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Promoting effect of potassium and calcium additives to cerium–zirconium oxide catalysts for the complete oxidation of carbon monoxide

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Abstract

The effect of potassium and calcium additives on the catalytic activity of the Ce0.8Zr0.2O2 system in the reaction of CO oxidation was studied. With the use of X-ray diffraction analysis, it was found that the Ce0.8Zr0.2O2 and Ce0.8Zr0.2O2–Ca,K samples contained a mixed oxide of cerium and zirconium; the presence of the independent phases of potassium and calcium compounds in the modified system was not detected. With the use of the low-temperature adsorption–desorption of nitrogen, X-ray photoelectron spectroscopy, and temperature-programmed reduction, it was established that the Ce0.8Zr0.2O2–Ca,K system (in spite of the fact that its specific surface area was lower than that of Ce0.8Zr0.2O2) contained more active oxygen on the surface; peroxide and superoxide complexes formed upon the chemisorption of O2 can act as active oxygen species. This can be the reason for a higher efficiency of the Ce0.8Zr0.2O2–Ca,K system in comparison with that of the unmodified oxide. The results obtained indicate that the ash impurities of Ca and K can increase the catalytic activity of the biomorphic mixed oxides Ce0.8Zr0.2O2 prepared with the use of sawdust as a template.

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References

  1. Royer, S. and Duprez, D., ChemCatChem, 2010, vol. 3, no. 1, p. 24.

    Article  Google Scholar 

  2. European Environment Agency. http://www.eea.europa. eu/data-and-maps/data/data-viewers/air-emissionsviewer-lrtap.

  3. Ozawa, M., J. Alloys Compd., 1998, vols. 275–277, p. 886.

    Article  Google Scholar 

  4. Duprez, D., Descorme, C., Birchem, T., and Rohart, E., Top. Catal., 2001, vol. 16, p. 49.

    Article  Google Scholar 

  5. Zheng, X-C., Wang, S.-P., Wang, S.-R., Zhang, S.M., Huang, W.P., and Wu, S.H., Mater. Sci. Eng., 2005, vol. 25, p. 516.

    Article  Google Scholar 

  6. Ayastuy, J.L., Iglesias-González, A., and Gutiérrez-Ortiz, M.A., J. Chem. Eng., 2014, vol. 244, p. 372.

    Article  CAS  Google Scholar 

  7. Cao, J.L., Deng, Q.F., and Yuan, Z.Y., J. Mater. Sci., 2009, vol. 44, no. 24, p. 6663.

    Article  CAS  Google Scholar 

  8. Pu, Z.-Y., Liu, X.-S., Jia, A.-P., Xie, Y.L., Lu, J.Q., and Luo, M.F., J. Phys. Chem. C, 2008, vol. 112, p. 15045.

    Article  CAS  Google Scholar 

  9. Hori, C.E., Permana, H., Ng, K.Y.S., Brenner, A., More, K., Rahmoeller, K.M., and Belton, D., Appl. Catal., B, 1998, vol. 16, p. 105.

    Article  CAS  Google Scholar 

  10. Fornasiero, P., Dimonte, R., Rao, G.R., Kaspar, J., Meriani, S., Trovarelli, A., and Graziani, M., J. Catal., 1995, vol. 151, no. 1, p. 168.

    Article  CAS  Google Scholar 

  11. Aneggi, E., de Leitenburg, C., Dolcetti, G., and Trovarelli, A., Catal. Today, 2008, vol. 136, no. 1, p. 3.

    Article  CAS  Google Scholar 

  12. Kaplin, I.Yu., Lokteva, E.S., Golubina, E.V., Maslakov, K.I., Chernyak, S.A., Levanov, A.V., Strokova, N.E., and Lunin, V.V., Russ. J. Phys. Chem. A, 2016, vol. 90, no. 11, p. 2157.

    Article  CAS  Google Scholar 

  13. Kuznetsova, T.G., Sadykov, V.A., Moroz, E.M., Trukhan, S.N., Paukshtis, E.A., Kolomiichuk, V.N., Burgina, E.V., Zaikovskii, V.I., Fedotov, M.A., Lunin, V.V., and Kemnitz, E., Stud. Surf. Sci. Catal., 2000, vol. 143, p. 659.

