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Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements

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Abstract

By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Demakov, S. A. Sapchenko, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Demakov, S. A. Sapchenko, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

Authors
  1. P. A. Demakov
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  2. S. A. Sapchenko
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  3. D. G. Samsonenko
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  4. D. N. Dybtsev
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  5. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 5, pp. 849-856.

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Demakov, P.A., Sapchenko, S.A., Samsonenko, D.G. et al. Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements. J Struct Chem 60, 815–822 (2019). https://doi.org/10.1134/S0022476619050159

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  • DOI: https://doi.org/10.1134/S0022476619050159

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