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Temperature Hysteresis in the Reaction of Methane Oxidation on a Palladium-Doped Manganese Hexaaluminate Catalyst

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Abstract

A study of the Pd-containing catalyst based on manganese hexaaluminate by X-ray diffraction analysis, transmission electron microscopy, thermo-programmed reduction with hydrogen, and thermoprogrammed oxidation showed the hysteresis manifested itself in a difference between the temperature dependences of its catalytic activity in the oxidation of methane under the conditions of sample heating or cooling is related to the decomposition of PdO to metallic palladium at temperatures higher than 700–800°C and the subsequent formation of PdO nanoparticles, which are localized on the surface of metallic Pd (30–50 nm) in the form of polycrystalline films with a thickness of 2–5 nm, at temperatures lower than 600–700°C. A near-surface oxide film is formed under the conditions of cooling in oxygen-containing atmospheres, including in the presence of methane. The value of the hysteresis depends on the heat treatment temperature of the catalyst, and it reaches a maximum on the catalysts calcined at 900 and 1000°C.

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References

  1. Pfefferle, L.D. and Pfefferle, W.C., Catal. Rev. Sci. Eng., 1987, vol. 29, p.219.

    Article  CAS  Google Scholar 

  2. Hicks, R.F., Qi, H., Young, M.L., and Lee, R.G., J. Catal., 1990, vol. 122, p.280.

    Article  CAS  Google Scholar 

  3. Hicks, R.F., Qi, H., Young, M.L., and Lee, R.G., J. Catal., 1990, vol. 122, p.295.

    Article  CAS  Google Scholar 

  4. Baldwin, T.H. and Burch, R., Appl. Catal., 1990, vol. 66, p.337.

    Article  CAS  Google Scholar 

  5. Baldwin, T.H. and Burch, R., Appl. Catal., 1990, vol. 66, p.359.

    Article  CAS  Google Scholar 

  6. Briot, P. and Primet, M., Appl. Catal., 1991, vol. 68, p.301.

    Article  CAS  Google Scholar 

  7. Oh, S.H., Mitchell, P.J., and Siewert, R.M., J. Catal., 1991, vol. 132, p.287.

    Article  CAS  Google Scholar 

  8. Lampert, J.K., Kazi, M.S., and Farrauto, R.J., Appl. Catal. B, vol. 14, p.211.

  9. Garbowski, E., Feumi-Jantou, C., Mouaddib, N., and Primet, M., Appl. Catal. A, 1994, vol. 109, p.277.

    Article  CAS  Google Scholar 

  10. Burch, R. and Urbano, F.J., Appl. Catal. A, 1995, vol. 124, p.121.

    Article  CAS  Google Scholar 

  11. Burch, R., Loader, P.K., and Urbano, F.J., Catal. Today, 1996, vol. 27, p.243.

    Article  CAS  Google Scholar 

  12. McCarty, J.G., Catal. Today, 1995, vol. 26, p.283.

    Article  CAS  Google Scholar 

  13. Lyubovsky, M. and Pfefferle, L.D., Appl. Catal. A, 1998, vol. 173, p.107.

    Article  CAS  Google Scholar 

  14. Lyubovsky, M., Smith, L.L., Castaldi, M., Karim, H., Nentwick, B., Etemad, S., LaPierre, R., and Pfefferle, W.C., Catal. Today, 2003, vol. 83, p.71.

    Article  CAS  Google Scholar 

  15. Ismagilov, Z.R., Kerzhentsev, M.A., Sazonov, V.A., Tsykoza, L.T., Shikina, N.V., Kuznetsov, V.V., Ushakov, V.A., Mishanin, S.V., Kozhukhar, N.G., Russo, G., and Deutschmann, O., Korean J. Chem. Eng., 2003, vol. 20, p.461.

    Article  CAS  Google Scholar 

  16. Yashnik, S.A. and Ismagilov, Z.R., Top. Catal., 2012, vol. 55, p.818.

    Article  CAS  Google Scholar 

  17. McCarty, J.G., Gusman, M., Lowe, D.M., Hildenbrand, D.L., and Lau, K.N., Catal. Today, 1999, vol. 47, p.5.

    Article  CAS  Google Scholar 

  18. Yashnik, S.A., Ismagilov, Z.R., Kuznetsov, V.V., Ushakov, V.V., Rogov, V.A., and Ovsyannikova, I.A., Catal. Today, 2006, vol. 117, p.525.

    Article  CAS  Google Scholar 

  19. Yashnik, S.A., Chesalov, Yu.A., Ishchenko, A.V., Kaichev, V.V., and Ismagilov, Z.R., Appl. Catal. B, 2017, vol. 204, p.89.

