. 1, p.208.

    Article  CAS  Google Scholar 

  5. Yang, Y., Xiang, H.W., Xu, Y.Y., Bai, L., and Li, Y.W., Appl. Catal., 2004, vol. 266, p.181.

    Article  CAS  Google Scholar 

  6. Bukur, D.B., Mukesh, D., and Patel, S.A., Ind. Eng. Chem. Res., 1990, vol. 29, p.194.

    Article  CAS  Google Scholar 

  7. Li, S.Z., Li, A.W., Krishnamoorthy, S., and Iglesia, E., Catal. Lett., 2001, vol. 77, p.197.

    Article  CAS  Google Scholar 

  8. Dry, M.E. and Oosthuizen, G.J., J. Catal., 1968, vol. 11, p.18.

    Article  CAS  Google Scholar 

  9. Zoppi, A., Lofrumento, C., Castellucci, E.M., and Sciau, P., J. Raman Spectrosc., 2008, vol. 39, p.40.

    Article  CAS  Google Scholar 

  10. Li, J., Cheng, X., Zhang, C., Chang, Q., Wang, J., Wang, X., Lv, Z., Dong, W., Yang, Y., and Li, Y., Appl. Catal., A, 2016, vol. 528, p.131.

    Article  CAS  Google Scholar 

  11. Dry, M.E., Shingles, T., Boshoff, L., and Oosthuizen, G.J., J. Catal., 1969, vol. 15, p.190.

    Article  CAS  Google Scholar 

  12. Arakawa, H. and Bell, A.T., Ind. Eng. Chem. Process. Des. Dev., 1983, vol. 22, p.97.

    Article  CAS  Google Scholar 

  13. Yang, Y., Xiang, H.W., Xu, Y.Y., Bai, L., and Li, Y.W., Appl. Catal., 2004, vol. 266, p.181.

    Article  CAS  Google Scholar 

  14. Ma, W., Kugler, E.L., and Dadyburjor, D.B., Energy Fuels, 2007, vol. 21, p. 1832.

    Article  CAS  Google Scholar 

  15. Muhler, M., Schutze, J., Wesemann, M., Rayment, T., Dent, A., Schlogel, R., and Ertl, G., J. Catal., 1990, vol. 126, p.339.

    Article  CAS  Google Scholar 

  16. Kang, C., Ordomskya, V.V., Legrasa, B., Virginiea, M., Paula, S., Wang, Y., and Khodakov, A.Y., Appl. Catal., A, 2015, p.204.

    Google Scholar 

  17. Chernavskii, P.A., Lunin, B.S., Zakharyan, R.A., Pankina, G.V., and Perov, N.S., Instrum. Exp. Tech., 2014, vol. 57, p.78.

    Article  CAS  Google Scholar 

  18. Selwood, P.W., Magnetochemistry, Interscience, 1948.

    Google Scholar 

  19. Menil, F., J. Phys. Chem. Solids, 1985, vol. 46, p.763.

    Article  CAS  Google Scholar 

  20. Kündig, W., Bömmel, H., Konstabaris, H., and Lindquist, R.H., Phys. Rev., 1966, vol. 142, p.327.

    Article  Google Scholar 

  21. Lancok, A., Závëta, K., Popovici, M., Savii, C., Gich, M., Roig, A., Molins, E., and Barcova, K., Hyperfine Interact., 2005, vol. 165, p.203.

    Article  Google Scholar 

  22. Bozorth, R.M., Ferromagnetism, New York: Van Nostrand, 1951.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    P. A. Chernavskii, V. O. Kazak, G. V. Pankina, N. E. Strokova & Yu. D. Perfil’ev

Authors
  1. P. A. Chernavskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. O. Kazak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Pankina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. E. Strokova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. D. Perfil’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. A. Chernavskii.

Additional information

Original Russian Text © P.A. Chernavskii, V.O. Kazak, G.V. Pankina, N.E. Strokova, Yu.D. Perfil’ev, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 2, pp. 251–259.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chernavskii, P.A., Kazak, V.O., Pankina, G.V. et al. Effect of Potassium Promotion on the Formation of a Fe/Cact Catalyst in the Course of Reduction in CO and CO/H2. Kinet Catal 59, 229–236 (2018). https://doi.org/10.1134/S0023158418020040

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158418020040

Keywords

Search

Navigation