Kinetics and Catalysis

, Volume 59, Issue 2, pp 150–159 | Cite as

The Oxidation of Carbon Monoxide as an Integrated Part of the Coupled Alkane Oxidation Process: Gas-Phase Oxidation over Supported Metal-Complex Catalysts

  • E. G. ChepaikinEmail author
  • A. P. Bezruchenko
  • G. N. Menchikova
  • O. P. Tkachenko
  • L. M. Kustov
  • A. V. Kulikov


Heterogeneous rhodium–copper chloride catalysts for gas-phase oxidation processes were prepared via the cold impregnation of γ-Al2O3 with aqueous RhCl3 and CuCl2 solutions. Heptafluorobutyric or pentafluorobenzoic acids were additionally deposited onto these catalysts to simulate the action of homogeneous rhodium–copper chloride catalytic systems in the coupled alkane–carbon monoxide oxidation reaction. The catalysts were studied in the reactions of carbon monoxide oxidation and coupled propane–CO oxidation with dioxygen by diffuse reflectance IR Fourier transform spectroscopy (DRIFTS) and electron paramagnetic resonance (EPR). The obtained data indicate the probable transfer of electrons between rhodium and copper compounds.


carbon monoxide catalytic oxidation rhodium chloride copper chloride γ-aluminum oxide DRIFTS EPR 


