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Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine

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Abstract

Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu2(μ2-I)2L4], wherein Cu⋯Cu contact of 2.6351(4) Å is observed. The each metal atom of the [Cu2(μ2-I)2] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (λmax = 600 nm) with the average lifetime of 1.66 μs and quantum yield of 17%.

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Acknowledgments

The authors are grateful to the Multi-Access Chemical Service Center SB RAS for single crystal XRD analysis.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Artem’ev & A. S. Beresin

  2. Novosibirsk State University, Novosibirsk, Russia

    A. V. Artem’ev, A. S. Beresin & I. Yu. Bagryanskaya

  3. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    I. Yu. Bagryanskaya

Authors
  1. A. V. Artem’ev
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  2. A. S. Beresin
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  3. I. Yu. Bagryanskaya
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Corresponding author

Correspondence to A. V. Artem’ev.

Additional information

Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 6, pp. 1008–1012.

Funding

This work was supported by Russian Science Foundation (Project 18-73-10086).

Conflict Of Interests

The authors declare that they have no conflict of interests.

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Artem’ev, A.V., Beresin, A.S. & Bagryanskaya, I.Y. Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine. J Struct Chem 60, 967–971 (2019). https://doi.org/10.1134/S0022476619060118

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  • DOI: https://doi.org/10.1134/S0022476619060118

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