    Article  CAS  Google Scholar 

  20. Yashnik, S.A., Shikina, N.V., Ismagilov, Z.R., Zagoruiko, A.N., Kerzhentsev, M.A., Parmon, V.N., Zakharov, V.M., Braynin, B.I., Favorski, O.N., and Gumerov, A.M., Catal. Today, 2009, vol. 147, p.237.

    Article  CAS  Google Scholar 

  21. Ismagilov, Z.R., Shikina, N.V., Yashnik, S.A., Zagoruiko, A.N., Kerzhentsev, M.A., Ushakov, V.A., Sazonov, V.A., Parmon, V.N., Zakharov, V.M., Braynin, B.I., and Favorskii, O.N., Catal. Today, 2010, vol. 155, p.35.

    Article  CAS  Google Scholar 

  22. Ismagilov, Z.R., Kerzhentsev, M.A., Yashnik, S.A., Shikina, N.V., Zagoruiko, A.N., Parmon, V.N., Zakharov, V.M., Braynin, B.I., and Favorski, O.N., Gas Turbines. Ed. Gurrapa I. Sciyo, 2010, Chapter 4, p.79.

  23. Farrauto, R.J., Hobson, M.C., Kennelly, T., and Waterman, E.M., Appl. Catal. A, 1992, vol. 81, p.227.

    Article  CAS  Google Scholar 

  24. Farrauto, R.J., Lampert, J.K., Hobson, M.C., and Waterman, E.M., Appl. Catal. B, 1995, vol. 6, p.263.

    Article  CAS  Google Scholar 

  25. Rodriguez, N.M., Oh, S.G., Dallabetta, R.A., and Baker, R.T.K., J. Catal., 1995, vol. 157, p.676.

    Article  CAS  Google Scholar 

  26. Salmonsson, P., Johansson, S., and Kasemo, B., Catal. Lett., 1995, vol. 33, p.1.

    Article  Google Scholar 

  27. Ho, Y.S., Wang, C.-B., and Yeh, C.T., J. Mol. Catal. A, 1996, vol. 112, p.287.

    Article  CAS  Google Scholar 

  28. Lyubovsky, M. and Pfefferle, L., Catal. Today, 1999, vol. 47, p.29.

    Article  CAS  Google Scholar 

  29. Datye, A.K., Bravo, J., Nelson, T.R., Atanasova, P., Lyubovsky, M., and Pfefferle, L., Appl. Catal. A, 2000, vol. 198, p.179.

    Article  CAS  Google Scholar 

  30. Yang, S., Maroto-Valiente, A., Benito-Gonzalez, M., Rodriguez-Ramos, I., and Guerrero-Ruiz, A., Appl. Catal. B, 2000, vol. 28, p.223.

    Article  CAS  Google Scholar 

  31. Thevenin, P.O., Alcalde, A., Pettersson, L.J., Jaras, S.G., and Fierro, J.L.G., J. Catal., 2003, vol. 215, p.78.

    Article  CAS  Google Scholar 

  32. Simplicio, L.M.T., Brandao, S.T., Domingos, D., Bozon-Verduraz, F., and Sales, E.A., Appl. Catal. A, 2009, vol. 360, p.2.

    Article  CAS  Google Scholar 

  33. Colussi, S., Trovarelli, A., Vesselli, E., Baraldi, A., Comelli, G., Groppi, G., and Llorca, J., Appl. Catal. A, 2010, vol. 390, p.1.

    Article  CAS  Google Scholar 

  34. Widjaja, H., Sekizawa, K., Eguchi, K., and Arai, H., Catal. Today, 1999, vol. 47, p.95.

    Article  CAS  Google Scholar 

  35. Ismagilov, Z.R., Shikina, N.V., Yashnik, S.A., Parmon, V.N., Favorskii, O.N., Zakharov, V.M., and Branin, B.I., RF Patent no. 2372556, 2009.

  36. Aulchenko, V.M., Evdokov, O.V., Kutovenko, V.D., Pirogov, B.Ya., Sharafutdinov, M.R., Titov, V.M., Tolochko, B.P., Vasiljev, A.V., Zhogin, I.A., and Zhulanov, V.V., Nucl. Instrum. Methods. Res. A, 2009, vol. 603, p.76.

    Article  CAS  Google Scholar 

  37. Chen, J.J. and Ruckenstein, E., J. Phys. Chem., 1981, vol. 85, p. 1606.

    Article  CAS  Google Scholar 

  38. Yashnik, S.A., Kuznetsov, V.V., Ismagilov, Z.R., Ushakov, V.V., Danchenko, N.M., and Denisov, S.P., Top. Catal., 2004, vol. 30-31, p.293.

    Article  Google Scholar 

  39. Yashnik, S.A., Ismagilov, Z.R., Porsin, A.V., Denisov, S.P., and Danchenko, N.M., Top. Catal., 2007, vol. 42–43, p.465.

