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Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene

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Abstract

Ionic complexes of the composition [LnL2(NO3)2]2[Ln(NO3)5]3Me2CO (Ln = Sm (1), Eu (2), Tb (3), Dy (4)) with an optically active ligand L containing 1,10-phenanthroline and (+)−3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure of compound 2 is composed of complex [EuL2(NO3)2]+ cations (N6O4 polyhedron) and complex [Eu(NO3)5]2− anions (O10 polyhedron), and also Me2CO molecules. The L and NO3 ligands perform both tridentate and bidentate chelating functions respectively. Complexes 1–4 are isostructural and crystallize in the non-centrosymmetric space group P1; their magnetic properties are studied in the temperature range 2–300 K. The μeff values for 1–4 at 300 K are 3.14 μB, 6.08 μB, 16.76 μB, and 18.30 μB respectively and are typical of Ln3+ ions. For complex 3 significant anisotropy results in a nonlinear field dependence of the magnetization at 2 K. Complexes 1–4 exhibit metal-centered orange (Sm3+), red (Eu3+), green (Tb3+), and yellow (Dy3+) luminescence in the solid state at room temperature. Luminescence quantum yield decreases for solid samples in the order 2 > 1 > 3 ≈ 4.

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Acknowledgments

The authors are thankful to A.P. Zubareva and V.V. Ankudovich for the elemental analysis data, P.E. Plyusnin for the thermogravimetry data, N.I. Alferova for the IR spectra, and N.P. Korotkevich for the powder XRD data.

Funding

The study was supported by RFBR within scientific project No. 18-33-00239.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. A. Bryleva, L. A. Glinskaya, M. I. Rakhmanova, T. S. Sukhikh, E. A. Gorbunova & S. V. Larionov

  2. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. M. Agafontsev & A. V. Tkachev

  3. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Bogomyakov

  4. Novosibirsk State University, Novosibirsk, Russia

    Yu. A. Bryleva, A. M. Agafontsev, A. S. Bogomyakov, T. S. Sukhikh, E. A. Gorbunova, A. V. Tkachev & S. V. Larionov

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  1. Yu. A. Bryleva
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  2. L. A. Glinskaya
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  3. A. M. Agafontsev
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  4. M. I. Rakhmanova
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  6. T. S. Sukhikh
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  7. E. A. Gorbunova
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  8. A. V. Tkachev
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  9. S. V. Larionov
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Correspondence to Yu. A. Bryleva.

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The authors declare that they have no conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 8, pp. 1366–1378.

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Bryleva, Y.A., Glinskaya, L.A., Agafontsev, A.M. et al. Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)−3-Carene. J Struct Chem 60, 1314–1326 (2019). https://doi.org/10.1134/S0022476619080110

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  • DOI: https://doi.org/10.1134/S0022476619080110

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