    Article  Google Scholar 

  14. Cerfontain, M.B., Meijer, R., Kapteijn, F., and Moulijn, J.A., J. Catal., 1987, vol. 107, p. 173.

    Article  CAS  Google Scholar 

  15. Dolle, P., Drissi, S., Besancon, M., and Jupille, J., Surf. Sci., 1992, vols. 269–270, p. 687.

    Article  Google Scholar 

  16. Mullins, D.R., Overbury, S.H., and Huntley, D.R., Surf. Sci., 1998, vol. 409, no. 2, p. 307.

    Article  CAS  Google Scholar 

  17. Abi-aad, E., Bechara, R., Grimblot, J., and Aboukais, A., Chem. Mater., 1993, vol. 5, no. 6, p. 793.

    Article  CAS  Google Scholar 

  18. Noronha, F.B., Fendley, E.C., Soareset, R.R., Alvarez, W.E., and Resasco, D.E., J. Chem. Eng., 2001, vol. 82, p. 21.

    Article  CAS  Google Scholar 

  19. Galtayries, A., Sporken, R., Riga, J., Blanchard, G., and Caudano, R., J. Electron Spectrosc. Relat. Phenom., 1998, vol. 88, p. 951.

    Article  Google Scholar 

  20. Nelson, A.E. and Schulz, K.H., Appl. Surf. Sci., 2003, vol. 210, p. 206.

    Article  CAS  Google Scholar 

  21. Tang, X., Zhang, B., Li, Y., Xu, Y., Xin, Q., and Shen, W., Catal. Today, 2004, vol. 93, p. 191.

    Article  Google Scholar 

  22. Holgado, J.P., Munuera, G., Espinós, J.P., and González-Elipe, A.R., Appl. Surf. Sci., 2000, vol. 158, p. 164.

    Article  CAS  Google Scholar 

  23. Yao, H.C. and Yu-Yao, Y.F., J. Catal., 1984, vol. 86, p. 254.

    Article  CAS  Google Scholar 

  24. Zhang, C., Wen, X.D., Teng, B.T., Zhao, Y., and Fan, M., Fuel Process. Technol., 2015, vol. 131, p. 1.

    Article  CAS  Google Scholar 

  25. Wang, X.Y., Kang, Q., and Li, D., Catal. Commun., 2008, vol. 9, p. 2158.

    Article  CAS  Google Scholar 

  26. Trovarelli, A., Deleitenburg, C., Dolcetti, G., and Lorca, J.L., J. Catal., 1995, vol. 151, no. 1, p. 111.

    Article  CAS  Google Scholar 

  27. Terribile, D., Trovarelli, A., de Leitenburg, C., Primavera, A., and Dolcetti, G., Catal. Today, 1999, vol. 47, p. 133.

    Article  CAS  Google Scholar 

  28. Atribak, I., Bueno-López, A., and García-García, A., J. Catal., 2008, vol. 259, no. 1, p. 123.

    Article  CAS  Google Scholar 

  29. Guillén-Hurtado, N., Bueno-López, A., and García-García, A., J. Mater. Sci., 2012, vol. 47, p. 3204.

    Article  Google Scholar 

  30. Zhu, Z.H. and Lu, G.Q., J. Catal., 1999, vol. 197, p. 262.

    Article  Google Scholar 

  31. Zhu, Z.H., Lu, G.Q., and Yang, R.T., J. Catal., 2000, vol. 192, p. 77.

    Article  CAS  Google Scholar 

  32. Ogura, M., Kimura, R., Ushiyama, H., Nikaido, F., Yamashita, K., and Okubo, T., ChemCatChem, 2014, vol. 6, p. 479.

    Article  CAS  Google Scholar 

  33. Weng, D., Li, J., Wu, X., and Si, Z., J. Environ. Sci., 2011, vol. 23, no. 1, p. 145.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    I. Yu. Kaplin, E. S. Lokteva, E. V. Golubina, K. I. Maslakov, S. A. Chernyak & V. V. Lunin

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  1. I. Yu. Kaplin
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  2. E. S. Lokteva
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  3. E. V. Golubina
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  4. K. I. Maslakov
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  5. S. A. Chernyak
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  6. V. V. Lunin
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Correspondence to I. Yu. Kaplin.

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Original Russian Text © I.Yu. Kaplin, E.S. Lokteva, E.V. Golubina, K.I. Maslakov, S.A. Chernyak, V.V. Lunin, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 5, pp. 598–605.

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Kaplin, I.Y., Lokteva, E.S., Golubina, E.V. et al. Promoting effect of potassium and calcium additives to cerium–zirconium oxide catalysts for the complete oxidation of carbon monoxide. Kinet Catal 58, 585–592 (2017). https://doi.org/10.1134/S0023158417050081

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  • DOI: https://doi.org/10.1134/S0023158417050081

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