    Article  CAS  Google Scholar 

  40. Ferrandon, M., Carno, J., Jaras, S., and Bjornbom, E., Appl. Catal. A, 1999, vol. 180, p.141.

    Article  CAS  Google Scholar 

  41. Alvarez-Galvan, M.C., de la Pena O’Shea, V.A., Fierro, J.L.G., and Arias, P.L., Catal. Commun., 2003, vol. 4, p.223.

    Article  CAS  Google Scholar 

  42. Kapteijn, F., van Langeveld, D., Moulijn, J.A., Andreini, A., Vuurman, M.A., Turek, A.M., Jehng, J., and Wachs, I.E., J. Catal., 1994, vol. 150, p.94.

    Article  CAS  Google Scholar 

  43. Yashnik, S.A., Denisov, S.P., Danchenko, N.M., and Ismagilov, Z.R., Top. Catal., 2007, vol. 42–43, p.465.

    Article  CAS  Google Scholar 

  44. Pinna, F., Signoretto, M., Strukul, G., Polizzi, S., and Pernicone, N., React. Kinet. Catal. Lett., 1997, vol. 60, p.9.

    Article  CAS  Google Scholar 

  45. Bonarowska, M., Pielaszek, J., Juszczyk, W., and Karpinski, J., J. Catal., 2000, vol. 195, p.304.

    Article  CAS  Google Scholar 

  46. Scholten, J.J.S. and Konvalinka, J.A., J. Catal., 1966, vol. 5, p.1.

    Article  CAS  Google Scholar 

  47. Tsikoza, L.T., Ismagilov, Z.R., Ushakov, V.A., Kuznetsov, V.V., and Ovsyannikova, I.A., Kinet. Katal., 2003, vol. 44, p.879.

    Google Scholar 

  48. Yashnik, S.A., Ushakov, V.V., Leonov, N.L., and Ismagilov, Z.R., Eurasian Chemico-Technological J., 2015, vol. 17, p.145.

    Article  CAS  Google Scholar 

  49. Rode, E.Ya., Kislorodnye soedineniya margantsa (Oxygen compounds of manganese), Moscow: Nauka, 1952.

    Google Scholar 

  50. Kaptejn, F., Singoredjo, L., Andreini, A., and Moulijn, J.A., Appl. Catal. B, 1994, vol. 3, p.173.

    Article  Google Scholar 

  51. Carroni, R., Griffin, T., Mantzaras, J., and Reinke, M., Catal. Today, 2003, vol. 83, p.157.

    Article  CAS  Google Scholar 

  52. Fujimoto, K., Ribeiro, F.H., Avalos-Borja, M., and Iglesia, E., J. Catal., 1998, vol. 179, p.431.

    Article  CAS  Google Scholar 

  53. Ersson, A., Kusar, H., Carroni, R., Griffin, T., and Jaras, S., Catal. Today, 2003, vol. 83, p.265.

    Article  CAS  Google Scholar 

  54. Su, S.C., Carstens, J.N., and Bell, A.T., J. Catal., 1998, vol. 176, p.125.

    Article  CAS  Google Scholar 

  55. Zhang, X. and Lee, C.S.-M., Mingos, D.M.P., Hayward, D.O., Appl. Catal. A, 2003, vol. 240, p.183.

    Article  CAS  Google Scholar 

  56. Wolf, M.M., Zhu, H., Green, W.H., and Jackson, G.S., Appl. Catal. A, 2003, vol. 244, p. 323.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    S. A. Yashnik, Z. S. Vinokurov, A. V. Salnikov, A. V. Ishchenko, V. V. Kaichev & Z. R. Ismagilov

  2. Institute of Coal Chemistry and Chemical Materials Science, Siberian Branch, Russian Academy of Sciences, Kemerovo, 650000, Russia

    Z. R. Ismagilov

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  1. S. A. Yashnik
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  2. Z. S. Vinokurov
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  4. A. V. Ishchenko
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  5. V. V. Kaichev
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  6. Z. R. Ismagilov
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Correspondence to S. A. Yashnik.

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Original Russian Text © S.A. Yashnik, Z.S. Vinokurov, A.V. Salnikov, A.V. Ishchenko, V.V. Kaichev, Z.R. Ismagilov, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 1, pp. 92–104.

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Yashnik, S.A., Vinokurov, Z.S., Salnikov, A.V. et al. Temperature Hysteresis in the Reaction of Methane Oxidation on a Palladium-Doped Manganese Hexaaluminate Catalyst. Kinet Catal 59, 70–82 (2018). https://doi.org/10.1134/S0023158418010160

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  • DOI: https://doi.org/10.1134/S0023158418010160

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