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  1. 1.
    Sokol’skii, D.V. and Dorfman, Ya.A., Kataliz ligandami v vodnykh rastvorakh (Catalysis by ligands in water solutions), Alma-Ata: Nauka, 1972.Google Scholar
  2. 2.
    Rakitskaya, T.L. and Paina, V.Ya., Kinet. Katal., 1990, vol. 31, no. 2, p. 1393.Google Scholar
  3. 3.
    Kuznetsova, L.I., Matveev, K.I., and Zhizhina, E.G., Kinet. Katal., 1986, vol. 26, no. 5, p. 1029.Google Scholar
  4. 4.
    Kakhniashvili, G.N., Mishchenko, Yu.A., Dulin, D.A., Isaeva, E.G., and Gel’bshtein, A.I., Kinet. Katal., 1985, vol. 26, no. 1, p.134.Google Scholar
  5. 5.
    Park, E.D. and Lee, J.S., J. Catal., 2000, no. 1, p.5.CrossRefGoogle Scholar
  6. 6.
    Shen, Y., Lu, G., Guo, Y., and Gong, X., Catal. Today, 2011, vol. 175, p.558.CrossRefGoogle Scholar
  7. 7.
    Kotareva, I.A., Oshanina, I.V., Odintsov, K.Yu., Bruk, L.G., and Temkin, O.N., Kinet. Katal., 2008, vol. 49, no. 1, p.22.CrossRefGoogle Scholar
  8. 8.
    Titov, D.N., Ustyugov, A.V., Tkachenko, O.P., Kustov, L.M., Zubavichus, Ya.V., Veligzhanin, A.A., Sadovskaya, N.V., Oshanina, I.V., Bruk, L.G., and Temkin, O.N., Kinet. Catal., 2012, vol. 53, no. 2, p.262.CrossRefGoogle Scholar
  9. 9.
    Golodov, V.A., Sokolsky, D.V., and Noskova, N.F., J. Mol. Catal., 1977, nos. 1–3, p.51.CrossRefGoogle Scholar
  10. 10.
    Lee, J.S. and Park, E.D., Top. Catal., 2002, vol. 18, nos. 1–2, p.67.CrossRefGoogle Scholar
  11. 11.
    Arutyunov, V.S. and Krylov, O.V., Okislitel’nye prevrashcheniya metana (Oxidative transformations of methane), Moscow: Nauka, 1998.Google Scholar
  12. 12.
    Chepaikin, E.G., Usp. Khim., 2011, vol. 80, no. 4, p.384.CrossRefGoogle Scholar
  13. 13.
    Chepaikin, E.G., J. Mol. Catal. A.: Chem, 2014, vol. 385, p.160.CrossRefGoogle Scholar
  14. 14.
    Chepaikin, E.G. and Borshch, V.N., J. Organomet. Chem., 2015, vol. 793, p.78.CrossRefGoogle Scholar
  15. 15.
    Sen, A., Acc. Chem. Res., 1998, vol. 31, no. 9, p.550.CrossRefGoogle Scholar
  16. 16.
    Lin, M., Hogan, T., and Sen, A., J. Am. Chem. Soc., 1996, vol. 118, no. 19, p. 4574.CrossRefGoogle Scholar
  17. 17.
    Chepaikin, E.G., Bezruchenko, A.P., Leshcheva, A.A., Boyko, G.N., Kuzmenkov, I.V., Grigoryan, E.H., and Shilov, A.E., J. Mol. Catal. A.: Chem, 2001, vol. 169, p.89.CrossRefGoogle Scholar
  18. 18.
    Chepaikin, E.G., Bezruchenko, A.P., and Leshcheva, A.A., Kinet. Catal., 2002, vol. 43, no. 4, p.507.CrossRefGoogle Scholar
  19. 19.
    Chepaikin, E.G., Bezruchenko, A.P., Boiko, G.N., Gekhman, A.E., and Moiseev, I.I., Kinet. Catal., 2006, vol. 47, no. 1, p.12.CrossRefGoogle Scholar
  20. 20.
    Chepaikin, E.G., Bezruchenko, A.P., Menchikova, G.N., and Gekhman, A.E., J. Mol. Catal. A.: Chem., 2017, vol. 426, p.389.CrossRefGoogle Scholar
  21. 21.
    Shilov, A.E., Metal Complexes in Biomimetic Chemical Reactions, Boca Raton: CRC Press, 1997.Google Scholar
  22. 22.
    Zuberbuhler, A., Helv. Chim. Acta, 1967, vol. 50, no. 2, p.466.CrossRefGoogle Scholar
  23. 23.
    Mehnert, C.P., Chem.–Eur. J., 2005, vol. 11, p.50.CrossRefGoogle Scholar
  24. 24.
    Haumann, M., Dentler, K., Joni, J., Rissager, A., and Wassersheid, P., Adv. Synth. Catal., 2007, vol. 349, p.425.CrossRefGoogle Scholar
  25. 25.
    Oliver-Bourbigou, H., Magna, L., and Morvan, D., Appl. Catal., A., 2010, vol. 373, p.1.CrossRefGoogle Scholar
  26. 26.
    Guan, H.L., Lin, J., Qiao, B.T., Yang, X.F., Li, L., Miao, S., Liu, J.Y., Wang, A.Q., Wang, X.D., and Zang, T., Angew. Chem., 2016, vol. 55, p. 2820.CrossRefGoogle Scholar
  27. 27.
    Guan, H.L., Lin, J., Li, L., Wang, X.D., and Zang, T., Appl. Catal., B., 2016, vol. 184, p.299.CrossRefGoogle Scholar
  28. 28.
    Kustov, L.M., Top. Catal., 1995, vol. 4, p.131.CrossRefGoogle Scholar
  29. 29.
    Davydov, A.A. Molecular Spectroscopy of Oxide Catalyst Surfaces, Hoboken: John Wiley & Sons, Inc., 2003, p.466.CrossRefGoogle Scholar
  30. 30.
    Hadjiivanov, K.I. and Vayssilov, G.N., Adv. Catal., 2002, vol. 47, p.307.Google Scholar
  31. 31.
    Sheppard, N. and Nguyen, T.T. Advances in Infrared and Raman Spectroscopy, Eds. Clark, R.J.H., Heste, R.E., vol. 5, chapter 2, London: Heyden and Son, 1978.Google Scholar
  32. 32.
    Kubiak, C.P. and Eisenberg, R., J. Am. Chem. Soc., 1980, vol. 102, p. 3637.CrossRefGoogle Scholar
  33. 33.
    Hosokawa, T., Nomura, T., and Murahashi, S.-I., J. Organomet. Chem., 1998, vol. 551, p. 387.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. G. Chepaikin
    • 1
    Email author
  • A. P. Bezruchenko
    • 1
  • G. N. Menchikova
    • 1
  • O. P. Tkachenko
    • 2
  • L. M. Kustov
    • 2
    • 3
  • A. V. Kulikov
    • 4
  1. 1.Merzhanov Institute of Structural Macrokinetics and Materials ScienceRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Department of ChemistryMoscow State UniversityMoscowRussia
  4. 4.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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